无机材料学报 ›› 2019, Vol. 34 ›› Issue (6): 573-589.DOI: 10.15541/jim20180403
• 综述 • 下一篇
李纳1,刘斌1,施佼佼1,薛艳艳1,赵衡煜1,施张丽1,侯文涛1,徐晓东2(),徐军1(
)
收稿日期:
2018-09-03
修回日期:
2018-10-10
出版日期:
2019-06-20
网络出版日期:
2019-05-23
作者简介:
李 纳(1992-), 女, 博士. E-mail: 1710069@tongji.edu.cn
基金资助:
Na LI1,Bin LIU1,Jiao-Jiao SHI1,Yan-Yan XUE1,Heng-Yu ZHAO1,Zhang-Li SHI1,Wen-Tao HOU1,Xiao-Dong XU2(),Jun Xu1(
)
Received:
2018-09-03
Revised:
2018-10-10
Published:
2019-06-20
Online:
2019-05-23
Supported by:
摘要:
可见光激光在数据存储、光通讯、激光显示、激光医疗、激光打印以及科学研究等领域具有非常重要的应用价值。随着蓝光LD泵浦源的商用化, 直接泵浦稀土离子掺杂激光晶体实现可见光激光输出吸引了人们极大的研究兴趣。目前, 可见光稀土离子主要集中在Pr 3+、Dy 3+、Tb 3+和Sm 3+等。其中, Pr 3+的研究较多, 发光波长涵盖面较广, 发射波段覆盖蓝光、绿光、红光、橙光; Dy 3+和Tb 3+因为能够发射黄光以填补Pr 3+的不足也吸引了广泛的研究; 此外, Sm 3+和Eu 3+也是典型的可见波段稀土发光离子。本文综述了近几年可见波段稀土离子掺杂激光晶体的研究现状, 主要以Pr 3+、Dy 3+、Tb 3+和Sm 3+掺杂YAlO3 (YAP)、Mg : SrAl12O19 (SRA)等晶体为研究对象, 总结了一套适合Pr 3+掺杂材料的判据, 对晶体生长、结构、热学性能、偏振光谱性能和激光性能进行了系统的研究。
中图分类号:
李纳, 刘斌, 施佼佼, 薛艳艳, 赵衡煜, 施张丽, 侯文涛, 徐晓东, 徐军. 可见光波段稀土激光晶体的研究进展[J]. 无机材料学报, 2019, 34(6): 573-589.
Na LI, Bin LIU, Jiao-Jiao SHI, Yan-Yan XUE, Heng-Yu ZHAO, Zhang-Li SHI, Wen-Tao HOU, Xiao-Dong XU, Jun Xu. Research Progress of Rare-earth Doped Laser Crystals in Visible Region[J]. Journal of Inorganic Materials, 2019, 34(6): 573-589.
Transitions | Parameters | LLF | YLF | GLF | LaF3 | BYF | LMA | ASL | YAP | SRA | ||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Absorption | ||||||||||||
3H4→3P2 | labs/nm σabs /(×10-20, cm2) FWHMabs /nm | 444 10.3 1.70 | 444 9.0 1.80 | 444 7.8 1.9 | 442 1.6 5 | 445 3.7 - | 444 1.2 7.1 | 444 1.3 - | 449 5.64 5.6 | 445 1.14 9.59 | ||
Emission | ||||||||||||
3P1→3H5 | lem/nm σem /(×10-20, cm2) FWHMem /nm σemτf /(×10-20, cm2·μs) | 522 3 ~2 113.7 | 522 3 ~2 107.1 | 522 3 1 130.8 | 537 0.7 ~3 35.7 | 522 0.4 ~4 17.9 | 530 0.25 4 8.6 | 542 2 - 76 | 533 8.8 1.9 168.6 | 525 1.35 9.8 41.5 | ||
3P0→3H6 | lem/nm σem /(×10-20, cm2) FWHMem /nm σemτf /(×10-20, cm2·μs) | 607 12 ~3 454.8 | 607 14 ~3 499.8 | 607 13 - 566.8 | 610 2.9 ~6.9 147.9 | 607 24.7 1.2 1062.1 | 625 3.7 11 127.7 | 620 2.9 - 110.2 | 621 25.01 1.56 479.2 | 622 3.52 6.53 108.3 | ||
3P0→3F2 | lem/nm σem /(×10-20, cm2) FWHMem /nm σemτf /(×10-20, cm2·μs) | 640 21 ~0.7 795.9 | 640 22 ~0.7 785.4 | 640 23 - 1003 | 635 1.2 ~1 61.2 | 639 12.1 0.6 520.3 | 647 2.3 6.6 79.4 | 643 8.5 - 323 | 662 4.71 1.28 90.2 | 644 10.37 5.07 319.0 | ||
