AgIn合金量子点复合玻璃的制备及光学性质研究

doi:10.15541/jim20140015

无机材料学报 ›› 2014, Vol. 29 ›› Issue (10): 1034-1038.DOI: 10.15541/jim20140015

AgIn合金量子点复合玻璃的制备及光学性质研究

尹德武^1,2, 刘振², 杨昕宇², 张希艳¹, 向卫东²

(1. 长春理工大学材料科学与工程学院, 长春130022; 2. 温州大学化学与材料工程学院, 温州325035)

收稿日期:2014-01-06 修回日期:2014-04-29 出版日期:2014-10-20 网络出版日期:2014-09-22
作者简介:尹德武(1977–), 男, 博士研究生. E-mail: dewuyin@wzu.edu.cn
基金资助:
国家自然科学基金(51202166);浙江省自然科学基金(Y4100233)

Preparation and Optical Properties of AgIn Alloy Quantum Dots Doped Glass

YIN De-Wu^1,2, LIU Zhen², YANG Xin-Yu², ZHANG Xi-Yan¹, XIANG Wei-Dong²

(1. College of Materials Sciense and Engineering, Changchun University of Science and Technology, Changchun 130022, China; 2. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China)

Received:2014-01-06 Revised:2014-04-29 Published:2014-10-20 Online:2014-09-22
About author:YIN De-Wu. E-mail: dewuyin@wzu.edu.cn
Supported by:
National Natural Science Foundation of China (51202166);Zhejiang Province Natural Science Foundation of China(Y4100233)

摘要/Abstract

摘要：

采用溶胶-凝胶法结合气氛控制的技术制备了AgIn合金量子点掺杂钠硼硅基(NBS)玻璃。利用X射线粉末衍射仪(XRD)、X射线光电子能谱(XPS)、高分辨透射电子显微镜(HRTEM)以及选区电子衍射(SAED)对AgIn合金量子点在玻璃中的形貌和微结构进行了表征, 并利用荧光光谱仪对该玻璃的荧光性质进行了研究。结果表明, 在600℃热处理下钠硼硅玻璃中形成了尺寸分布在5 nm左右的均一的AgIn六方晶系量子点, 而且分布在玻璃中的AgIn量子点在435 nm附近存在一个荧光峰, 表明AgIn量子点掺杂NBS玻璃可以作为激光源、非线性介质和光子设备的候选玻璃。

关键词: AgIn合金量子点, 溶胶-凝胶法, 荧光, 钠硼硅玻璃

Abstract:

Indium-silver alloy quantum dots doped sodium borosilicate (NBS) glass was prepared by Sol-Gel method with controlled atmosphere technology. The morphology and microstructure of AgIn alloy quantum dots in the glass were characterized by means of X-ray powder diffraction (XRD), X-ray photoelectron spectroscope (XPS), high- resolution transmission electron microscope (HRTEM) and electron diffraction (SAED). The fluorescent properties of the glass by fluorescence spectrometer were studied. The results showed that indium-silver alloy quantum dots with an average grain size of 5 nm were finely dispersed in the sodium borosilicate glass after heat-treated at 600℃. Indium- silver alloy quantum dots in the glass exhibited a fluorescence peak at around 435 nm which nominated AgIn quantum dots doped NBS glass as the candidate glass for laser sources, nonlinear media and photonic applications.

Key words: indium-silver alloy quantum dots, Sol-Gel method, fluorescence, sodium borosilicate glass

中图分类号:

TQ174

尹德武, 刘振, 杨昕宇, 张希艳, 向卫东. AgIn合金量子点复合玻璃的制备及光学性质研究[J]. 无机材料学报, 2014, 29(10): 1034-1038.

YIN De-Wu, LIU Zhen, YANG Xin-Yu, ZHANG Xi-Yan, XIANG Wei-Dong. Preparation and Optical Properties of AgIn Alloy Quantum Dots Doped Glass[J]. Journal of Inorganic Materials, 2014, 29(10): 1034-1038.

图/表 4

图1 不同处理温度下获得的玻璃的XRD图谱

Fig. 1 XRD patterns of as-obtained glass after heat-treatment at different temperatures

图2 经过O2→N2→H2气氛处理后, AgIn合金玻璃的Ag3d核和In3d核的XPS能谱图

Fig.2 Ag3d and In3d core XPS spectra of AgIn glass sample after treatment in O2→N2→H2 atmosphere

图3 AgIn玻璃的(a)TEM照片、(b)电子选区衍射、(c) HRTEM照片、(d) EDX分析和(e)样品尺寸分布图

Fig.3 TEM image (a), SAED pattern (b), HRTEM image (c), EDX analyses (d) and size distribution (e) of AgIn glass sample

图4 掺杂AgIn玻璃和纯NBS玻璃的荧光发射光谱图

Fig. 4 Fluorescence emission spectra of the glass doped with AgIn quatumn dots and pure NBS glass

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AgIn合金量子点复合玻璃的制备及光学性质研究

Preparation and Optical Properties of AgIn Alloy Quantum Dots Doped Glass

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