烧结助剂(Y3+、La3+和Mg2+)对半透明氧化铝陶瓷的透光率的影

doi:10.15541/jim20160682

摘要/Abstract

摘要：

通过化学沉淀法引入烧结助剂Y³⁺、La³⁺和Mg²⁺, 采用真空烧结工艺制备了半透明Al₂O₃陶瓷, 并研究了烧结助剂对烧结材料的微观结构、相对密度和透光率的影响。结果表明: 引入的烧结助剂能均匀分散在合成的半透明Al₂O₃陶瓷中。烧结助剂的最佳引入量为Mg²⁺(0.15wt%)、Y³⁺(0.05wt%)和La³⁺(0.05wt%), 对应的试样在350~800 nm的波长范围内显示出的最高的总透光率(TFT)高于80%。此外, Y³⁺的掺杂可以促进晶粒生长, 降低孔隙率, 从而提高半透明Al₂O₃陶瓷的透光率。

关键词: 半透明氧化铝陶瓷, 化学沉淀法, 烧结助剂, 透光率

Abstract:

Translucent Al₂O₃ ceramics were prepared by vacuum sintering using Y³⁺, La³⁺ and Mg²⁺ as sintering aids which were introduced via chemical precipitation. Effects of the sintering aids on microstructure, relative density and optical transmittance of the translucent Al₂O₃ ceramics were investigated. The results show that the sintering aids are homogeneously dispersed in translucent Al₂O₃ ceramics. The optimal amount of the sintering aid introduced is Mg²⁺ (0.15wt%), Y³⁺ (0.05wt%) and La³⁺ (0.05wt%), and the corresponding sample shows the highest total forward transmittance (above 80% in the wavelength range of 350-800 nm). Moreover, the addition of Y³⁺ could promote grain growth and decrease porosity, thus the optical transmittance of the translucent Al₂O₃ ceramics is enhanced.

Key words: translucent alumina ceramics, chemical precipitation, sintering aids, optical transmittance

中图分类号:

TQ174

袁康, 廖其龙, 王辅, 代云雅, 黄金山. 烧结助剂(Y³⁺、La³⁺和Mg²⁺)对半透明氧化铝陶瓷的透光率的影[J]. 无机材料学报, 2017, 32(9): 1004-1008.

YUAN Kang, LIAO Qi-Long, WANG Fu, DAI Yun-Ya, HUANG Jin-Shan. Effects of Sintering Aids (Y³⁺, La³⁺ and Mg²⁺) on the Optical Transmittance of Translucent Alumina Ceramic[J]. Journal of Inorganic Materials, 2017, 32(9): 1004-1008.

图/表 8

Table 1 Contents of sintering aids in the obtained samples

Samples	Content of sintering aids / wt%
Samples	Mg²⁺	Y³⁺	La³⁺
MYL-1	0.15	0	0.05
MYL-2	0.15	0.03	0.05
MYL-3	0.15	0.05	0.05
MYL-4	0.20	0.05	0.05
MYL-5	0.25	0.05	0.05

Fig. 1 Schematic and flow chart of the adopted chemical precipitation method

Fig. 2 XRD patterns of the obtained samples

Fig. 3 (a) The surface morphology of sample MYL-5, X-ray mapping of (b) Mg, (c) Y and (d) La for sample MYL-5

Fig. 4 Surface morphologies of the samples (a) MYL-1, (b) MYL-2, (c) MYL-3, (d) MYL-4, and (e) MYL-5

Fig. 5 Fracture surface morphologies of the samples (a) MYL-1; (b) MYL-2; (c) MYL-3; (d) MYL-4; (e) MYL-5

Fig. 6 Total forward transmittance spectra of all samples

Fig. 7 Photograph of all samples (a) MYL-1; (b) MYL-2; (c) MYL-3; (d) MYL-4; (e) MYL-5

参考文献 22

[1]	COBLE R L.Sintering crystalline solids. I. intermediate and final state diffusion models in powder compact.Journal of Applied Physics, 1961, 32: 793-799.
[2]	JIANG D, HULBERT D M, ANSELMI-TAMBURINI U,et al.Optically transparent polycrystalline Al2O3 produced by spark plasma sinterin. Journal of the American Ceramic Society, 2008, 91: 151-154.
[3]	KRELL A, BLANK P, MA H W, et al. Transparent sintered corundum with high hardness and strength.Journal of the American　Ceramic　Society　 2003, 86: 12-18.