3P0→3F4 | lem/nm σem /(×10-20, cm2) FWHMem /nm σemτf /(×10-20, cm2·μs) | 720 7 ~1 265.3 | 720 9 ~1 321.3 | 720 16 - 697.6 | 720 6.6 ~3 336.6 | 721 7.3 1.3 309.6 | 728 3.3 8.5 113.9 | 725 11 - 418 | 747 10.37 1.54 198.7 | 725 5.75 4.35 176.9 | ||
τf/μs | 37.90 | 35.70 | 43.6 | 51 | 43 | 34.5 | 38 | 19.16 | 30.76 | |||
Ref. | [23] | [23] | [23] | [24] | [25-26] | [27] | [28] | This work |
表1 Pr : YAP、Pr : SRA和其他已实现Pr3+激光输出晶体的光谱参数
Table 1 Lasing wavelength λem, emission cross-section σem and σemτ for the 3P0→3H6 transition of Pr3+ doped YAP and other crystals
Transitions | Parameters | LLF | YLF | GLF | LaF3 | BYF | LMA | ASL | YAP | SRA | ||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Absorption | ||||||||||||
3H4→3P2 | labs/nm σabs /(×10-20, cm2) FWHMabs /nm | 444 10.3 1.70 | 444 9.0 1.80 | 444 7.8 1.9 | 442 1.6 5 | 445 3.7 - | 444 1.2 7.1 | 444 1.3 - | 449 5.64 5.6 | 445 1.14 9.59 | ||
Emission | ||||||||||||
3P1→3H5 | lem/nm σem /(×10-20, cm2) FWHMem /nm σemτf /(×10-20, cm2·μs) | 522 3 ~2 113.7 | 522 3 ~2 107.1 | 522 3 1 130.8 | 537 0.7 ~3 35.7 | 522 0.4 ~4 17.9 | 530 0.25 4 8.6 | 542 2 - 76 | 533 8.8 1.9 168.6 | 525 1.35 9.8 41.5 | ||
3P0→3H6 | lem/nm σem /(×10-20, cm2) FWHMem /nm σemτf /(×10-20, cm2·μs) | 607 12 ~3 454.8 | 607 14 ~3 499.8 | 607 13 - 566.8 | 610 2.9 ~6.9 147.9 | 607 24.7 1.2 1062.1 | 625 3.7 11 127.7 | 620 2.9 - 110.2 | 621 25.01 1.56 479.2 | 622 3.52 6.53 108.3 | ||
3P0→3F2 | lem/nm σem /(×10-20, cm2) FWHMem /nm σemτf /(×10-20, cm2·μs) | 640 21 ~0.7 795.9 | 640 22 ~0.7 785.4 | 640 23 - 1003 | 635 1.2 ~1 61.2 | 639 12.1 0.6 520.3 | 647 2.3 6.6 79.4 | 643 8.5 - 323 | 662 4.71 1.28 90.2 | 644 10.37 5.07 319.0 | ||
3P0→3F4 | lem/nm σem /(×10-20, cm2) FWHMem /nm σemτf /(×10-20, cm2·μs) | 720 7 ~1 265.3 | 720 9 ~1 321.3 | 720 16 - 697.6 | 720 6.6 ~3 336.6 | 721 7.3 1.3 309.6 | 728 3.3 8.5 113.9 | 725 11 - 418 | 747 10.37 1.54 198.7 | 725 5.75 4.35 176.9 | ||
τf/μs | 37.90 | 35.70 | 43.6 | 51 | 43 | 34.5 | 38 | 19.16 | 30.76 | |||
Ref. | [23] | [23] | [23] | [24] | [25-26] | [27] | [28] | This work |
Hosts | λem/nm | Polarizations | Laser transitions | ηslope/% | Pout/mW | Pthr/mW | Pump source | Year |
---|---|---|---|---|---|---|---|---|
YLF | 491 | σ | 3PJ→3H4 | 6 | 70 | 285 | 2w-OPSL | 2014[ |
