柔性Eu3+掺杂SiO2纳米纤维薄膜的制备及其发光性能

doi:10.15541/jim20140659

无机材料学报 ›› 2015, Vol. 30 ›› Issue (7): 719-724.DOI: 10.15541/jim20140659

柔性Eu³⁺掺杂SiO₂纳米纤维薄膜的制备及其发光性能

张书娴, 崔博, 王宏志, 李耀刚, 张青红

(东华大学材料科学与工程学院, 纤维材料改性国家重点实验室, 上海201620)

收稿日期:2014-12-18 修回日期:2015-02-05 出版日期:2015-07-20 网络出版日期:2015-06-25
作者简介:张书娴(1990–), 女, 硕士研究生. E-mail: susansmile@yeah.net
基金资助:
高等学校学科创新引智计划(111-2-04);高等学校博士学科点专项科研基金(20110075130001);教育部创新团队发展计划(IRT1221);上海市科委项目(12nm0503900, 13JC1400200)

Preparation and Luminescence Properties of Flexible Eu³⁺Doped SiO₂ Fibrous Membranes

ZHANG SHU-XIAN, CUI BO, WANG HONG-ZHI, LI YAO-GANG, ZHANG QING-HONG

(State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China)

Received:2014-12-18 Revised:2015-02-05 Published:2015-07-20 Online:2015-06-25
About author:ZHANG SHU-XIAN. E-mail: susansmile@yeah.net
Supported by:
The Program of Introducing Talents of Discipline to Universities (111-2-04);Specialized Research Fund for the Doctoral Program of Higher Education (20110075130001);Innovative Research Team in University (IRT1221);Science and Technology Commission of Shanghai Municipality (12nm0503900, 13JC1400200)

摘要/Abstract

摘要：

采用溶胶-凝胶法结合静电纺丝技术制备了柔性Eu³⁺掺杂SiO₂纤维薄膜, 采用SEM、XRD、FT-IR、TG和PL等测试方法对材料进行表征。Eu³⁺掺杂SiO₂纤维薄膜在热处理后纤维直径变小, 纤维表面平滑无粘连。通过控制升温速度, 纤维薄膜经热处理后仍具有较高的力学强度, 750℃热处理后其拉伸强度可达4.31 MPa, 经过多次弯曲仍能保持原样。在392.6 nm光源激发下, Eu³⁺掺杂SiO₂纤维薄膜在570~670 nm附近呈现出来自于⁵D₀→⁷F_J的发射峰。当Eu³⁺掺杂浓度为8mol%时, 经过750℃热处理后Eu³⁺掺杂SiO₂纤维薄膜的发光强度达到最大值。

关键词: 静电纺丝, 柔性, SiO2纤维薄膜, 发光性能

Abstract:

Eu³⁺ doped SiO₂ fibrous membranes were prepared by Sol-Gel and electrospinning methods. The obtained samples were chacterized by SEM, XRD, FT-IR, TG, PL, etc. By heat-treatment, the organic components were removed slowly and the diameters of the Eu³⁺ doped SiO₂ fibers decreased. SEM images exhibit that the surface of the fibers retains smooth and uniform after heat-treatment. By controlling the heating rate, the Eu³⁺ doped SiO₂ fibrous membranes present relatively high tensile strength at about 4.31 MPa after heat-treatment at 750℃. The samples exhibit no cracks after bending and recovering process. By excited by 392.6 nm light, the emission peaks between 570-670 nm are observed, which attributes to the ⁵D₀→⁷F_Jtransition. The strongest emission peak situates at 616 nm results from Eu^{3+ 5}D₀→⁷F₂ transition. The optimal heat-treatment temperature is 750℃. PL spectra also show that the luminescence intensity attains the highest value at the concentration of 8mol% Eu³⁺doped.

Key words: electrospinning, flexible, SiO2 fibrous membranes, luminescence properties

中图分类号:

TB34

张书娴, 崔博, 王宏志, 李耀刚, 张青红. 柔性Eu³⁺掺杂SiO₂纳米纤维薄膜的制备及其发光性能[J]. 无机材料学报, 2015, 30(7): 719-724.

ZHANG SHU-XIAN, CUI BO, WANG HONG-ZHI, LI YAO-GANG, ZHANG QING-HONG. Preparation and Luminescence Properties of Flexible Eu³⁺Doped SiO₂ Fibrous Membranes[J]. Journal of Inorganic Materials, 2015, 30(7): 719-724.