[4]	LIU W, XIE Z P, LIU G W,et al.Novel preparation of translucent alumina ceramics induced by doping additives via chemical precipitation metho. Journal of the American Ceramic Society, 2011, 94: 3211-3215.
[5]	STUER M, ZHAO Z, ASCHAUER U,et al. Transparent polycrystalline alumina using spark plasma sintering: effect of Mg, Y and La dopin. Journal of the European Ceramic Society, 2010, 30: 1335-1343.
[6]	APETZ R, BRUGGEN M P B. Transparent alumina: a light-scattering mode.Journal of the American Ceramic Society, 2003, 86: 480-486.
[7]	KRELL A, KLIMKE J.Effect of the homogeneity of particle coordination on solid-state sintering of transparent alumin.Journal of the American Ceramic Society, 2006, 89: 1985-1992.
[8]	LI J G, YE Y P.Densification and grain growth of Al2O3 nanoceramics during pressureless sinterin.Journal of the American Ceramic Society, 2006, 89: 139-143.
[9]	WANG S F, ZHANG J, LUO D W,et al. Transparent ceramics: processing, materials and application. Progress in Solid State Chemistry, 2013, 41: 20-54.
[10]	CHEN C, YI X Z, ZHANG S,et al.Vacuum sintering of Tb3Al5O12 transparent ceramics with combined TEOS+MgO sintering aid. Ceramics International, 2015, 41: 12823-12827.
[11]	BENNISON S J, HARMER M P. Grain-growth kinetics for alumina in the absence of a liquid-phase. Journal of the American Ceramic Society#/magtechI#, 1985, 68: C-22-C-2 .
[12]	BERRY K A, HARMER M P.Effect of MgO solute on microstructure development in Al2O3.Journal of the American Ceramic Society, 1986, 69: 143-149.
[13]	CHO J Y, RICHMAN J M, CHAN H M,et al. Modeling of grain boundary segregation behavior in aluminum oxid. Journal of the American Ceramic Society, 2000, 83: 344-352.
[14]	NAGASHIMA M, MOTOIKE K, HAYAKAWA M.Fabrication and optical characterization of high-density Al2O3 doped with slight MnO dopan.Journal of the American Ceramic Society, 2008, 116: 645-648.
[15]	YOSHIMURA H N, GOLDENSTEIN H.Light scattering in polycrystalline alumina with Bi-dimensionally large surface grain.Journal of the European Ceramic Society, 2009, 29: 293-303.
[16]	BERNARD-GRANGER G, GUIZADR C, ADDAD A.Influence of co-doping on the sintering path and on the optical properties of a submicronic alumina materia.Journal of the American Ceramic Society, 2008, 91: 1703-1706.
[17]	SUAREZ M, FERNANDEZ A, MENENDEZ J L,et al. Grain growth control and transparency in spark plasma sintered self- doped alumina material. Scripta Materialia, 2009, 61: 931-934.
[18]	LIU G W, XIE Z P, LIU W,et al. Fabrication of translucent alumina ceramics from pre-sintered bodies infiltrated with sintering additive precursor solution. Journal of the European Ceramic Society, 2012, 32: 711-715.
[19]	YIN J L, WANG X H, ZHANG Y,et al. Effect of sintering aids on high purity alumina ceramic densification proces. Chinese Rare Earths, 2014, 5: 16-20.
[20]	WANG W, XIE Z P, LIU G W.Fabrication of blue-colored zirconia ceramic.via heterogeneous nucleation method. Crystal Growth & Design, 2009, 9: 4373-4377.
[21]	WINKLER P M, STEINER G, VRTALA A.Heterogeneous nucleation experiments bridging the scale from molecular ion clusters to nanoparticle.Science, 2008, 319: 1374-1377.
[22]	YU H L, LIAO Q L, LIU L B.Effect of MgO on microstructure and transmittance of transparent alumina ceramic.China Ceramics, 2013, 49: 27-34.