523 | π | 3PJ→3H5 | 45 | ~4200 | >500 | 2×2w-OPSL | 2016[ | |
546 | π | 3PJ→3H5 | 60 | 2000 | 120 | 2w-OPSL | 2014[ | |
605 | σ | 3PJ→3H6 | 25 | 2100 | ~1500 | Blue-LD | 2017[ 2017[ | |
640 | σ | 3PJ→3F2 | 50 | 4800 | ~500 | Blue-LD | ||
698 | σ | 3PJ→3F3 | 36 | 1300 | 78 | InGaN-LD | 2016[ | |
721 | π | 3PJ→3F4 | 53 | 1000 | 16 | 2w-OPSL | 2014[ | |
LLF | 523 | E//c | 3P0→3H5 | 56 | 52.7 | 10 | 2-OPSL | 2007[ |
607 | E//c | 3P0→3H6 | 31 | 34.5 | 26 | 2-OPSL | 2007[ | |
640 | E//c | 3P0→3F2 | 56 | 52.7 | 39 | 2-OPSL | 2007[ | |
722 | E//c | 3P0→3F4 | 46 | 50 | 31 | 2-OPSL | 2007[ | |
BYF | 495 | E//X | 3PJ→3H4 | 27 | 201 | 163 | 2w-OPSL | 2014[ |
607 | E//Y | 3PJ→3H6 | 12.6 | 99 | 264 | Blue-LD | 2014[ | |
639 | E//Y | 3PJ→3F2 | 6.4 | 60 | 146 | Blue-LD | 2014[ | |
KYF | 554 | - | 3PJ→3H5 | 27 | 121 | 166 | InGaN-LD | 2013[ |
610 | - | 3PJ→3H6 | 18 | 97 | 162 | InGaN-LD | 2013[ | |
645 | - | 3PJ→3F2 | 38 | 268 | 30 | InGaN-LD | 2013[ | |
YGF | 523 | E//a | 3PJ→3H5 | 11 | 63 | 148 | InGaN-LD | 2015[ |
538 | E//b | 3PJ→3H5 | 24 | 140 | 135 | InGaN-LD | 2015[ | |
604 | E//a | 3PJ→3H6 | 13 | 105 | 72 | InGaN-LD | 2015[ | |
638 | E//a | 3PJ→3F2 | 16 | 128 | 188 | InGaN-LD | 2015[ | |
700 | E//a | 3PJ→3F4 | 18 | 78 | 47 | InGaN-LD | 2015[ | |
724 | E//b | 3PJ→3F4 | 20 | 117 | 48 | InGaN-LD | 2015[ | |
CaF2 | 642 | - | 3PJ→3F2 | 7.5 | 22 | 305 | InGaN-LD | 2017[ |
LaF3 | 537 | π | 3PJ→3H5 | 16 | 15 | 159 | InGaN-LD | 2012[ |
612 | π | 3PJ→3H6 | 15 | 20 | 98 | InGaN-LD | 2012[ | |
635 | c | 3PJ→3F2 | 16 | 23 | 95 | InGaN-LD | 2012[ | |
720 | π | 3PJ→3F4 | 37 | 80 | 10 | InGaN-LD | 2012[ | |
ASL | 620 | π | 3PJ→3H6 | 11 | 50 | ~510 | 2w-OPSL | 2018[ 2018[ 2018[ |
643 | π | 3PJ→3F2 | 27 | 160 | ~200 | 2w-OPSL | ||
725 | π | 3PJ→3F4 | 37 | 318 | ~280 | 2w-OPSL | ||
LMA | 620 | σ | 3PJ→3H6 | 2 | 2.9 | ~100 | 2w-OPSL | 2012[ |
648 | σ | 3PJ→3F2 | 4 | 10.1 | ~90 | 2w-OPSL | 2012[ | |
729 | σ | 3PJ→3F4 | 12 | 63.7 | ~25 | 2w-OPSL | 2012[ | |
YAP | 547 | E//c | 3PJ→3H5 | 6.1 | 37 | 320 | InGaN-LD | 2013[ |
662 | E//c | 3PJ→3F2 | 9 | 27.4 | 680 | GaN-LD | 2011[ | |
747 | E//b | 3PJ→3F4 | 45 | 490 | 300 | 2×InGaN-LD | 2014[ | |
SRA | 525 | - | 3PJ→3H5 | - | 36 | ~1000 | 2w-OPSL | 2013[ |
623 | σ | 3PJ→3H6 | 11 | 114 | ~200 | 4×InGaN-LD | 2014[ | |
644 | - | 3PJ→3F2 | 37 | 1065 | ~500 | 2w-OPSL | 2013[ | |
