氮化碳基纳米复合材料在重金属去除方面研究进展

doi:10.15541/jim20190436

无机材料学报 ›› 2020, Vol. 35 ›› Issue (3): 260-270.DOI: 10.15541/jim20190436

所属专题： 2020年环境材料论文精选(二)重金属元素去除；优秀作者论文集锦； 2019~2020年度优秀作者作品欣赏:环境材料

氮化碳基纳米复合材料在重金属去除方面研究进展

王祥学^1,²,李星¹,王佳琦¹,朱洪涛¹

^1. 华北电力大学环境科学与工程系, 燃煤电站烟气多污染物协同控制实验室, 保定 071003
^2. 西南科技大学核废物与环境安全国防重点学科实验室, 绵阳621010

收稿日期:2019-08-19 修回日期:2019-10-03 出版日期:2020-03-20 网络出版日期:2019-10-25
作者简介:王祥学(1976-), 男, 博士, 讲师. E-mail: wang730304@163.com

Recent Advances in Carbon Nitride-based Nanomaterials for the Removal of Heavy Metal Ions from Aqueous Solution

WANG Xiangxue^1,²,LI Xing¹,WANG Jiaqi¹,ZHU Hongtao¹

^1. Hebei Key Lab of Power Plant Flue Gas Multi-pollutants Control, Department of Environmental Science and Engineering, North China Electric Power University, Baoding 071003, China
^2. Fundamental Science on Nuclear Wastes and Environmental Safety Laboratory, Southwest University of Science and Technology, Mianyang 621010, China

Received:2019-08-19 Revised:2019-10-03 Published:2020-03-20 Online:2019-10-25
About author:WANG Xiangxue (1976-), male, PhD, lecturer. E-mail: wang730304@163.com
Supported by:
National Natural Science Foundation of China(21876048);Fundamental Research Funds for the Central Universities(2018MS114);Open Fund of National Defense Key Discipline Laboratory of Nuclear Waste and Environmental Security(17kfhk01)

摘要/Abstract

摘要：

石墨相氮化碳材料作为一种重要的二维层状材料, 在光催化、能源存储和环境污染治理等领域引起了广泛关注。氮化碳基复合材料以其稳定的物理化学性质、低成本和环境友好等特点成为不同领域的研究热点。在过去几年中, 氮化碳及其氮化碳基复合材料的制备、性质表征和不同领域应用取得了重要进展。本文总结了近几年氮化碳基复合材料的制备及掺杂和功能化研究, 及其在重金属离子废水中的去除应用, 以及不同研究方法对吸附机理的分析。最后还总结了氮化碳基材料在未来研究和应用中面临的主要问题、挑战和机遇。

关键词: 氮化碳, 吸附, 重金属离子, 作用机理, 综述

Abstract:

Graphitic-like carbon nitride (g-C₃N₄), one of the most significant two-dimensional layered materials, has attracted worldwide attention in multidisciplinary areas such as photocatalysis, energy conversion and environmental pollution management. Its derivative compounds have also attracted multifarious attention owing to the intrinsic characters of their stable physicochemical properties, low cost and environmentally friendly features. This review focus on the design of high-performance g-C₃N₄-based nanomaterials and their potential for pollutant elimination in environmental pollution cleanup. Over the past few years, signi?cant advances have been achieved to synthesize g-C₃N₄ and g-C₃N₄-based nanomaterials, and their properties have been enhanced and characterized in detail. In this review, recent developments in the synthesis and modification of g-C₃N₄-based nanomaterials are summarized. The applications in heavy metal ions adsorption from wastewaters are gathered and their underlying reaction mechanisms are discussed. Finally, a summary and outlook are also briefly illustrated.

Key words: carbon nitride, adsorption, heavy metal ions, interaction mechanism, review

中图分类号:

X591

王祥学, 李星, 王佳琦, 朱洪涛. 氮化碳基纳米复合材料在重金属去除方面研究进展[J]. 无机材料学报, 2020, 35(3): 260-270.

WANG Xiangxue, LI Xing, WANG Jiaqi, ZHU Hongtao. Recent Advances in Carbon Nitride-based Nanomaterials for the Removal of Heavy Metal Ions from Aqueous Solution[J]. Journal of Inorganic Materials, 2020, 35(3): 260-270.

