聚对苯撑纳米复合提升ZnO基热电材料性能

doi:10.15541/jim20160118

无机材料学报 ›› 2016, Vol. 31 ›› Issue (11): 1249-1254.DOI: 10.15541/jim20160118

聚对苯撑纳米复合提升ZnO基热电材料性能

吴子华, 谢华清, 王元元, 毛建辉, 邢姣娇, 李奕怀

(上海第二工业大学工学部环境与材料工程学院, 上海 201209)

收稿日期:2016-03-03 修回日期:2016-04-21 出版日期:2016-11-10 网络出版日期:2016-10-25
作者简介:吴子华(1978–), 男, 副教授. E-mail: wuzihua@ sspu.edu.cn
基金资助:
国家自然科学基金(51590902, 51476095);上海市青年东方学者岗位支持计划(QD2015052)

PPP Addition to Improve Thermoelectric Properties of ZnO-based Thermoelectric Composites

WU Zi-Hua, XIE Hua-Qing, WANG Yuan-Yuan, MAO Jian-Hui, XING Jiao-Jiao, LI Yi-Huai

(School of Environment and Materials Engineering, College of Engineering, Shanghai Polytechnic University, Shanghai, 201209, China)

Received:2016-03-03 Revised:2016-04-21 Published:2016-11-10 Online:2016-10-25
About author:WU Zi-Hua. E-mail: wuzihua@ sspu.edu.cn
Supported by:
National Science Foundation of China(51590902, 51476095), Program for Professor of Special Appointment (Young Eastern Scholar, QD2015052) at Shanghai Institutions of Higher Learning

摘要/Abstract

摘要：

以溶胶-凝胶法合成了PPP@Zn_1-_xCo_xO纳米复合热电材料(x=0, 0.025), 再以放电等离子烧结制备成块体, 并对其热电性能进行了研究。由透射电镜照片发现, PPP纳米颗粒尺寸在200 nm以下。热电性能分析表明, 随着PPP添加量的增加, 赛贝克系数先增大后减小。电导率随PPP含量增加而大幅度提高。与ZnO块体材料相比, 溶胶-凝胶法合成的PPP@Zn_1-_xCo_xO纳米复合热电材料的热导率大幅度降低, 在640 K时, 9wt% PPP的纳米复合热电材料热导率降低至5.4 W/(m·K)。电导率的增加和热导率的降低, 导致热电性能大幅度提高, 9wt%PPP@Zn_0.975Co_0.025O纳米复合热电材料在870 K时具有最大ZT值(0.16), 是Zn_0.975Co_0.025O材料的8倍。

关键词: ZnO, 热电性能, 溶胶-凝胶, 分子结

Abstract:

PPP@Zn_1-_xCo_xO (x=0, 0.025) nanocomposites were prepared by Sol-Gel method, then bulk samples were prepared by spark plasma sintering. And thermoelectric properties of the samples were studied. Transmission electron microscopy (TEM) observations indicate that PPP nanoparticles are smaller than 200 nm. With the increase of PPP content, Seebeck coefficient gradually increases at first and then decreases, while electric conductivity increases quickly. Compared with ZnO bulk samples, the thermal conductivity of PPP@Zn_1-_xCo_xO nanocomposite is decreased. The thermal conductivity of 9wt% PPP@Zn_0.975Co_0.025O is decreased to 5.4 W/(m·K) at 640 K. The increase of electrical conductivity and the decrease of thermal conductivity resulted in a great increase in the value of thermoelectric properties. 9wt% PPP@Zn_0.975Co_0.025O has a maximal ZT value of 0.16 at 870 K, which is 8 times of that of Zn_0.975Co_0.025O bulk material.

Key words: ZnO, thermoelectric property, Sol-Gel, molecular junction

中图分类号:

TB34

吴子华, 谢华清, 王元元, 毛建辉, 邢姣娇, 李奕怀. 聚对苯撑纳米复合提升ZnO基热电材料性能[J]. 无机材料学报, 2016, 31(11): 1249-1254.

WU Zi-Hua, XIE Hua-Qing, WANG Yuan-Yuan, MAO Jian-Hui, XING Jiao-Jiao, LI Yi-Huai. PPP Addition to Improve Thermoelectric Properties of ZnO-based Thermoelectric Composites[J]. Journal of Inorganic Materials, 2016, 31(11): 1249-1254.

