纳米异质结光催化材料制取太阳能燃料研究进展

doi:10.15541/jim20150182

无机材料学报 ›› 2015, Vol. 30 ›› Issue (11): 1121-1130.DOI: 10.15541/jim20150182

• • 下一篇

纳米异质结光催化材料制取太阳能燃料研究进展

韩成1, 雷永鹏², 王应德¹

(国防科技大学1. 新型陶瓷纤维及其复合材料重点实验室; 2. 基础教育学院, 长沙410073)

收稿日期:2015-04-14 修回日期:2015-06-25 出版日期:2015-11-20 网络出版日期:2015-10-20
作者简介:韩成(1991–), 男, 博士研究生. E-mail: hancheng.com@163.com
基金资助:
国家自然科学基金(51173202,51203182);低维量子物理国家重点实验室(清华大学)开放基金 (KF201312);材料复合新技术国家重点实验室(武汉理工大学)开放基金(2014-KF-10);湖南省优秀博士学位论文获得者科研项目(YB2014B004);湖南省高校科技创新团队支持计划;国防科技大学创新群体计划

Recent Progress on Nano-heterostructure Photocatalysts for Solar Fuels Generation

HAN Cheng¹, LEI Yong-Peng², WANG Ying-De¹

(1. Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, National University of Defense Technology, Changsha 410073, China; 2. College of Basic Education, National University of Defense Technology, Changsha 410073, China)

Received:2015-04-14 Revised:2015-06-25 Published:2015-11-20 Online:2015-10-20
About author:HAN Cheng. E-mail: hancheng.com@163.com
Supported by:
National Natural Science Foundation of China (51173202, 51203182);Open Research Fund Program of the State Key Laboratory of Low-Dimensional Quantum Physics (KF201312);State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology) (2014-KF-10);Hunan Provincial Education Department (YB2014B004);Aid program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province and Aid Program for Innovative Group of National University of Defense Technology

摘要/Abstract

摘要：

光催化制取太阳能燃料主要包括光催化分解H₂O制取H₂及光催化还原CO₂制取碳氢化合物, 是应对能源危机最具前景的方法之一。目前, 太阳能燃料的最高转化效率为5%, 无法满足商业化要求(≥10%)。纳米异质结由于能展现出单组分纳米材料或体相异质结所不具备的独特性质, 更能促进光生电子和空穴快速转移, 提供更多的光生电子或使光生电子具有更强的还原性, 因而能显著提高光催化活性。本文主要综述了几种纳米异质结(I-型、II-型、p-n型及Z-型)的光催化原理及其在制取太阳能燃料方面的研究进展, 并展望了研究发展方向。

关键词: 纳米异质结, 光催化材料, 太阳能燃料, 综述

Abstract:

Photocatalytic solar fuels generation, including H₂ production from water splitting and hydrocarbon compounds generation from CO₂ reduction, is considered as one of the most perspective strategies to solve energy crisis in the future. State-of-the-art photocatalysts yield the highest energy conversion efficiency of 5%, failed to achieve the goal of 10% for the large-scale economic production of solar fuels. Nano-heterostructure photocatalysts have distinct properties which are not observed in bulk heterostructure or in the individual nanoscale components, thus can facilitate the separation of photoinduced charge carries, provide more electrons or stronger redox ability, and consequently improve photocatalytic activity. This review firstly introduces the photocatalytic principles of diverse nano-heterostructures, including type I, type II, p-n, and Z-scheme types. Their applications in solar fuels generation are summarized, and some perspectives on the development are also discussed.

Key words: nano-heterostructure, photocatalyst, solar fuels, review

中图分类号:

TB321

韩成, 雷永鹏, 王应德. 纳米异质结光催化材料制取太阳能燃料研究进展[J]. 无机材料学报, 2015, 30(11): 1121-1130.

HAN Cheng, LEI Yong-Peng, WANG Ying-De. Recent Progress on Nano-heterostructure Photocatalysts for Solar Fuels Generation[J]. Journal of Inorganic Materials, 2015, 30(11): 1121-1130.

图/表 7

图1 光催化制取太阳能燃料原理示意图

Fig. 1 Schematic illustration of basic principle for photocatalytic solar fuels generation

图2 I-型(a)和II-型(b)纳米异质结中半导体能级分布及光生载流子的转移途径[23]

Fig. 2 Band alignment and transportation of the charge carries in type I (a) and type II (b) nano-heterostructures[23]

表1 用于制取太阳能燃料的纳米异质结光催化材料

Table 1 Nano-heterostructure photocatalysts for solar fuels generation

Nano-heterostructure photocatalysts	Production of H₂ from water splitting	Generation of C_xH_yO_z from CO₂ reduction
Type I	TiO₂/CuO^[35]; CdSe/CdS^[36]; In₂O₃/In₂S₃^[37]; CdS/ZnS^[25,38]; MoS₂/g-C₃N₄^[39]	Bi₂S₃/CdS^[40]
Type II	g-C₃N₄-N-TiO₂^[22]; g-C₃N₄/g-C₃N₄^[41]; g-C₃N₄/polypyrrole^[42]; g-C₃N₄/SrTiO₃^[43]; CdS/g-C₃N₄^[4,44]; CdS/TiO₂^[45]	g-C₃N₄-N-TiO₂^[46]; ZnO/g-C₃N₄^[47]; Cu₂O/TiO₂^[48]; TiO₂{001}/TiO₂{101}^[49];
p-n type	Cu₂S/CdS^[50]; MoS₂/CdS^[51]; CuO/ZnO^[52]
Z-scheme	TiO₂/RGO/Metal sulfide^[30]; WO₃/g-C₃N₄^[53]; ZnO/Cd/CdS^[54]; g-C₃N₄/Au/CdS^[55]; Si/TiO₂^[56]; CdS/SiC^[57]	Ag₃PO₄/Ag/g-C₃N₄^[3]; Fe₂V₄O₁₃/RGO/CdS^[58]; SnO_2-_x/g-C₃N₄^[59]; TaON/Ag/RuBLRu′^[60]

图3 (a) p-型、n-型半导体接触前能级分布和(b) p-n型纳米异质结中光生载流子的转移途径[27]

Fig. 3 (a) Band alignment of p-type and n-type semiconductors before contact and (b) transportation of the charge carries in p-n type nano-heterostructure[27]

图4 绿色植物光合作用系统(a)和全固态Z-型纳米异质结(b)中电子转移途径[24]

Fig. 4 Transportation of the electrons in (a) photosynthesis system and (b) all-solid-state Z-scheme nano-heterostructure[24]

图5 基于II-型异质结的g-C3N4/TiO2纳米纤维光催化制H2机理示意图[22]

Fig. 5 Schematic illustration of the mechanism for photocatalytic H2 production in the type II nano-heterostructure of g-C3N4/TiO2 nanofiber[22]

图6 (a) TiO2 {001}/{101}晶面异质结中氧化还原反应位点的空间分离[49]和(b) Fe2V4O13/RGO/CdS Z-型纳米异质结光催化还原CO2制取CH4[58]

Fig. 6 Schematic illustration of (a) the spatial separation of redox sites in TiO2 {001}/{101} surface heterojunction[49] and (b) conversion of CO2 into CH4 over Fe2V4O13/RGO/CdS Z-scheme nano-heterostructure photocatalyst[58]

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纳米异质结光催化材料制取太阳能燃料研究进展

Recent Progress on Nano-heterostructure Photocatalysts for Solar Fuels Generation

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