图/表 5

参考文献 61

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g-C₃N₄-based material	Adsorbate	(m/V)/(g·L^-1)	pH	C₀/(mg·L^-1)	Time/h	T/K	Q_max/(mg·g^-1)	Interaction mechanism	Ref.
g-C₃N₄	Pb(II)	3.0	3.5	20	1	298	282	Inner-sphere surface complexation	[46]
	Cu(II)						134
	Cd(II)						112
	Ni(II)						38
Coral reef-like g-C₃N₄	Pb(II)	0.2	5	10	2		720	Surface complexation	[31]
	Cd(II)		5				480
	As(V)		3				220
g-C₃N₄/β-CD	Pb(II)	0.3	5.5	10	20	298	101	Complexation and electrostatic interaction	[48]
S-g-C₃N₄	Pb(II)	0.2	4.5	10	2	298	53	Inner-sphere complexation	[52]
BCN NS	Pb(II)	0.4	7	108.0	0.7	298	211	Electrostatic interaction and molecular interaction	[53]
BCN NS	Hg(II)	0.4	7	307.8	0.7	298	625	Electrostatic interaction and molecular interaction	[53]
Fe₃O₄&g-C₃N₄	Pb(II)	1	6	200	1	298	424	Conjugation	[54]
GNS	Pb(II)	1	5.1		0.7		407	Ion exchange	[56]
GNS	Cd(II)	1	6.2		0.7		73	Ion exchange	[56]
2D-g-C₃N₄ nanosheets	Cd(II)	0.3	7	200	5	318.5	94	π-π conjugate interaction and electrostatic attraction	[57]
BCN	Cd(II)	2	5	11	0.2		159	Complexation	[59]
OM g-C₃N₄	U(VI)	0.2	4	10	1	298	150	Chemisorption	[32]
l-C₃N₄/PDA/PEI₃	U(VI)	0.5	5	40	10	298	101	Inner-sphere complexation and surface co-precipitation	[49]

g-C₃N₄-based material	Adsorbate	(m/V)/(g·L^-1)	pH	C₀/(mg·L^-1)	Time/h	T/K	Q_max/(mg·g^-1)	Interaction mechanism	Ref.
g-C₃N₄	Pb(II)	3.0	3.5	20	1	298	282	Inner-sphere surface complexation	[46]
	Cu(II)						134
	Cd(II)						112
	Ni(II)						38
Coral reef-like g-C₃N₄	Pb(II)	0.2	5	10	2		720	Surface complexation	[31]
	Cd(II)		5				480
	As(V)		3				220
g-C₃N₄/β-CD	Pb(II)	0.3	5.5	10	20	298	101	Complexation and electrostatic interaction	[48]
S-g-C₃N₄	Pb(II)	0.2	4.5	10	2	298	53	Inner-sphere complexation	[52]
BCN NS	Pb(II)	0.4	7	108.0	0.7	298	211	Electrostatic interaction and molecular interaction	[53]
BCN NS	Hg(II)	0.4	7	307.8	0.7	298	625	Electrostatic interaction and molecular interaction	[53]
Fe₃O₄&g-C₃N₄	Pb(II)	1	6	200	1	298	424	Conjugation	[54]
GNS	Pb(II)	1	5.1		0.7		407	Ion exchange	[56]
GNS	Cd(II)	1	6.2		0.7		73	Ion exchange	[56]
2D-g-C₃N₄ nanosheets	Cd(II)	0.3	7	200	5	318.5	94	π-π conjugate interaction and electrostatic attraction	[57]
BCN	Cd(II)	2	5	11	0.2		159	Complexation	[59]
OM g-C₃N₄	U(VI)	0.2	4	10	1	298	150	Chemisorption	[32]
l-C₃N₄/PDA/PEI₃	U(VI)	0.5	5	40	10	298	101	Inner-sphere complexation and surface co-precipitation	[49]

氮化碳基纳米复合材料在重金属去除方面研究进展

Recent Advances in Carbon Nitride-based Nanomaterials for the Removal of Heavy Metal Ions from Aqueous Solution

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