图/表 5

图1 Zn1-xCoxO材料的XRD图谱

Fig. 1 XRD patterns of Zn1-xCoxO sample

图2 PPP@Zn1-xCoxO材料的透射电镜照片

Fig. 2 TEM images of PPP@Zn1-xCoxO samples(a) Zn0.975Co0.025O; (b) 5wt% PPP@Zn0.975Co0.025O; (c) 9wt% PPP@Zn0.975 Co0.025O; (d) HRTEM image of 9wt% PPP@Zn0.975Co0.025O

图3 聚对苯撑FTIR谱和TG-DSC曲线

Fig. 3 FTIR spectrum and TG-DSC curve of polyparaphenylene

图4 PPP@Zn1-xCoxO材料的电性能和热导率与温度的关系

Fig. 4 Temperature dependence of electronic properties and thermal conductivity of PPP@Zn1-xCoxO sample

图5 PPP@Zn1-xCoxO材料的ZT

Fig. 5 ZT of PPP@Zn1-xCoxO sample

参考文献 22

[1]	ZHANG Q H, AI X, WANG W J, et al.Preparation of 1-D/3-D structured AgNWs/Bi2Te3 nanocomposites with enhanced thermoelectric properties.Acta Materialia, 2014, 73(4): 37-47.
[2]	CHEN LI-DONG, XIONG ZHEN, BAI SHENG-QIANG.Recent progress of thermoelectric nano-composites.Journal of Inorganic Materials, 2010, 25(6): 561-568.
[3]	JOSEPH R S, DUCK Y C, MERCOURI G K.New and old concepts in thermoelectric materials.Angew. Chem. Int. Ed., 2009, 48(46): 8616-8639.
[4]	ZHANG Q L, JANG W J, LI J L, et al.Preparation and thermoelectric properties of multi-walled carbon nanotube/polyaniline hybrid nanocomposites.J. Mater. Chem. A, 2013, 1(39): 12109-12114.
[5]	HICKS L D, DRESSELHAUS M S.Effect of quantum-well structures on the thermoelectric figure of merit.Phys. Rev. B, 1993, 47: 12727.
[6]	VENKATASUBRAMANIAN R, SIIVOLA E, COLPITTS T, et al.Thin-film thermoelectric devices with high room-temperature figures of merit.Nature, 2001, 413: 597-602.
[7]	HARMAN T C, TAYLOR P J, WALSH M P, et al.Quantum dot superlattice thermoelectric materials and devices.Science, 2002, 297(5590): 2229-2232.
[8]	HU F, CAI Q, LIAO F, et al.Recent advancements in nanogenerators for energy harvesting.Small, 2015, 11(42): 5611-5628.
[9]	ALVARADO A, ATTAPATTU J, ZHANG Y, et al.Thermoelectric properties of rocksalt ZnO from first-principles calculations.J. Appl. Phys., 2015, 118: 165101.
[10]	OHTAKI M, TSSUBOTA T, EGUCHI K, et al.High-temperature thermoelectric properties of (Zn1-x Al x)O.J. Appl. Phys., 1996, 79: 1816.
[11]	ZHANG D B, ZHANG B P, YE D S, et al.Enhanced Al/Ni co-doping and power factor in textured ZnO thermoelectric ceramics prepared by hydrothermal synthesis and spark plasma sintering.Journal of Alloys and Compounds, 2016, 656: 784-792.
[12]	ONG K P, SINGH D J, WU P.Analysis of the thermoelectric properties of n-type ZnO.Phys. Rev. B, 2011, 83: 115110.
[13]	LIANG X.Thermoelectric transport properties of Fe-enriched ZnO with high-temperature nanostructure refinement. ACS Appl. Mater. Interfaces, 2015, 7(15): 7927-7937.
[14]	JOOD P, PELECKIS G, WANG X, et al.Effect of gallium doping and ball milling process on the thermoelectric performance of n-type ZnO.Journal of Materials Research, 2012, 27(17): 2278-2285.
[15]	MALEN J A, YEE S K, MAJUMDAR A, et al.Fundamentals of energy transport, energy conversion, and thermal properties in organic-inorganic heterojunctions.Chemical Physics Letters, 2010, 491(4/5/6): 109-122.
[16]	SEE K C, FESER J P, CHEN C E, et al.Water-processable polymer-nanocrystal hybrids for thermoelectrics.Nano Letters, 2010, 10(11): 4664-4667.
[17]	HE M, GE J, LIN Z, et al.Thermopower enhancement in conducting polymer nanocomposites via carrier energy scattering at the organic-inorganic semiconductor interface.Energy & Environmental Science, 2012, 5(8): 8351-8358.
[18]	DRAXL C A, MAJEWSKI J A, VOGL P, et al.First-principles studies of the structural and optical properties of crystalline poly(para-phenylene).Physical Review B, 1995, 51: 9668-9676.
[19]	SHACKLETTE L W, ECKHARDT H, CHANCE R R, et al.Solid‐state synthesis of highly conducting polyphenylene from crystalline oligomers.The Journal of Chemical Physics, 1980, 73: 4098.
[20]	LEE Y S, KERTESZ M.The effect of heteroatomic substitutions on the band gap of polyacetylene and polyparaphenylene derivatives.The Journal of Chemical Physics, 1988, 88: 2609.
[21]	FANG Y J, SHA J, WANG Z L, et al.Behind the change of the photoluminescence property of metal-coated ZnO nanowire arrays.Applied Physics Letters, 2011, 98: 033103.
[22]	BAXTER J B, SCHMUTTENMAER C A.Conductivity of ZnO nanowires, nanoparticles, and thin films using time-resolved terahertz spectroscopy.The Journal of Physical Chemistry B, 2006, 110(50): 25229-25239.