724 | σ | 3PJ→3F4 | 50 | 564 | 15.5 | 4×InGaN-LD | 2014[ |
表2 Pr3+掺杂激光晶体在可见波段的连续激光输出
Table 2 Visible laser output of Pr3+ doped crystals
Hosts | λem/nm | Polarizations | Laser transitions | ηslope/% | Pout/mW | Pthr/mW | Pump source | Year |
---|---|---|---|---|---|---|---|---|
YLF | 491 | σ | 3PJ→3H4 | 6 | 70 | 285 | 2w-OPSL | 2014[ |
523 | π | 3PJ→3H5 | 45 | ~4200 | >500 | 2×2w-OPSL | 2016[ | |
546 | π | 3PJ→3H5 | 60 | 2000 | 120 | 2w-OPSL | 2014[ | |
605 | σ | 3PJ→3H6 | 25 | 2100 | ~1500 | Blue-LD | 2017[ 2017[ | |
640 | σ | 3PJ→3F2 | 50 | 4800 | ~500 | Blue-LD | ||
698 | σ | 3PJ→3F3 | 36 | 1300 | 78 | InGaN-LD | 2016[ | |
721 | π | 3PJ→3F4 | 53 | 1000 | 16 | 2w-OPSL | 2014[ | |
LLF | 523 | E//c | 3P0→3H5 | 56 | 52.7 | 10 | 2-OPSL | 2007[ |
607 | E//c | 3P0→3H6 | 31 | 34.5 | 26 | 2-OPSL | 2007[ | |
640 | E//c | 3P0→3F2 | 56 | 52.7 | 39 | 2-OPSL | 2007[ | |
722 | E//c | 3P0→3F4 | 46 | 50 | 31 | 2-OPSL | 2007[ | |
BYF | 495 | E//X | 3PJ→3H4 | 27 | 201 | 163 | 2w-OPSL | 2014[ |
607 | E//Y | 3PJ→3H6 | 12.6 | 99 | 264 | Blue-LD | 2014[ | |
639 | E//Y | 3PJ→3F2 | 6.4 | 60 | 146 | Blue-LD | 2014[ | |
KYF | 554 | - | 3PJ→3H5 | 27 | 121 | 166 | InGaN-LD | 2013[ |
610 | - | 3PJ→3H6 | 18 | 97 | 162 | InGaN-LD | 2013[ | |
645 | - | 3PJ→3F2 | 38 | 268 | 30 | InGaN-LD | 2013[ | |
YGF | 523 | E//a | 3PJ→3H5 | 11 | 63 | 148 | InGaN-LD | 2015[ |
538 | E//b | 3PJ→3H5 | 24 | 140 | 135 | InGaN-LD | 2015[ | |
604 | E//a | 3PJ→3H6 | 13 | 105 | 72 | InGaN-LD | 2015[ | |
638 | E//a | 3PJ→3F2 | 16 | 128 | 188 | InGaN-LD | 2015[ | |
700 | E//a | 3PJ→3F4 | 18 | 78 | 47 | InGaN-LD | 2015[ | |
724 | E//b | 3PJ→3F4 | 20 | 117 | 48 | InGaN-LD | 2015[ | |
CaF2 | 642 | - | 3PJ→3F2 | 7.5 | 22 | 305 | InGaN-LD | 2017[ |
LaF3 | 537 | π | 3PJ→3H5 | 16 | 15 | 159 | InGaN-LD | 2012[ |
612 | π | 3PJ→3H6 | 15 | 20 | 98 | InGaN-LD | 2012[ | |
635 | c | 3PJ→3F2 | 16 | 23 | 95 | InGaN-LD | 2012[ | |
720 | π | 3PJ→3F4 | 37 | 80 | 10 | InGaN-LD | 2012[ | |
ASL | 620 | π | 3PJ→3H6 | 11 | 50 | ~510 | 2w-OPSL | 2018[ 2018[ 2018[ |
643 | π | 3PJ→3F2 | 27 | 160 | ~200 | 2w-OPSL | ||
725 | π | 3PJ→3F4 | 37 | 318 | ~280 | 2w-OPSL | ||
LMA | 620 | σ | 3PJ→3H6 | 2 | 2.9 | ~100 | 2w-OPSL | 2012[ |
648 | σ | 3PJ→3F2 | 4 | 10.1 | ~90 | 2w-OPSL | 2012[ | |
729 | σ | 3PJ→3F4 | 12 | 63.7 | ~25 | 2w-OPSL | 2012[ | |
