面向太阳光全光谱应用铒掺杂硫卤玻璃上转换发光特性研究

doi:10.15541/jim20140383

无机材料学报 ›› 2015, Vol. 30 ›› Issue (3): 245-248.DOI: 10.15541/jim20140383

面向太阳光全光谱应用铒掺杂硫卤玻璃上转换发光特性研究

张继红^{1, 2}, 陶海征¹, 顾少轩¹, 张高科², 刘超¹, 赵修建¹

(1. 硅酸盐建筑材料国家重点实验室(武汉理工大学), 武汉430070; 2. 武汉理工大学资源与环境工程学院, 武汉 430070)

收稿日期:2014-07-23 修回日期:2014-09-09 出版日期:2015-03-20 网络出版日期:2015-03-06
作者简介:张继红(1976–), 男, 博士. E-mail: wilhelm_zhang@hotmail.com
基金资助:
新世纪优秀人才支持计划(NCET-11-0687);国家自然科学基金(51172169, 51372180);湖北省自然科学基金(2013CFA008)

Upconversion Luminescence of Er³⁺ Doped Chalcohalide Glasses and Its
Potential Application for Si Solar Cell Efficiency Enhancement

ZHANG Ji-Hong^{1, 2}, TAO Hai-Zheng¹, GU Shao-Xuan¹, ZHANG Gao-Ke², LIU Chao¹, ZHAO Xiu-Jian¹

(1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China; 2. School of Resource and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China)

Received:2014-07-23 Revised:2014-09-09 Published:2015-03-20 Online:2015-03-06
About author:ZHANG Ji-Hong. E-mail: wilhelm_zhang@hotmail.com
Supported by:
Program of New Century Excellent Talents in University (NCET-11-0687);National Natural Science Foundation of China (51172169, 51372180);Natural Science Foundation of Hubei Province, China (2013CFA008)

摘要/Abstract

摘要： 使用熔融淬冷法制备了Er³⁺掺杂Ge-Ga-S-CsBr硫卤玻璃, 研究了其在1550 nm激光激发下的上转换发光特性, 观察到强的波长中心位于525和545 nm绿色发光及弱的中心波长位于660 nm红色发光, 也观察到了中心波长分别位于810和980 nm的红外上转换发光。基于泵探光功率关系和能级寿命测试研究了发光机理, 发现中间态能级寿命的延长是上转换发光效率增强的根本原因。使用全光谱光源测试了Si太阳能效率, 当使用上转换发光层时, 太阳能电池平均效率从7.28%上升至7.32%。结果显示所探索的稀土掺杂硫卤玻璃有望应用于硅太阳能电池效率增强领域。

关键词: 稀土离子, 硫卤玻璃, 上转换发光

Abstract:

Er³⁺ doped Ge-Ga-S-CsBr chalcohalide glasses were fabricated by melt-quenching method. The properties of upconversion luminescence under the excitation of 1550 nm laser were investigated. Strong green emissions centered at 525 nm and 545 nm, and weak red emission centered at 660 nm, were observed, along with near infrared emission bands centered at 810 nm and 980 nm. The up-conversion fluorescence was contributed to multi-photon involved process. The Si solar cell efficiency slightly increased from 7.28% (without upconversion layer) to 7.32% (using Er³⁺ doped 0.9(Ge₂₅Ga₁₀S₆₅)-0.1CsBr glass as upconversion layer). The results show that the investigated Er³⁺-doped chalcohalide glasses has a potential application for the enhancement of Si solar cell efficiency.

Key words: rare earth ions, chalcohalide glass, upconversion luminescence

中图分类号:

TQ174

张继红, 陶海征, 顾少轩, 张高科, 刘超, 赵修建. 面向太阳光全光谱应用铒掺杂硫卤玻璃上转换发光特性研究[J]. 无机材料学报, 2015, 30(3): 245-248.

ZHANG Ji-Hong, TAO Hai-Zheng, GU Shao-Xuan, ZHANG Gao-Ke, LIU Chao, ZHAO Xiu-Jian. Upconversion Luminescence of Er³⁺ Doped Chalcohalide Glasses and Its
Potential Application for Si Solar Cell Efficiency Enhancement[J]. Journal of Inorganic Materials, 2015, 30(3): 245-248.

图/表 4

图1 1550 nm激发条件下, 不同CsBr含量的Er3+掺杂Ge-Ga-S-CsBr硫卤玻璃的可见上转换发光(a)及980 nm附近近红外上转换发光(b)

Fig. 1 Upconversion luminescence of visible region (a) and near IR region at about 980 nm (b) of Er3+-doped Ge-Ga-S-CsBr chalcohalide glasses with different CsBr concentrations under 1550 nm laser excitation

图2 0.90(Ge25Ga10S65)-0.10CsBr玻璃中Er3+上转换发光强度与激发光功率的关系

Fig. 2 Logarithm power dependence on the emission intensity of Er3+-doped 0.90(Ge25Ga10S65)-0.10CsBr chalcohalide glasses

图3 1550 nm激光激发条件下, Er3+的上转换发光机理示意图

Fig. 3 Simplified upconversion luminescence mechanisms for Er3+ in chalcohalide glasses excited with 1550 nm laser

图4 以0.9(Ge25Ga10S65)-0.1CsBr为基质玻璃, Er3+离子2H11/2激发态在不同激发波长下的衰减曲线

Fig. 4 The Er3+ 2H11/2 level decay time changes with different excitation wavelengths (a) 800nm, ~550 μs, (b) 1550 nm, ~3.5 ms

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面向太阳光全光谱应用铒掺杂硫卤玻璃上转换发光特性研究

Upconversion Luminescence of Er³⁺ Doped Chalcohalide Glasses and Its
Potential Application for Si Solar Cell Efficiency Enhancement

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面向太阳光全光谱应用铒掺杂硫卤玻璃上转换发光特性研究

Upconversion Luminescence of Er3+ Doped Chalcohalide Glasses and Its Potential Application for Si Solar Cell Efficiency Enhancement

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Upconversion Luminescence of Er³⁺ Doped Chalcohalide Glasses and Its
Potential Application for Si Solar Cell Efficiency Enhancement