聚对苯撑纳米复合提升ZnO基热电材料性能

PPP Addition to Improve Thermoelectric Properties of ZnO-based Thermoelectric Composites

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 5

参考文献 22

相关文章 15

编辑推荐

Metrics

本文评价

[1]	汪波, 余健, 李存成, 聂晓蕾, 朱婉婷, 魏平, 赵文俞, 张清杰. Gd/Bi_0.5Sb_1.5Te₃热电磁梯度复合材料的服役稳定性[J]. 无机材料学报, 2023, 38(6): 663-670.
[2]	贺丹琪, 魏明旭, 刘蕤之, 汤志鑫, 翟鹏程, 赵文俞. 一步法制备重费米子YbAl₃热电材料及其性能提升[J]. 无机材料学报, 2023, 38(5): 577-582.
[3]	林思琪, 李艾燃, 付晨光, 李荣斌, 金敏. Zintl相Mg₃X₂(X=Sb, Bi)基晶体生长及热电性能研究进展[J]. 无机材料学报, 2023, 38(3): 270-279.
[4]	程成, 李建波, 田震, 王鹏将, 康慧君, 王同敏. In₂O₃/InNbO₄复合材料的热电性能研究[J]. 无机材料学报, 2022, 37(7): 724-730.
[5]	刘丹, 赵亚欣, 郭锐, 刘艳涛, 张志东, 张增星, 薛晨阳. 退火条件对磁控溅射MgO-Ag₃Sb-Sb₂O₄柔性薄膜热电性能的影响[J]. 无机材料学报, 2022, 37(12): 1302-1310.
[6]	任培安, 汪聪, 訾鹏, 陶奇睿, 苏贤礼, 唐新峰. Te与In共掺杂对Cu₂SnSe₃热电性能的影响[J]. 无机材料学报, 2022, 37(10): 1079-1086.
[7]	逯旭, 侯绩翀, 张强, 樊建锋, 陈少平, 王晓敏. Mg含量对Mg₃₍₁₊_z₎Sb₂化合物热电传输性能的影响[J]. 无机材料学报, 2021, 36(8): 835-840.
[8]	向晖, 全慧, 胡艺媛, 赵炜骞, 徐波, 殷江. 类石墨烯单层结构ZnO和GaN的压电特性对比研究[J]. 无机材料学报, 2021, 36(5): 492-496.
[9]	满鑫, 吴南, 张牧, 贺红亮, 孙旭东, 李晓东. Lu₂O₃-MgO纳米粉体合成及其复相红外透明陶瓷制备[J]. 无机材料学报, 2021, 36(12): 1263-1269.
[10]	杨丛纲, 米乐, 冯爱虎, 于洋, 孙大志, 于云. KH-560改性SiO₂绝缘薄膜的制备及性能研究[J]. 无机材料学报, 2021, 36(12): 1343-1348.
[11]	张清明, 朱敏, 周晓霞. CuO/ZnO复合电催化剂的制备及其还原CO₂制合成气[J]. 无机材料学报, 2021, 36(11): 1145-1153.
[12]	杨枭, 苏贤礼, 鄢永高, 唐新峰. (GeTe)_nBi₂Te₃的结构与热电性能研究[J]. 无机材料学报, 2021, 36(1): 75-80.
[13]	张东硕,蔡昊,高凯茵,马子川. Zn₂SiO₄-ZnO-生物炭复合物的制备及其可见光催化H₂O₂降解甲硝唑[J]. 无机材料学报, 2020, 35(8): 923-930.
[14]	朱泽阳,魏济时,黄健航,董向阳,张鹏,熊焕明. 晶格空位ZnO纳米棒的制备及其在镍锌电池中的应用[J]. 无机材料学报, 2020, 35(4): 423-430.
[15]	张伟,高鹏,侯成义,李耀刚,张青红,王宏志. 基于ZnO复合材料的芯片式pH和温度传感器[J]. 无机材料学报, 2020, 35(4): 416-422.