YAP | 547 | E//c | 3PJ→3H5 | 6.1 | 37 | 320 | InGaN-LD | 2013[ |
662 | E//c | 3PJ→3F2 | 9 | 27.4 | 680 | GaN-LD | 2011[ | |
747 | E//b | 3PJ→3F4 | 45 | 490 | 300 | 2×InGaN-LD | 2014[ | |
SRA | 525 | - | 3PJ→3H5 | - | 36 | ~1000 | 2w-OPSL | 2013[ |
623 | σ | 3PJ→3H6 | 11 | 114 | ~200 | 4×InGaN-LD | 2014[ | |
644 | - | 3PJ→3F2 | 37 | 1065 | ~500 | 2w-OPSL | 2013[ | |
724 | σ | 3PJ→3F4 | 50 | 564 | 15.5 | 4×InGaN-LD | 2014[ |
Hosts | σabs/(×10-21, cm2) | β/% | σem/(×10-20, cm2) | τf/μs | Ref. |
---|---|---|---|---|---|
YAG | 1.6 | 50.96 | 1.50 | 376 | [64] |
YAl(BO3)4 | - | 65.90 | 1.90 | 520 | [65] |
LiLuF4 | - | 65.40 | 1.02 | 582 | [66] |
Lu2SiO4 | - | 61.0 | 0.74 | 509 | [67] |
KY3F10 | - | 59.8 | 0.83 | 440 | [66] |
Li2Gd4(MoO4)7 | σ: 2.5 π: 4.4 | σ:72.0 π: 71.9 | σ: 1.45 π: 1.34 | 139 | [68] |
YAP | a:0.743 b:0.690 c:0.870 | a:88.5 b:88.7 c:87.8 | a:0.298 b:0.450 c:0.452 | 185 | This work |
表3 Dy : YAP晶体与Dy3+掺杂其他基质的光谱参数
Table 3 Spectroscopic parameters of Dy3+ doped YAP and other crystals
Hosts | σabs/(×10-21, cm2) | β/% | σem/(×10-20, cm2) | τf/μs | Ref. |
---|---|---|---|---|---|
YAG | 1.6 | 50.96 | 1.50 | 376 | [64] |
YAl(BO3)4 | - | 65.90 | 1.90 | 520 | [65] |
LiLuF4 | - | 65.40 | 1.02 | 582 | [66] |
Lu2SiO4 | - | 61.0 | 0.74 | 509 | [67] |
KY3F10 | - | 59.8 | 0.83 | 440 | [66] |
Li2Gd4(MoO4)7 | σ: 2.5 π: 4.4 | σ:72.0 π: 71.9 | σ: 1.45 π: 1.34 | 139 | [68] |
YAP | a:0.743 b:0.690 c:0.870 | a:88.5 b:88.7 c:87.8 | a:0.298 b:0.450 c:0.452 | 185 | This work |
Crystals | λem/nm | Polarizations | Laser transitions | ηslope/% | Pout/mW | Pthr/mW | Type | Year |
---|---|---|---|---|---|---|---|---|
Dy,Tb : LLF | 574 | σ | 4F9/2→6H13/2 | 13 | 55 | 320 | CW | 2014[ |
Dy,Eu : YLF | 574 | σ | 4F9/2→6H13/2 | 10 | 47 | 244 | CW | 2016[ 2016[ 2016[ |
Dy : LLF | 578 | σ | 4F9/2→6H13/2 | 4 | 17 | 188 | Self-pulsed | |
661 | π | 4F9/2→6H11/2 | 2 | 4 | 143 | Self-pulsed | ||
Dy : YAG | 583 | - | 4F9/2→6H13/2 | 12 | 150 | - | Self-pulsed | 2012[ |
Dy : ZnWO4 | 575 | E//b | 4F9/2→6H13/2 | 13 | 110 | 550 | CW | 2017[ |
表4 掺Dy3+激光晶体在可见波段的激光输出
Table 4 Laser output of Dy3+ doped some common laser crystal
Crystals | λem/nm | Polarizations | Laser transitions | ηslope/% | Pout/mW | Pthr/mW | Type | Year |
---|---|---|---|---|---|---|---|---|
Dy,Tb : LLF | 574 | σ | 4F9/2→6H13/2 | 13 | 55 | 320 | CW | 2014[ |
