LED用荧光玻璃的制备及性能研究

doi:10.15541/jim20140570

无机材料学报 ›› 2015, Vol. 30 ›› Issue (6): 588-592.DOI: 10.15541/jim20140570

LED用荧光玻璃的制备及性能研究

张延¹, 刘升¹, 许虹杰², 王连军¹, 江莞¹

(1. 东华大学材料科学与工程学院, 纤维材料改性国家重点实验室, 上海 201620 2. 上海柯瑞冶金炉料有限公司, 上海 201908)

收稿日期:2014-11-10 修回日期:2015-02-09 出版日期:2015-06-04 网络出版日期:2015-05-22
作者简介:张延(1989–), 男, 硕士研究生. E-mail: zy_hjh@live.com
基金资助:
国家自然科学基金(11179028, 51432004);上海市优秀技术带头人计划(15XD1525100)

Preparation and Performance of Ce:YAG Phosphor-in-glass

ZHANG Yan¹, LIU Sheng¹, XU Hong-Jie², WANG Lian-Jun¹, JIANG Wan¹

(1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China; 2. Shanghai Career Metallurgy Furnace Material Co., Ktd., Shanghai 201908, China)

Received:2014-11-10 Revised:2015-02-09 Published:2015-06-04 Online:2015-05-22
About author:ZHANG Yan. E-mail: zy_hjh@live.com
Supported by:
National Natural Science Foundation of China (11179028, 51432004);Program of Shanghai Subject Chief Scientist (15XD1525100)

摘要/Abstract

摘要：

以行星球磨得到的SiO₂粉体和商用Ce:YAG荧光粉为原料, 采用放电等离子体烧结技术(简称SPS)成功制备块体荧光玻璃。利用XRD、SEM、紫外/可见光分光光度计和荧光光谱仪等研究了Ce:YAG荧光玻璃的物相、显微结构、吸收和发光性能等。研究结果表明: SPS烧结制备的块体荧光玻璃样品主体是非晶相, 同时荧光粉颗粒在玻璃基质中均匀分布, 颗粒大小也未发生变化, 这表明荧光粉晶体在SPS烧结过程中没有发生化学分解反应, 在玻璃基体中得到很好地保存。该荧光玻璃吸收峰在460 nm左右, 发射波长在530 nm左右。通过对不同含量荧光粉的荧光玻璃进行发光性能表征, 发现荧光粉含量为3wt%的荧光玻璃性能最佳, 以此封装的白光LED样品在800 mA电流驱动下, 获得白光输出, 色坐标为(0.33, 0.38)。

关键词: 白光LED, Ce:YAG, 荧光玻璃, 放电等离子体烧结

Abstract:

One-step spark plasma sintering (SPS) process was introduced to fabricate Ce:YAG phosphor-in-silica-glass (PiSG), of which the composite powder of glass powder/commercial Ce:YAG phosphor was directly obtained by ball mill grinding. The phase, microstructures, absorption spectrum and photoluminescence properties of PiSG samples were investigated by XRD, SEM, UV-Vis spectrophotometer, fluorescence spectrophotometer, etc. The results showed that the as-sintered PiSG sample had amorphous phase and the Ce:YAG phosphor particles was uniformly distributed in glass matrix with no size change, indicating that Ce:YAG phosphor particles were well preserved in silica glass matrix without any decomposition reaction. There was a strong absorption peak around 460 nm and a broad emission band peaked at 530 nm of PiSG sample. The properties of PiSG samples were studied by adjusting the phosphor concentration, demonstrating that the photoluminescence intensity reached the highest when Ce:YAG phosphor concentration was 3wt%. Besides, the optimized 3wt% PiSG based LED modules fell into white light range(0.33, 0.38) under 800 mA current drive.

Key words: white LED, Ce:YAG, phosphor-in-glass, spark plasma sintering

中图分类号:

TQ174

张延, 刘升, 许虹杰, 王连军, 江莞. LED用荧光玻璃的制备及性能研究[J]. 无机材料学报, 2015, 30(6): 588-592.

ZHANG Yan, LIU Sheng, XU Hong-Jie, WANG Lian-Jun, JIANG Wan. Preparation and Performance of Ce:YAG Phosphor-in-glass[J]. Journal of Inorganic Materials, 2015, 30(6): 588-592.