图/表 9

图1 热处理前后荧光纤维膜的SEM照片 (a)未处理 (b)650℃处理

Fig. 1 SEM images of fibrous membranes before (a) and after (b) heating treatment

图2 不同温度热处理后前驱体纤维膜的XRD图谱

Fig. 2 X-ray diffraction patterns for fibrous membranes after heat-treatment at different temperatures

图3 前驱体纤维膜和650℃热处理后Eu3+掺杂SiO2荧光纤维膜的红外光谱

Fig. 3 FT-IR spectra of the fibrous membranes before (a) and after (b) heat-treatment at 650℃

图4 前驱体纤维薄膜(a)和PVA颗粒(b)的热失重曲线

Fig. 4 TG curves of hybrid fibrous membranes (a) and PVA powder (b)

图5 样品弯曲示意图(a)和待测试样品图(b)

Fig. 5 Photographs of the blending sample (a) and the sample for testing (b)

图6 不同温度热处理后纤维薄膜拉伸强度变化曲线(a)和纤维薄膜4%拉伸循环往复曲线(b)

Fig. 6 Strength of fibrous membranes change with heat-treatment temperature (a) and 4% tensile recycle curve of fibrous membranes (b)

图7 荧光纤维膜的特征光谱(a)激发光谱和(b)发射光谱

Fig. 7 Excitation and emission spectra of fibrous membranes (a) λem=616 nm; (b) λex=392.6 nm

图8 不同热处理温度后荧光纤维膜的发射光谱(a)和Eu3+的5D0→7F2/5D0→7F1跃迁的强度比(b)

Fig. 8 Emission spectra (a) and intensity ratio of 5D0→7F2 transition to 5D0→7F1 transition (b) of fibrous membranes heat-treated at different temperatures

图9 不同Eu3+掺杂量的纤维薄膜的荧光光谱

Fig. 9 Emission spectra of fibrous membranes for different concentrations of Eu3+

参考文献 19

[1]	GU Y, ZHANG Q, WANG H, et al.CaSi2O2N2: Eu nanofiber mat based on electrospinning: facile synthesis, uniform arrangement, and application in white LEDs. Journal of Materials Chemistry, 2011, 21(44): 17790-17797.
[2]	YU H, SONG H, PAN G, et al.Preparation and luminescent properties of europium-doped yttria fibers by electrospinning.Journal of luminescence, 2007, 124(1): 39-44.
[3]	ZHANG P, JIAO X, CHEN D.Fabrication of electrospun Al2O3 fibers with CaO-SiO2 additive.Materials Letters, 2013, 91: 23-26.
[4]	QIANG W, JIAN D, JIANG L, et al.Flexible inorganic nanofibrous membranes with hierarchical porosity for efficient water purification. Chemical Science, 2013, 4(12): 4378-4382.
[5]	CHEN Y, MAO X, SHAN H, et al.Free-standing zirconia nanofibrous membranes with robust flexibility for corrosive liquid filtration.RSC Advances, 2014, 4(6): 2703-2710.
[6]	YANG L, RAZA A, SI Y, et al.Synthesis of superhydrophobic silica nanofibrous membranes with robust thermal stability and flexibility via in situ polymerization.Nanoscale, 2012, 4(20): 6581-6587.
[7]	FRANZO G, VINCIGUERRA V, PRIOLO F.The excitation mechanism of rare-earth ions in silicon nanocrystals.Applied Physics A, 1999, 69(1): 3-12.
[8]	YU M, LIN J, FANG J.Silica spheres coated with YVO4: Eu3+ layers via Sol-Gel process: a simple method to obtain spherical core-shell phosphors.Chemistry of Materials, 2005, 17(7): 1783-1791.
[9]	PETIT L, GRIFFIN J, CARLIE N, et al.Luminescence properties of Eu3+ or Dy3+, Au co-doped SiO2 nanoparticles. Materials Letters, 2007, 61(14): 2879-2882.
[10]	JIN T, TSUTSUMI S, DEGUCHI Y, et al.Preparation and luminescence characteristics of the europium and terbium complexes incorporated into a silica matrix using a Sol-Gel method.Journal of Alloys and Compounds, 1997, 252(1): 59-66.
[11]	BAUMGARTEN P K.Electrostatic spinning of acrylic microfibers. Journal of Colloid and Interface Science, 1971, 36(1): 71-79.
[12]	MUNIR M M, SURYAMAS A B, ISKANDAR F, et al.Scaling law on particle-to-fiber formation during electrospinning.Polymer, 2009, 50(20): 4935-4943.
[13]	SHENOY S L, BATES W D, FRISCH H L, et al.Role of chain entanglements on fiber formation during electrospinning of polymer solutions: good solvent, non-specific polymer-polymer interaction limit.Polymer, 2005, 46(10): 3372-3384.
[14]	THERON S A, ZUSSMAN E, YARIN A L.Experimental investigation of the governing parameters in the electrospinning of polymer solutions.Polymer, 2004, 45(6): 2017-2030.
[15]	INNOCENZI P.Infrared spectroscopy of Sol-Gel derived silica- based films: a spectra-microstructure overview. Journal of Non- Crystalline Solids, 2003, 316(2): 309-319.
[16]	SHAO C, KIM H Y, GONG J, et al.Fiber mats of poly (vinyl alcohol)/silica composite via electrospinning.Materials Letters, 2003, 57(9): 1579-1584.
[17]	CHOI S S, LEE S G, IM S S, et al.Silica nanofibers from electrospinning/Sol-Gel process.Journal of Materials Science Letters, 2003, 22(12): 891-893.
[18]	NOGAMI M, ABE Y.Properties of Sol-Gel-derived Al2O3-SiO2 glasses using Eu3+ ion fluorescence spectra.Journal of Non-crystalline Solids, 1996, 197(1): 73-78.
[19]	孙家跃, 杜海燕, 胡文祥. 固体发光材料. 北京: 化学工业出版社, 2003: 88-94.

