量子点敏化太阳能电池对电极材料的研究进展

doi:10.15541/jim20170307

无机材料学报 ›› 2018, Vol. 33 ›› Issue (5): 483-493.DOI: 10.15541/jim20170307

所属专题：光伏材料；乘风破浪的新能源材料

量子点敏化太阳能电池对电极材料的研究进展

孟祥东¹, 尹默¹, 舒婷², 胡悦¹, 孙萌¹, 于兆亮^1,3, 李海波^1,3

1.吉林师范大学功能材料物理与化学教育部重点实验室, 长春130015;
2. 湖北科技学院, 咸宁 437100;
3. 吉林大学无机合成与制备化学国家重点实验室, 长春 130023

收稿日期:2017-06-21 修回日期:2017-09-27 出版日期:2018-05-20 网络出版日期:2018-04-26
作者简介:孟祥东(1975-), 男, 教授. E-mail: xdmeng@jlnu.edu.cn
基金资助:
国家自然科学基金(61275047, 21301055);教育部科学技术研究项目(213009A);湖北省自然科学基金(2018CFB740)

Research Progress on Counter Electrodes of Quantum Dot-sensitized Solar Cells

MENG Xiang-Dong¹, YIN Mo¹, SHU Ting², HU Yue¹, SUN Meng¹, YU Zhao-Liang^1,3, LI Hai-Bo^1,3

1. Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Changchun 130015, China;
2. Hubei University of Science and Technology, Xianning 437100, China;
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China

Received:2017-06-21 Revised:2017-09-27 Published:2018-05-20 Online:2018-04-26
About author:MENG Xiang-Dong. E-mail: xdmeng@jlnu.edu.cn
Supported by:
National Natural Science Foundation of China(61275047, 21301055);The Project of Ministry of Education of China (213009A);Hubei Provincial Natural Science Foundation of China (2018CFB740)

摘要/Abstract

摘要：

量子点敏化太阳能电池(Quantum Dot-Sensitized Solar cells, QDSCs)制备工艺简单, 制造成本低廉, 是一种有希望的新型太阳能电池。QDSCs利用量子点具有光谱吸收强、尺寸可调和多激子效应等优点, 能够提高其光电转换效率; 同时, 利用无机量子点替代染料作为敏化剂, 能够解决染料敏化太阳能电池(DSCs)的稳定性问题。但是, QDSCs光电转换效率较低是制约其应用的主要问题。近年来, 通过改变和调控对电极的材料和电子特性提高QDSCs的光电效率的方法受到了广泛关注。本文综述了QDSCs对电极材料的制备方法、微观形貌和晶体结构; 重点分析了金属化合物、复合材料、杂化材料、多元金属硫族化合物、导电聚合物和碳材料对电极对量子点敏化太阳能电池的电荷转移阻抗、光电性能等参数的影响; 并分析影响其电催化活性和电子传输性能的主要因素。最后, 提出通过表面修饰、复合和杂化等方法构筑新型对电极材料, 进而改善和提高QDSCs转换效率和稳定性, 是今后的研究重点和研究方向。

关键词: 量子点, 敏化太阳能电池, 对电极, 电荷转移阻抗, 综述

Abstract:

Quantum dots sensitized solar cells (QDSCs) play a key role in the new generation photovoltaic devices due to their low cost and easy fabrication process. The absorption spectrum of quantum dots can be tailored by controlling grain size, and multi-exaction generation. QDSCs using inorganic compound QDs replaces the dye as a sensitizer, which is able to solve the stability of the dye sensitized solar cells. However, further improvement of the conversion efficiency of QDSCs is still a major issue for their application. Recently, tailoring electronic properties of the counter electrode(CE) in QDSCs using different materials has been considered as a promising way to improve photovoltaic performance of QDSCs. This article reviewed the quite recent progress of CE in QDSCs based on synthesis method, surface microtopography and crystal structure. This review gave a panorama of metal chalcogenides, composite materials, hybrid materials, muti-component metal chalcogenides, conductive polymers, and carbon CE materials for QDSCs, while the influence of CE materials on the charge transfer impedance, the electron transport process, catalytic properties, and I-V characteristics was stressed in detail. Finally, an outlook on the future challenges and prospects of novel materials as the CE for QDSCs were also briefly put forward.

Key words: quantum dots, sensitized solar cells, counter electrode, charge transfer resistance, review

中图分类号:

O611

孟祥东, 尹默, 舒婷, 胡悦, 孙萌, 于兆亮, 李海波. 量子点敏化太阳能电池对电极材料的研究进展[J]. 无机材料学报, 2018, 33(5): 483-493.

MENG Xiang-Dong, YIN Mo, SHU Ting, HU Yue, SUN Meng, YU Zhao-Liang, LI Hai-Bo. Research Progress on Counter Electrodes of Quantum Dot-sensitized Solar Cells[J]. Journal of Inorganic Materials, 2018, 33(5): 483-493.