图/表 5

图1 (a)不同研磨时间的SiO2粉体粒径分布和(b)中位粒径值

Fig. 1 (a) Size distribution and (b) median particle diameter of the SiO2 powders milled for different time

图2 不同烧结温度制备的纯石英玻璃样品(a), 不同荧光粉浓度的荧光玻璃样品(b)的照片和不同烧结温度制备的纯石英玻璃样品XRD图谱(c)

Fig. 2 Pictures of (a) as-sintered quartz glass samples sintered at different temperatures and (b) PiSG samples with different phosphor concentrations (c) XRD patterns of quartz glass samples sintered at different temperatures

图3 (a)荧光玻璃和荧光粉XRD图谱和(b)3wt%荧光玻璃光学显微图像, 插图为对应荧光粉图像

Fig. 3 (a) XRD patterns of the PiSG sample and commercial Ce:YAG phosphor and (b) optical micrograph of the 3wt% PiSG sample. Inset is the optical micrograph of Ce:YAG phosphor

图4 不同浓度的荧光玻璃的透过光谱(a)和发射光谱(b)

Fig. 4 Optical transmittance (a) and photoluminescence spectra (b) of PiSG sample with various phosphor concentrations

图5 荧光玻璃封装的白光LED色品坐标图

Fig. 5 Chromaticity color coordinates of the white LED modules employing 3wt% PiSG sample

参考文献 15

[1]	ZHANG Q, ZHANG L, HAN P, et al.Light converting inorganic phosphors for white light-emitting diodes.Progress in Chemistry, 2011, 23(6): 1108-1122.
[2]	Ye S, XIAO F, PAN Y X, et al.Phosphors in phosphor-converted white light-emitting diodes: recent advances in materials, techniques and properties. Materials Science and Engineering: R: Reports, 2010, 71(1): 1-34.
[3]	CRAWFORD M H.LEDs for solid-state lighting: performance challenges and recent advances.IEEE Journal of Selected Topics in Quantum Electronics, 2009, 15(4): 1028-1040.
[4]	SCHUBERT E F, KIM J K. Solid-state light sources getting smart. Science, 2005, 308(5726): 1274-1278.
[5]	TSAI C C, HSU Y C, HUANG S B, et al.Investigation of Ce: YAG doping effect on thermal aging for high-power phosphor-converted white-light-emitting diodes.IEEE Transactions on Device and Materials Reliability, 2009, 9(3): 367-371.
[6]	WANG J, TSAI C C, CHENG W C, et al.High thermal stability of phosphor-converted white light-emitting diodes employing Ce: YAG-doped glass.IEEE Journal of Selected Topics in Quantum Electronics, 2011, 17(3): 741-746.
[7]	YI K L, JIN S L, JONG H, et al.Phosphor in glasses with Pb-free silicate glass powders as robust color-converting materials for white LED applications. Optics letters, 2012, 37(15): 3276-3278.
[8]	ZHU X H, FAN G H, WANG H L, et al.White LED packaged by novel Ce: YAG ceramic phosphor.Journal of Functional Materials and Devices, 2010, 16(4): 389-393.
[9]	HUANG H Y, XIANG W D, ZHANG Z M, et al.Preparation and luminescence properties of cerium, manganese co-doping YAG glass ceramics.Journal of the Chinese Society of Rare Earths, 2012, 06: 726-731.
[10]	FUJITA S, YOSHIHARA S, SAKAMOTO A, et al. YAG glass-ceramic phosphor for white LED (I): background and development. Proceedings of the SPIE-The International Society for Optical Engineering, 2005, 5941: 594111-1-7.
[11]	FUJITA S, SAKAMOTO A, TANABE S.Luminescence characteristics of YAG glass-ceramic phosphor for white LED.IEEE Journal of Selected Topics in Quantum Electronics, 2008, 14(5): 1387-1391.
[12]	TSAI C C, CHENG W C, CHANG J K, et al.Ultra-high thermal- stable glass phosphor layer for phosphor-converted white light-emitting diodes.Journal of Display Technology, 2013, 9(6): 427-432.
[13]	ZHANG R, LIN H, YU Y L, et al.A new-generation color converter for high-power white LED: transparent Ce3+: YAG phosphor-in-glass.Laser & Photonics Reviews, 2014, 8(1): 158-164.
[14]	YONG T O, FUJINO S, MORINAGA K.Fabrication of transparent silica glass by powder sintering.Science and Technology of Advanced Materials, 2002, 3(4): 297-301.
[15]	WEEBER A W, BAKKER H.Amorphization by ball milling. A review. Physica B, 1988, 153(1/2/3): 93-135.