柔性Eu³⁺掺杂SiO₂纳米纤维薄膜的制备及其发光性能

Preparation and Luminescence Properties of Flexible Eu³⁺Doped SiO₂ Fibrous Membranes

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 19

相关文章 15

编辑推荐

Metrics

本文评价

[1]	杨洋, 崔航源, 祝影, 万昌锦, 万青. 柔性神经形态晶体管研究进展[J]. 无机材料学报, 2023, 38(4): 367-377.
[2]	王志强, 吴济安, 陈昆峰, 薛冬峰. 大尺寸Er,Yb:YAG单晶的生长及其性能[J]. 无机材料学报, 2023, 38(3): 329-334.
[3]	盛丽丽, 常江. 光/磁热Fe₂SiO₄/Fe₃O₄双相生物陶瓷及其复合电纺丝膜制备及抗菌性能研究[J]. 无机材料学报, 2022, 37(9): 983-990.
[4]	刘丹, 赵亚欣, 郭锐, 刘艳涛, 张志东, 张增星, 薛晨阳. 退火条件对磁控溅射MgO-Ag₃Sb-Sb₂O₄柔性薄膜热电性能的影响[J]. 无机材料学报, 2022, 37(12): 1302-1310.
[5]	罗艺, 夏书海, 牛波, 张亚运, 龙东辉. 柔性有机硅气凝胶的制备及其高温无机化转变研究[J]. 无机材料学报, 2022, 37(12): 1281-1288.
[6]	刘城, 赵倩, 牟志伟, 雷洁红, 段涛. 新型铋基SiOCNF复合膜对放射性气态碘的吸附性能[J]. 无机材料学报, 2022, 37(10): 1043-1050.
[7]	张晓山, 王兵, 吴楠, 韩成, 刘海燕, 王应德. 高红外遮蔽SiZrOC纳米纤维膜的制备及其性能研究[J]. 无机材料学报, 2022, 37(1): 93-100.
[8]	马玲玲, 常江. Nd掺杂硅酸钙及其复合电纺丝膜的制备及性能研究[J]. 无机材料学报, 2021, 36(9): 974-980.
[9]	王袁杰, 裴学良, 李好义, 徐鑫, 何流, 黄政仁, 黄庆. 自由基引发活性聚碳硅烷交联及其在制备SiC纤维中的应用[J]. 无机材料学报, 2021, 36(9): 967-973.
[10]	李婷婷, 张志明, 韩正波. 基于静电纺丝技术的聚合物基MOFs纳米纤维膜的研究进展[J]. 无机材料学报, 2021, 36(6): 592-600.
[11]	方华靖, 赵泽天, 武文婷, 汪宏. 柔性电致变色器件研究进展[J]. 无机材料学报, 2021, 36(2): 140-151.
[12]	包峰, 常江. 硅酸钙纳米线复合电纺丝支架的制备及离子释放研究[J]. 无机材料学报, 2021, 36(11): 1199-1207.
[13]	徐海丰,侯成义,张青红,李耀刚,王宏志. 碲纳米线柔性薄膜的制备及其热电性能[J]. 无机材料学报, 2020, 35(9): 1034-1040.
[14]	朱正旺,冯锐,柳扬,张扬,谢文翰,董丽杰. 类鱼骨结构CoFe₂O₄纳米纤维的制备与性能[J]. 无机材料学报, 2020, 35(9): 1011-1016.
[15]	杨以娜, 王冉冉, 孙静. MXenes在柔性力敏传感器中的应用研究进展[J]. 无机材料学报, 2020, 35(1): 8-18.