Dy,Eu : YLF | 574 | σ | 4F9/2→6H13/2 | 10 | 47 | 244 | CW | 2016[ 2016[ 2016[ |
Dy : LLF | 578 | σ | 4F9/2→6H13/2 | 4 | 17 | 188 | Self-pulsed | |
661 | π | 4F9/2→6H11/2 | 2 | 4 | 143 | Self-pulsed | ||
Dy : YAG | 583 | - | 4F9/2→6H13/2 | 12 | 150 | - | Self-pulsed | 2012[ |
Dy : ZnWO4 | 575 | E//b | 4F9/2→6H13/2 | 13 | 110 | 550 | CW | 2017[ |
Host | labs/nm | σabs/(×10-22, cm2) | lem/nm | σem/(×10-22, cm2) | τf/ms | Ref. | |
---|---|---|---|---|---|---|---|
LLF | 488.8 | 3.0 | 585 | ~11 | 4.8 | [76] | |
TPP | 485 | 1.3 | 587 | 1.0 | 3.4 | [75] | |
TLP | 487 | 2.2 | 588 | 1.0 | 3.7 | [75] | |
TAB | 483 | 3.6 | 592 | 1.0 | 0.8 | [75] | |
PZABP | - | - | 582 | 0.7 | 0.42 | [77] | |
LBTAF | - | - | 585 | 0.58 | 1.27 | [78] | |
YAP | E//a | 486 | 3.3 | 590 | 1.72 | 1.72 | This work |
E//b | 484 | 5.2 | 591 | 2.73 | |||
E//c | 484 | 4.1 | 588 | 2.65 |
表5 Tb : YAP晶体与Tb3+掺杂其他材料的光谱参数
Table 5 Spectroscopic parameters of Tb3+ doped YAP and other crystals
Host | labs/nm | σabs/(×10-22, cm2) | lem/nm | σem/(×10-22, cm2) | τf/ms | Ref. | |
---|---|---|---|---|---|---|---|
LLF | 488.8 | 3.0 | 585 | ~11 | 4.8 | [76] | |
TPP | 485 | 1.3 | 587 | 1.0 | 3.4 | [75] | |
TLP | 487 | 2.2 | 588 | 1.0 | 3.7 | [75] | |
TAB | 483 | 3.6 | 592 | 1.0 | 0.8 | [75] | |
PZABP | - | - | 582 | 0.7 | 0.42 | [77] | |
LBTAF | - | - | 585 | 0.58 | 1.27 | [78] | |
YAP | E//a | 486 | 3.3 | 590 | 1.72 | 1.72 | This work |
E//b | 484 | 5.2 | 591 | 2.73 | |||
E//c | 484 | 4.1 | 588 | 2.65 |
Crystals | λem/nm | Polarizations | Laser transitions | ηslope/% | Pout/mW | Pthr/mW | Pump source | Year |
---|---|---|---|---|---|---|---|---|
Tb : YLF | 542 | σ | 5D4→7F5 | 55 | 158 | 8 | 2w-OPSL | 2016[ |
587 | π | 5D4→7F4 | 22 | 71 | 32 | 2w-OPSL | ||
Tb : LLF | 542 | σ | 5D4→7F5 | 52 | 1130 | 32 | 2w-OPSL | |
587 | π | 5D4→7F4 | 14 | 82 | 107 | 2w-OPSL | ||
Tb : KYF | 545 | σ | 5D4→7F5 | 34 | 793 | 25 | 2w-OPSL | |
584 | π | 5D4→7F4 | 5 | 18 | 38 | 2w-OPSL | ||
Tb : BLuF | 546 | σ | 5D4→7F5 | 46 | 270 | 18 | 2w-OPSL | |
Tb : CaF2 | 541 | - | 5D4→7F5 | 48 | 103 | ~34 | 2w-OPSL | 2017[ |
表6 掺Tb3+激光晶体室温下的可见波段连续激光输出
Table 6 Laser output of Tb3+ doped some common laser crystal
Crystals | λem/nm | Polarizations | Laser transitions | ηslope/% | Pout/mW | Pthr/mW | Pump source | Year |