LED用荧光玻璃的制备及性能研究

Preparation and Performance of Ce:YAG Phosphor-in-glass

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 5

参考文献 15

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陆晨辉, 葛万银, 宋盼盼, 张盼锋, 徐美美, 张伟. 用于白光LED稀土Eu掺杂SiAlON基荧光粉的发光性能[J]. 无机材料学报, 2023, 38(1): 97-104.
[2]	邓陶丽, 陈河莘, 黑玲丽, 李淑星, 解荣军. 第二相引入荧光转换材料实现激光驱动高均匀性白光光源[J]. 无机材料学报, 2022, 37(8): 891-896.
[3]	杜傲宸, 杜琪源, 刘欣, 杨益民, 夏晨阳, 邹军, 李江. 高光效、大功率LEDs/LDs用Ce:YAG透明陶瓷[J]. 无机材料学报, 2021, 36(8): 883-892.
[4]	王兆武, 姬海鹏, 王飞翔, 侯星慧, 易莎莎, 周颖, 陈德良. 调控Al₂O₃晶型控制MgAl₂O₄:Mn⁴⁺荧光粉中Mn价态研究[J]. 无机材料学报, 2021, 36(5): 513-520.
[5]	姬海鹏, 张宗涛, XU Jian, TANABE Setsuhisa, 陈德良, 解荣军. Mn⁴⁺激活氧氟化物红光荧光粉的研究进展[J]. 无机材料学报, 2020, 35(8): 847-856.
[6]	董宇辉, 曾书玉, 韩博宁, 薛洁, 宋继中, 曾海波. BN/CsPbX₃复合纳米晶的制备及其白光LED应用[J]. 无机材料学报, 2019, 34(1): 72-78.
[7]	邵秀晨, 周圣明, 唐燕如, 易学专, 郝德明, 陈杰. Ce:YAG荧光陶瓷掺杂Gd对白光LED发光性能的影响[J]. 无机材料学报, 2018, 33(10): 1119-1123.
[8]	张瑞, 王伯阳, 王海. 白光LED用Phosphor-in-Glass荧光材料的研究进展[J]. 无机材料学报, 2017, 32(4): 337-345.
[9]	李杨, 胡丽丽, 杨波波, 石明明, 邹军. 烧结温度对硼硅基质荧光玻璃发光性能影响[J]. 无机材料学报, 2017, 32(3): 257-262.
[10]	王连军, 周蓓莹, 顾士甲, 江莞. 硅基氧化物发光玻璃及其制备技术研究进展[J]. 无机材料学报, 2016, 31(10): 1013-1022.
[11]	向卫东, 赵斌宇, 梁晓娟, 陈兆平, 谢翠萍, 骆乐, 张志敏, 张景峰, 钟家松. 白光LED用Ce:YAG单晶光学性能及封装工艺的研究[J]. 无机材料学报, 2014, 29(6): 614-620.
[12]	张骐昊, 徐磊磊, 王连军, 江莞. Se掺杂量对n型Bi₂Te_3-_xSe_x微结构及热电性能的影响[J]. 无机材料学报, 2014, 29(11): 1139-1144.
[13]	张守超, 阮永丰, 贾国治, 冯志辉, 刘枝朋, 裴利斌. 紫外光激发Ce³⁺掺YVO₄蓝光发射性能研究[J]. 无机材料学报, 2014, 29(10): 1067-1072.
[14]	李梦娜, 雷芳, 陈昊鸿, 施鹰, 赵景泰. Li、Eu掺杂NaY(WO₄)₂荧光粉的合成与红色发光[J]. 无机材料学报, 2013, 28(12): 1281-1285.
[15]	王志军, 李妍, 王颖, 李盼来, 郭庆林, 杨志平. Eu²⁺在KNaCa₂(PO₄)₂中的发光及晶体学格位[J]. 无机材料学报, 2011, 26(7): 731-734.