无铅非线性介电储能陶瓷: 现状与挑战

doi:10.15541/jim20170594

无机材料学报 ›› 2018, Vol. 33 ›› Issue (10): 1046-1058.DOI: 10.15541/jim20170594

所属专题：介电储能陶瓷

无铅非线性介电储能陶瓷: 现状与挑战

杜红亮¹, 杨泽田¹, 高峰², 靳立³, 程花蕾⁴, 屈绍波¹

1.空军工程大学理学院, 西安 710051;
2.西北工业大学凝固技术国家重点实验室, 西安 710073;
3.西安交通大学电子陶瓷与器件教育部重点实验室, 西安 710049;
4.宝鸡文理学院化学与化工学院, 宝鸡 721013

收稿日期:2017-12-12 修回日期:2018-02-06 出版日期:2018-10-20 网络出版日期:2018-09-25
基金资助:
国家自然科学基金(21501007);陕西省自然科学基金(2017JM5016);西北工业大学凝固技术国家重点实验室开放课题(SKLSP201709, SKLSP201718)

Lead-free Nonlinear Dielectric Ceramics for Energy Storage Applications: Current Status and Challenges

DU Hong-Liang¹, YANG Ze-Tian¹, GAO Feng², JIN Li³, CHENG Hua-Lei⁴, QU Shao-Bo¹

1.Science College, Air Force Engineering University, Xi’an 710051, China;
2. State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China;
3. Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education & International Center for Dielectric Research, Xi’an Jiaotong University, Xi’an 710049, China;
4. Department of Chemistry, Baoji University of Arts and Science, Baoji 721013, China

Received:2017-12-12 Revised:2018-02-06 Published:2018-10-20 Online:2018-09-25
Supported by:
National Science Foundation of China (21501007);Natural Science Basis Research Plan in Shaanxi Province of China (2017JM5016);The Fund of the State Key Laboratory of Solidification Processing in NWPU(SKLSP201709, SKLSP201718)

摘要/Abstract

摘要：

相对于聚合物等储能介质材料, 介电陶瓷具有温度稳定性好和循环寿命长的优点, 是制备脉冲功率储能电容器的优秀候选材料。但目前介电陶瓷的储能密度相对较低, 不能满足脉冲功率设备小型化的要求。因此, 如何显著提高介电陶瓷的储能密度成为近年来功能陶瓷研究的热点之一。本文首先介绍了介电储能电容器对陶瓷材料性能的要求, 然后结合本课题组的研究工作, 评述了BaTiO₃基、BiFeO₃基、(K_0.5Na_0.5)NbO₃基无铅弛豫铁电陶瓷和 (Bi_0.5Na_0.5)TiO₃基、AgNbO₃基无铅反铁电陶瓷储能特性的研究现状, 重点阐述了不同材料体系的组分设计思路及相关储能特性, 分析了无铅非线性介电储能陶瓷所面临的机遇和挑战, 指出了应对策略。最后, 展望了下一步的研究方向和内容。

关键词: 无铅陶瓷, 储能密度, 击穿场强, 极化差值, 综述

Abstract:

Compared to polymers and their nanocomposites, dielectric ceramics are considered as promising candidates for the pulsed-power devices because of their excellent temperature stability and good anti-fatigue characteristic. Nevertheless, relatively low energy storage density is the main disadvantage for dielectric ceramics, which does not meet the requirement of miniaturization for pulsed-power devices. Therefore, how to improve the energy storage density of dielectric ceramics has become one of hot topics on the research of functional ceramics in recent years. In this paper, the basic principle of the capacitor for electric energy storage was introduced firstly and then the research advances of BaTiO₃-based, BiFeO₃-based, (K_0.5Na_0.5)NbO₃-based lead-free relaxor ceramics and (Bi_0.5Na_0.5)TiO₃-based, and AgNbO₃-based lead-free anti-ferroelectric ceramics were reviewed based on our group’s research, in which the composition design strategies of different material systems were especially summarized. Finally, the opportunities and challenges of lead-free nonlinear energy-storage ceramics were analyzed, and the coping strategies as well as the future development direction were also proposed.

Key words: lead-free ceramics, energy storage density, dielectric breakdown strength, polarization difference, review

中图分类号:

TM534

杜红亮, 杨泽田, 高峰, 靳立, 程花蕾, 屈绍波. 无铅非线性介电储能陶瓷: 现状与挑战[J]. 无机材料学报, 2018, 33(10): 1046-1058.

DU Hong-Liang, YANG Ze-Tian, GAO Feng, JIN Li, CHENG Hua-Lei, QU Shao-Bo. Lead-free Nonlinear Dielectric Ceramics for Energy Storage Applications: Current Status and Challenges[J]. Journal of Inorganic Materials, 2018, 33(10): 1046-1058.

图/表 13

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Materials	E_b/(kV·cm^-1)	ΔP/(µC·cm^-2)	W_rec/(J·cm^-3)	η/%	Ref.
0.7BaTiO₃-0.3BiScO₃	225	25	2.3	-	[48]
0.8(0.6 BaTiO₃-0.4BiScO₃)-0.2(K_1/2Bi_1/2)TiO₃	220	~33.5	4.0	-	[50]
0.91BaTiO₃-0.09BiYbO₃	93	~17	0.71	~87	[52]
0.9BaTiO₃-0.1Bi(Mg_2/3Nb_1/3)O₃	143.5	~15	1.13	~96	[51]
0.88BaTiO₃-0.12Bi(Mg_1/2Ti_1/2)O₃	224	~19	1.81	~88	[23]
0.85BaTiO₃-0.15Bi(Zn_2/3Nb_1/3)O₃	131	7.9	0.79	93.5	[53]
0.88BaTiO₃-0.12Bi(Li_1/2Nb_1/2)O₃	270	13.35	2.032	88	[54]
0.9BaTiO₃-0.1Bi(Zn_1/2Zr_1/2)O₃	264	22.1	2.46	-	[55]

