不同形貌纳米NiCo2O4的研究进展

doi:10.15541/jim20180277

摘要/Abstract

摘要：

纳米NiCo₂O₄因其独特的理化性能已广泛应用于能源储存与转换, 尤其是超级电容器领域。鉴于纳米材料的形貌对其性能的重要影响, 本文综述了不同形貌(纳米针、纳米线、纳米管、纳米片、球状、纳米花、珊瑚状及三维复合结构)纳米NiCo₂O₄的合成方法及其在相关领域的应用, 叙述了各种制备方法的基本原理、特点以及对纳米NiCo₂O₄形貌的调控规律。同时, 简要说明了材料形貌与尺寸对其性能影响的机理及规律。最后, 展望了纳米NiCo₂O₄在能源储存与转换领域中未来的发展方向。

关键词: 纳米, NiCo₂O₄, 形貌, 制备, 综述

Abstract:

NiCo₂O₄ nanomaterials exhibit great potential in the fields of energy storage and conversion especially in supercapacitors for their unique physicochemical properties. Given the important impact of morphology of nano material on its performance, this review focuses on preparation methods and application of NiCo₂O₄ nanostructure with various morphologies including nanoneedle, nanowire, nanotube, nanosheet, sphere, nanoflower, coral-like structure and three-dimensional hybrid structure. Furthermore, the influence of morphology and particle size of NiCo₂O₄ on its properties is also introduced. Finally, the future research direction of NiCo₂O₄ nanomaterials in the fields of energy storage and conversion is prospected.

Key words: nanometer, NiCo₂O₄, morphologies, preparation, review

中图分类号:

TQ174

万宇驰,湛菁,陈军. 不同形貌纳米NiCo₂O₄的研究进展[J]. 无机材料学报, 2019, 34(2): 121-129.

WAN Yu-Chi, ZHAN Jing, CHEN Jun. Preparation of NiCo₂O₄ with Various Morphologies: a Review[J]. Journal of Inorganic Materials, 2019, 34(2): 121-129.

图/表 9

图1 水热法制备NiCo2O4微球煅烧(a)前(b)~(c)后的SEM照片; (d) NiCo2O4粉末XRD图谱[34]

Fig. 1 SEM images of NiCo2O4 microsphere prepared by hydrothermal method: (a) before and (b, c) after calcination with (d) XRD patterns of NiCo2O4 powders[34]

图2 Ni/Co摩尔比为 (a) 1 : 0、 (b) 7 : 3、(c) 5 : 5、(d) 3 : 7和(e)~(f) 0 : 1的花状结构镍钴氧化物的SEM照片[43]

Fig. 2 SEM images of flower-like nickel-cobalt oxides prepared with initial Ni/Co molar ratio of (a) 1 : 0, (b) 7 : 3, (c) 5 : 5, (d) 3 : 7 and (e, f) 0 : 1[43]

图3 (a)~(b) 微波辅助法获得的花状NiCo2O4的SEM照片, (c) 花状形貌形成过程示意图[46]

Fig. 3 (a, b) SEM images of flower-shaped NiCo2O4 prepared by microwave-assisted approach, (c) schematic illustration of the morphological evolution of flower-shaped microsphere precursors[46]

图4 (a)~(b) N-CNT/NiCo2O4 纳米片的TEM照片和 (c) N- CNT/NiCo2O4的制备过程示意图[57]

Fig. 4 (a, b) TEM images of the N-CNT/NiCo2O4 nanosheets, (c) schematic diagram of the fabrication process of N-CNT/ NiCo2O4[57]

图5 Co3O4@NiCo2O4纳米复合物的制备过程示意图[60]

Fig. 5 Illustration of the fabrication process of Co3O4@NiCo2O4[60]

图6 电沉积法制备的NiCo2O4纳米片在煅烧(a)~(b)前、(c)~(d)后的SEM照片; (e)NiCo2O4纳米片上电子与离子传递示意图[71]

Fig. 6 SEM images of NiCo2O4 nanosheets prepared by electrodeposition: (a, b) before and (c, d) after calcination, and (e) schematic illustration of the transportation of species on porous NiCo2O4 nanosheets[71]

图7 碳基NiCo2O4纳米线阵列前驱体的(a)低倍和(b)高倍SEM照片; 碳基NiCo2O4纳米线阵列的(c)低倍和(d)高倍SEM照片; (e)碳基NiCo2O4纳米线阵列的合成示意图[81]

Fig. 7 SEM images of the NiCo2O4 precursor NWAs/carbon textiles composite: (a) low and (b) high magnification, SEM images of the NiCo2O4 NWAs/carbon textiles composite: (c) low and (d) high magnification, and (e) schematic illustration of the formation of NiCo2O4 NWAs/carbon textiles composite[81]

图8 (a)~(b)NiCo2O4纳米管SEM照片, (c)NiCo2O4纳米管、纳米线、纳米环的制备过程示意图[86]

Fig. 8 (a, b) SEM images of the NiCo2O4 nanotubes and (c) schematic illustration of preparation of NiCo2O4 nanofibers, nanotubes and nanobelts[86]

图9 不同反应时间得到NiCo2O4样品的TEM照片: (a) 4 h, (b) 6 h, (c) 10 h, (d) 12 h; (e) NiCo2O4分层四方微管制备过程示意图[87]

Fig. 9 Representative TEM images of the samples obtained after reaction for (a) 4 h, (b) 6 h, (c) 10 h, (d) 12 h and (e) their corresponding schematic illustration of the formation process for hierarchical NiCo2O4 tetragonal microtubes[87]

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不同形貌纳米NiCo₂O₄的研究进展

Preparation of NiCo₂O₄ with Various Morphologies: a Review

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