---|---|---|---|---|---|---|---|---|
Tb : YLF | 542 | σ | 5D4→7F5 | 55 | 158 | 8 | 2w-OPSL | 2016[ |
587 | π | 5D4→7F4 | 22 | 71 | 32 | 2w-OPSL | ||
Tb : LLF | 542 | σ | 5D4→7F5 | 52 | 1130 | 32 | 2w-OPSL | |
587 | π | 5D4→7F4 | 14 | 82 | 107 | 2w-OPSL | ||
Tb : KYF | 545 | σ | 5D4→7F5 | 34 | 793 | 25 | 2w-OPSL | |
584 | π | 5D4→7F4 | 5 | 18 | 38 | 2w-OPSL | ||
Tb : BLuF | 546 | σ | 5D4→7F5 | 46 | 270 | 18 | 2w-OPSL | |
Tb : CaF2 | 541 | - | 5D4→7F5 | 48 | 103 | ~34 | 2w-OPSL | 2017[ |
Sample | labs/nm | σabs/(×10-20, cm2) | FWHMabs /nm | lem/nm | σem/(×10-21, cm2) | FWHMem/nm | τf/ms | Ref. |
---|---|---|---|---|---|---|---|---|
Sm : SrAl12O19 | 400(σ) | 8.5(σ) | - | 593(σ) | 1.2(σ) | - | 3.4 | [88] |
Sm : LiLuF4 | 401(σ) | 1.04(σ) | 2.3(σ) | 606(π) | 1.3(π) | 7.5(σ) | 4.8 | [87-88] |
401(π) | 1.51(π) | 3.1(π) | 9.5(π) | |||||
Sm : LiYF4 | 401(σ) | 0.72(σ) | 3(σ) | 597(σ) | 0.679(σ) | 7.5(σ) | 4.8 | [86] |
401(π) | 1.37(π) | 2(π) | 605(π) | 1.039(π) | 9.5(π) | |||
Sm : YAP | 409(E//a) | 0.25(E//a) | 8.4(E//a) | 604(E//a) | 0.47(E//a) | 6.29(E//a) | 0.59 | This work |
409(E//b) | 0.67(E//b) | 10.2(E//b) | 604(E//b) | 1.01(E//b) | 6.32(E//b) | |||
409(E//c) | 0.86(E//c) | 9.4(E//c) | 610(E//c) | 0.96(E//c) | 3.26(E//c) |
表7 Sm : YAP晶体与Sm3+掺杂其他材料的光谱参数
Table 7 Spectroscopic parameters of Sm3+ doped YAP and other crystals
Sample | labs/nm | σabs/(×10-20, cm2) | FWHMabs /nm | lem/nm | σem/(×10-21, cm2) | FWHMem/nm | τf/ms | Ref. |
---|---|---|---|---|---|---|---|---|
Sm : SrAl12O19 | 400(σ) | 8.5(σ) | - | 593(σ) | 1.2(σ) | - | 3.4 | [88] |
Sm : LiLuF4 | 401(σ) | 1.04(σ) | 2.3(σ) | 606(π) | 1.3(π) | 7.5(σ) | 4.8 | [87-88] |
401(π) | 1.51(π) | 3.1(π) | 9.5(π) | |||||
Sm : LiYF4 | 401(σ) | 0.72(σ) | 3(σ) | 597(σ) | 0.679(σ) | 7.5(σ) | 4.8 | [86] |
401(π) | 1.37(π) | 2(π) | 605(π) | 1.039(π) | 9.5(π) | |||
Sm : YAP | 409(E//a) | 0.25(E//a) | 8.4(E//a) | 604(E//a) | 0.47(E//a) | 6.29(E//a) | 0.59 | This work |
409(E//b) | 0.67(E//b) | 10.2(E//b) | 604(E//b) | 1.01(E//b) | 6.32(E//b) | |||
409(E//c) | 0.86(E//c) | 9.4(E//c) | 610(E//c) | 0.96(E//c) | 3.26(E//c) |
图15 Pr3+、Dy3+、Tb3+、Sm3+、Ho3+、Er3+、Eu3+掺杂激光材料的输出功率与发射波长关系图
Fig. 15 Output power vs laser wavelength of Pr3+, Dy3+, Tb3+, Sm3+, Ho3+, Er3+, Eu3+ doped some common crystals
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