基于PEG修饰的ZnO量子点光学特性研究

doi:10.15541/jim20140080

无机材料学报 ›› 2014, Vol. 29 ›› Issue (10): 1039-1043.DOI: 10.15541/jim20140080

基于PEG修饰的ZnO量子点光学特性研究

檀满林^1,2, 王彦涛¹, 张维丽¹, 符冬菊¹, 李冬霜¹, 王晓伟¹, 马清¹, 陈建军¹, 李廷凯²

(1. 深圳清华大学研究院, 深圳518057; 2. 湖南共创光伏科技有限公司, 衡阳421005)

收稿日期:2014-02-21 修回日期:2014-04-01 出版日期:2014-10-20 网络出版日期:2014-09-22
基金资助:
深圳市基础研究计划(JC201104220174A, JCYJ20130401171536527)

Optical Characteristics of Zinc Oxide Nanoparticles with Surface Modification Using Polyethylene Glycol

TAN Man-Lin^1,2, WANG Yan-Tao¹, ZHANG Wei-Li¹, FU Dong-Ju¹, LI Dong-Shuang¹, WANG Xiao-Wei¹, MA Qing¹, CHEN Jian-Jun¹, LI Ting-Kai²

(1. Research Institute of Tsinghua University in Shenzhen, Shenzhen 518057, China; 2. Hunan Photovoltaic Science & Technology Co. Ltd., Hengyang 421005, China)

Received:2014-02-21 Revised:2014-04-01 Published:2014-10-20 Online:2014-09-22
Supported by:
Shenzhen Fundamental Research Plan: (JC201104220174A, JCYJ20130401171536527)

摘要/Abstract

摘要：

采用溶胶-凝胶法制备了ZnO量子点, 并采用有机高分子试剂PEG(聚乙二醇, M_w=2000)对其表面进行修饰。借助X射线衍射分析、傅立叶红外光谱、光致发光谱和透射显微镜等测试方法, 研究了PEG表面修饰对ZnO量子点结构和光学性能的影响规律。研究表明, 混合加入的PEG聚合物能够成功地包覆在ZnO量子点表面, 但没有改变量子点的晶体结构, 经PEG表面修饰后的ZnO量子点尺寸变小, 稳定性增强, 分散更均匀。同时经PEG修饰的ZnO量子点在400~500 nm波长区域缺陷态发射峰明显减弱, 表明采用PEG来改善ZnO量子点表面缺陷结构具有良好效果。

关键词: ZnO量子点, PEG, 表面修饰, 发光性能

Abstract:

Surface of Zinc oxide (ZnO) nanoparticles prepared by Sol-Gel method was modified by a polymer reactant, PEG (polyethylene glycol, M_w=2000). The structure and optical properties of the PEG modified nanoparticles were then investigated by X-ray diffraction, Fourier transform infrared spectroscopy, photoluminescence spectroscopy, transmission electron microscopy. Results showed that the added PEG polymers were successfully coated on the surface of ZnO nanoparticles, without obvious variation being found in the ZnO crystal structure. The ZnO particles tend to have a smaller size, better stability and better dispersible uniformity after PEG coating. Furthermore, a defect state emission peak with significantly reduced intensity was found at the range of 400-500 nm in photoluminescence spectra, indicating that the surface defects of ZnO nanoparticles could be well improved by PEG modification.

Key words: ZnO nanoparticles, PEG, surface modification, photoluminescence characteristics

中图分类号:

O647

檀满林, 王彦涛, 张维丽, 符冬菊, 李冬霜, 王晓伟, 马清, 陈建军, 李廷凯. 基于PEG修饰的ZnO量子点光学特性研究[J]. 无机材料学报, 2014, 29(10): 1039-1043.

TAN Man-Lin, WANG Yan-Tao, ZHANG Wei-Li, FU Dong-Ju, LI Dong-Shuang, WANG Xiao-Wei, MA Qing, CHEN Jian-Jun, LI Ting-Kai. Optical Characteristics of Zinc Oxide Nanoparticles with Surface Modification Using Polyethylene Glycol[J]. Journal of Inorganic Materials, 2014, 29(10): 1039-1043.

图/表 5

图1 不同PEG添加量ZnO量子点的XRD图谱

Fig. 1 XRD patterns of ZnO quantum dots with different amounts of PEG modification (a) 0; (b) 4.8%; (c) 9.1%; (d) 16.7%; (e) 28.6%

图2 不同PEG添加量ZnO量子点的红外吸收

Fig. 2 FTIR patterns of ZnO quantum dots with different amouns of PEG modification (a) 0; (b) 4.8%; (c) 9.1%; (d) 16.7%; (e) 28.6%

图3 不同PEG添加量ZnO量子点的光致发光光谱图

Fig. 3 PL patterns of ZnO quantum dots with different amo-uns of PEG modification (a) 0; (b) 4.8%; (c) 9.1%; (d) 16.7%; (e) 28.6%

图4 PEG修饰前(a)后(b)ZnO量子点的TEM照片

Fig. 4 TEM images of ZnO quantum dots before (a) and after (b) PEG modification

图5 不同陈化时间后ZnO量子点的紫外可见光谱

Fig. 5 UV-visible spectra of ZnO quantum dots with differ-ent aging time (a) Without modification; (b) After PEG modification

参考文献 17

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基于PEG修饰的ZnO量子点光学特性研究

Optical Characteristics of Zinc Oxide Nanoparticles with Surface Modification Using Polyethylene Glycol

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