烧结助剂(Y³⁺、La³⁺和Mg²⁺)对半透明氧化铝陶瓷的透光率的影

Effects of Sintering Aids (Y³⁺, La³⁺ and Mg²⁺) on the Optical Transmittance of Translucent Alumina Ceramic

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 22

相关文章 15

编辑推荐

Metrics

本文评价

[1]	付师, 杨增朝, 李宏华, 王良, 李江涛. 复合烧结助剂对Si₃N₄陶瓷力学性能和热导率的影响[J]. 无机材料学报, 2022, 37(9): 947-953.
[2]	邹顺, 何夕云, 曾霞, 仇萍荪, 凌亮, 孙大志. 掺铋钇铁石榴石磁光陶瓷的热压烧结及其性能研究[J]. 无机材料学报, 2022, 37(7): 773-779.
[3]	樊帅, 金天, 张山林, 雒晓涛, 李成新, 李长久. Li₂O烧结助剂对固体氧化物燃料电池LSGM电解质烧结特性及离子电导率的影响[J]. 无机材料学报, 2022, 37(10): 1087-1092.
[4]	赵长江,马超,刘俊成,刘治钢,陈燕. 溅射功率对磁控溅射法制备MgF₂薄膜组织和性能的影响[J]. 无机材料学报, 2020, 35(9): 1064-1070.
[5]	胡泽望,陈肖朴,刘欣,李晓英,石云,寇华敏,谢腾飞,李江. 微量SiO₂添加对Pr:Lu₃Al₅O₁₂陶瓷光学及闪烁性能的影响[J]. 无机材料学报, 2020, 35(7): 796-802.
[6]	杨志宾, 朱腾龙, 项文龙, 于立安, 韩敏芳. Li₂O助烧的Gd_0.1Ce_0.9O_1.95烧结过程及其电导性能研究[J]. 无机材料学报, 2015, 30(4): 345-350.
[7]	孙志娟, 陈雪莲, 蒋春跃. 自组装法制备中空二氧化硅纳米粒子减反射薄膜[J]. 无机材料学报, 2014, 29(9): 947-955.
[8]	胡海龙, 曾宇平, 左开慧, 夏咏锋,姚冬旭. 烧结助剂种类对Si₃N₄/SiC陶瓷力学与摩擦性能的影响[J]. 无机材料学报, 2014, 29(8): 885-890.
[9]	胡海龙, 姚冬旭, 夏咏锋, 左开慧, 曾宇平. 反应烧结制备Si₃N₄/SiC复相陶瓷及其力学性能研究[J]. 无机材料学报, 2014, 29(6): 594-598.
[10]	张国庆, 杨帆, 吴云涛, 孙丹丹, 商珊珊, 任国浩. F/Cl比对PbFCl晶体生长和发光性能的影响[J]. 无机材料学报, 2014, 29(2): 162-166.
[11]	江虹, 郭瑞松, 徐江海, 高沿英, 邓雅平. 氧化钇掺杂锆铈酸钡质子导体的制备及性能研究[J]. 无机材料学报, 2012, 27(12): 1256-1260.
[12]	李美娟, 沈强, 罗国强, 张联盟. Li₂O对SPS烧结AlN陶瓷致密化、显微结构和导热性的影响[J]. 无机材料学报, 2011, 26(6): 659-663.
[13]	周宏明,易丹青,钟华. 稀土Dy和Ce共掺杂La₂Zr₂O₇新型热障涂层用陶瓷材料[J]. 无机材料学报, 2008, 23(3): 567-572.
[14]	周宏明,易丹青. 热障涂层用Nd₂O₃-CeO₂-ZrO₂陶瓷粉末制备及其性能研究[J]. 无机材料学报, 2008, 23(2): 247-252.
[15]	蒋久信,王佩玲,程一兵,陈卫武,庄汉锐,严东生. 高温自蔓延燃烧合成的β-Si₃N₄粉体的烧结[J]. 无机材料学报, 2004, 19(6): 1431-1435.