图/表 11

参考文献 79

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CE	QDs	Synthesis method	Electrolyte	R_ct/(?·cm²)	V_oc/mV	J_sc/(mA·cm^-2)	FF/%	ŋ/%
Cu₂S^[24]	CdSe	Dipping immersion	Polysulfide	2.72	590	16.04	56	5.21
PbS^[43]	CdS/ZnS	SILAR	Polysulfide	30.00	580	18.30	45	4.70
CuS^[35]	CdS	CBD	Polysulfide	1.04	570	14.58	55	4.53
CuS^[26]	CdS/CdSe	Heat-sealed method	Polysulfide	47.20	550	16.05	49	4.32
CoS₂^[46]	CdS/CdSe	Thermal sulfidation	Polysulfide	40.60	510	14.44	56	4.16
CuS^[37]	CdS/CdSe	CBD	Polysulfide	2.70	600	12.51	53	4.02
CuS^[38]	CdS, CdSe, ZnS	CBD	Polysulfide	4.40	550	13.87	51	4.01
Cu₂S^[25]	CdS&CdSe	Dipping immersion	Polysulfide	0.65	450	13.45	60	3.65
PbS^[44]	CdSe	Dipping immersion	Polysulfide	130.00	550	9.28	59	3.01
NiS^[49]	CdS, CdSe, ZnS	CBD	Polysulfide	3.16	510	10.38	55	2.97
Co_xSe^[47]	CdS	Hydrothermal	Polysulfide	2.68	650	9.29	35	2.11
FeS^[50]	CdS	Dipping immersion	Polysulfide	13.60	430	9.60	43	1.76
Mo₂S^[51]	CdS、ZnS	Hydrothermal	Polysulfide	/	480	6.22	41	1.21

CE	QDs	Synthesis method	Electrolyte	R_ct/(?·cm²)	V_oc/mV	J_sc/(mA·cm^-2)	FF/%	ŋ/%
Cu₂S^[24]	CdSe	Dipping immersion	Polysulfide	2.72	590	16.04	56	5.21
PbS^[43]	CdS/ZnS	SILAR	Polysulfide	30.00	580	18.30	45	4.70
CuS^[35]	CdS	CBD	Polysulfide	1.04	570	14.58	55	4.53
CuS^[26]	CdS/CdSe	Heat-sealed method	Polysulfide	47.20	550	16.05	49	4.32
CoS₂^[46]	CdS/CdSe	Thermal sulfidation	Polysulfide	40.60	510	14.44	56	4.16
CuS^[37]	CdS/CdSe	CBD	Polysulfide	2.70	600	12.51	53	4.02
CuS^[38]	CdS, CdSe, ZnS	CBD	Polysulfide	4.40	550	13.87	51	4.01
Cu₂S^[25]	CdS&CdSe	Dipping immersion	Polysulfide	0.65	450	13.45	60	3.65
PbS^[44]	CdSe	Dipping immersion	Polysulfide	130.00	550	9.28	59	3.01
NiS^[49]	CdS, CdSe, ZnS	CBD	Polysulfide	3.16	510	10.38	55	2.97
Co_xSe^[47]	CdS	Hydrothermal	Polysulfide	2.68	650	9.29	35	2.11
FeS^[50]	CdS	Dipping immersion	Polysulfide	13.60	430	9.60	43	1.76
Mo₂S^[51]	CdS、ZnS	Hydrothermal	Polysulfide	/	480	6.22	41	1.21

CE	QDs	Synthetic method	Electrolyte	R_ct/(?·cm²)	J_sc/mV	V_oc/(mA·cm^-2)	FF/%	ŋ/%
RGO/Cu₂S^[53]	CdSe	Spin-coating	Polysulfide	1.61	18.40	520.00	46	4.40
CuInS₂/C^[56]	CdS/CdSe	Dotor-blading	Polysulfide	18.79	14.16	512.00	60	4.32
PbS/CB^[61]	CdS/CdSe	Dotor-blading	Polysulfide	10.28	13.32	509.58	58	3.91
CuS/EC^[57]	CdS	Hydrothermal	Polysulfide	/	14.60	521.00	51	3.86
CoS/NiS^[60]	CdS/CdSe	CBD	Polysulfide	1.97	11.15	579.00	53	3.40
ZnO/PbS^[62]	CdSe	SILAR	Polysulfide	5.20	11.17	520.00	53	3.06

CE	QDs	Synthetic method	Electrolyte	R_ct/(?·cm²)	J_sc/mV	V_oc/(mA·cm^-2)	FF/%	ŋ/%
RGO/Cu₂S^[53]	CdSe	Spin-coating	Polysulfide	1.61	18.40	520.00	46	4.40
CuInS₂/C^[56]	CdS/CdSe	Dotor-blading	Polysulfide	18.79	14.16	512.00	60	4.32
PbS/CB^[61]	CdS/CdSe	Dotor-blading	Polysulfide	10.28	13.32	509.58	58	3.91
CuS/EC^[57]	CdS	Hydrothermal	Polysulfide	/	14.60	521.00	51	3.86
CoS/NiS^[60]	CdS/CdSe	CBD	Polysulfide	1.97	11.15	579.00	53	3.40
ZnO/PbS^[62]	CdSe	SILAR	Polysulfide	5.20	11.17	520.00	53	3.06

CE	QDs	Synthetic method	R_ct/(?·cm²)	V_oc/mV	J_sc/(mA·cm^-2)	FF/%	ŋ/%
AuPtNP/RGO	CdSe	Co-reduction	34.25	720	15.2	41	4.50
TiN/CNT-GR	CdSe/CdS	SILAR	14.40	642	14.0	46	4.13
TiN/CNT	CdSe/CdS		23.60	645	13.7	44	3.89
TiN-GR	CdSe/CdS		36.60	636	12.7	43	3.47
TiN	CdSe/CdS		123.00	609	6.6	20	0.80
CuS/Pt	CdS	Coated reaction method	424.00	567	8.0	50	2.27

量子点敏化太阳能电池对电极材料的研究进展

Research Progress on Counter Electrodes of Quantum Dot-sensitized Solar Cells

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