Materials	E_b/(kV·cm^-1)	ΔP/(µC·cm^-2)	W_rec/(J·cm^-3)	η/%	Ref.
0.7BaTiO₃-0.3BiScO₃	225	25	2.3	-	[48]
0.8(0.6 BaTiO₃-0.4BiScO₃)-0.2(K_1/2Bi_1/2)TiO₃	220	~33.5	4.0	-	[50]
0.91BaTiO₃-0.09BiYbO₃	93	~17	0.71	~87	[52]
0.9BaTiO₃-0.1Bi(Mg_2/3Nb_1/3)O₃	143.5	~15	1.13	~96	[51]
0.88BaTiO₃-0.12Bi(Mg_1/2Ti_1/2)O₃	224	~19	1.81	~88	[23]
0.85BaTiO₃-0.15Bi(Zn_2/3Nb_1/3)O₃	131	7.9	0.79	93.5	[53]
0.88BaTiO₃-0.12Bi(Li_1/2Nb_1/2)O₃	270	13.35	2.032	88	[54]
0.9BaTiO₃-0.1Bi(Zn_1/2Zr_1/2)O₃	264	22.1	2.46	-	[55]

Materials	Compositions	Marterial forms	E_b/(kV·cm^-1)	ΔP/(µC·cm^-2)	W_rec/(J·cm^-3)	η/%	Ref.
BF-BT	0.7(0.65BF-0.35BT)-0.3Nb₂O₅	Bulk	90	19.68	0.71	-	[60]
	0.61BF-0.33BT-0.06La(Mg_1/2Ti_1/2)O₃	Bulk	130	33.3	1.66	82	[61]
	0.61BF-0.33BT-0.06Ba(Mg_1/3Nb_2/3)O₃	Bulk	125	32.3	1.56	75	[62]
BF-ST	0.4BF-0.6ST	Thick film	420	-	6	-	[64]
BF-ST	0.4BF-0.6ST+0.5%MnO₂	Thin film	3600	~38	~51	64	[65]

Materials	Compositions	Marterial forms	E_b/(kV·cm^-1)	ΔP/(µC·cm^-2)	W_rec/(J·cm^-3)	η/%	Ref.
BF-BT	0.7(0.65BF-0.35BT)-0.3Nb₂O₅	Bulk	90	19.68	0.71	-	[60]
	0.61BF-0.33BT-0.06La(Mg_1/2Ti_1/2)O₃	Bulk	130	33.3	1.66	82	[61]
	0.61BF-0.33BT-0.06Ba(Mg_1/3Nb_2/3)O₃	Bulk	125	32.3	1.56	75	[62]
BF-ST	0.4BF-0.6ST	Thick film	420	-	6	-	[64]
BF-ST	0.4BF-0.6ST+0.5%MnO₂	Thin film	3600	~38	~51	64	[65]

Materials systems	Grain size/µm	E_b/(kV·cm^-1)	ΔP/(µC·cm^-2)	W_rec/(J·cm^-3)	η/%	Ref.
KNN	2.26	40	5	-	-	[85]
0.8KNN-0.2SSN	0.5	295	13.8	2.02	81.4	[84]
0.85KNN-0.15ST	0.3	400	25.8	4.03	52	[85]
0.90KNN-0.10BMN	0.31	300	33.0	4.08	62.7	[86]
0.8KNN-0.2SSN+0.5%ZnO	0.45	400	14.7	2.6	73.2	[90]
0.90KNN-0.10BMN+1.0%CuO	0.49	400	26	4.02	57.3	[91]

无铅非线性介电储能陶瓷: 现状与挑战

Lead-free Nonlinear Dielectric Ceramics for Energy Storage Applications: Current Status and Challenges

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Materials	Compositions	E_b/(kV·cm^-1)	ΔP/(µC·cm^-2)	W_rec/(J·cm^-3)	η/%	Ref.
BNT	0.89BNT-0.06BT-0.05KNN	99	27.2	0.90	-	[100]
	0.95BNT-0.05BT+3%BaO-B₂O₃-SiO₂	94.6	31	0.68	71	[101]
	0.9[0.92BNT-0.08BT]-0.1BMT	135	~40	2.00	88	[102]
	0.7BNT-0.3ST+0.05MnO₂	95	36.92	0.96	74.6	[103]
	0.9[0.92BNT-0.08BT]-0.1NaNbO₃	70	25	0.71	66	[104]
	0.7[0.94BNT-0.06BT]-0.3ST	90	30.8	0.98	82	[105]
	0.6BNT-0.2NN-0.2 Ba(Zr_0.2Ti_0.8)O₃	175	26.61	1.69	78.4	[106]
	0.9BNT-0.1KN	104	28	1.17	83	[107]
	0.84BNT-0.16KNN	100	-	1.20	71	[108]
	[(Bi_1/2Na_1/2)_0.94Ba_0.06]La_0.98Zr_0.02TiO₃	83.4	33	0.58	-	[109]
	0.62BNT-0.06BT-0.32(Sr_0.7Bi_0.3)TiO₃	60	~19	0.5	>90	[110]
	0.95(0.8BNT-0.2ST)-0.05NaNbO₃	70	27.53	0.74	55	[111]
AN	AN	175	-	2.1	-	[94]
	AN+0.1wt%MnO₂	150	~37	2.5	56	[95]
	Ag(Nb_0.85Ta_0.15)O₃	233	36.1	4.2	69	[78]

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