Ti3AlC2体材料的高温临氢行为研究

doi:10.15541/jim20130584

无机材料学报 ›› 2014, Vol. 29 ›› Issue (8): 864-868.DOI: 10.15541/jim20130584

Ti₃AlC₂体材料的高温临氢行为研究

陈辰^{1, 2}, 张海斌², 彭述明², 赵林杰², 朱建国¹

(1. 四川大学材料科学与工程学院, 成都 610065; 2. 中国工程物理研究院核物理与化学研究所, 绵阳 621900)

收稿日期:2013-11-12 修回日期:2014-01-18 出版日期:2014-08-20 网络出版日期:2014-07-15
作者简介:陈辰(1986-), 男, 硕士研究生. E-mail: 16111612@qq.com
基金资助:
国家自然科学基金(91326102);中国工程物理研究院科学技术发展基金(2012B0302035, 2013A0301012)

High Temperature Hydrogenation Behavior of Bulk Titanium Aluminum Carbide

CHEN Chen^{1, 2}, ZHANG Hai-Bin², PENG Shu-Min², ZHAO Lin-Jie², ZHU Jian-Guo¹

(1. College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China; 2. Institute of Nuclear Physics and Chemistry, Chinese Academy of Engineering Physics, Mianyang 621900, China)

Received:2013-11-12 Revised:2014-01-18 Published:2014-08-20 Online:2014-07-15
About author:CHEN Chen. E-mail: 16111612@qq.com
Supported by:
National Natural Science Foundation of China(91326102);Science and Technology Development Foundation of China Academy of Engineering Physics(2012B0302035, 2013A0301012)

摘要/Abstract

摘要：

实验研究了Ti₃AlC₂体材料在700~1000℃氢气氛中的热稳定性。通过XRD、SEM、EDS、XPS和Raman分析手段对反应产物和材料形貌进行了表征, 通过热力学软件Factsage对气体产物进行了理论模拟。在700~1000℃氢气氛(低O压)条件下, 固态产物是Al₂O₃、TiO₂和石墨, 气态产物是CH₄, 未检测到氢化物的生成。SEM分析表明, 样品表面未生成明显的孔洞和裂缝。通过Ti₃AlC₂临氢前后的物相及形貌变化分析结果, 初步表明这种材料具有良好的抗氢性能, 可能的原因是反应产物中生成的氧化物对Ti₃AlC₂基体起到了保护作用。

关键词: Ti3AlC2, 氢气氛, 热稳定性, 抗氢性能

Abstract:

Ti₃AlC₂ is a new type of nano-layered machinable ceramic with numerous salient properties. Therefore, recently it is considered to be a promising candidate for new generation reactors as the key structural material. In this work, the reaction product and material morphology between nano-layered Ti₃AlC₂ and hydrogen were investigated by XRD, SEM, EDS, XPS and Raman. The resulted gaseous products were calculated by Factsage sofeware. Under the condition of 700-1000℃, hydrogen atmosphere (low oxygen pressure), solid products are Al₂O₃, TiO₂ and C and gaseous product is CH₄. Hydrides are not detected in the current experiments. The SEM results indicate that the reacted samples keep intact and cracks are not formed on the surface, indicating the high temperature thermal stability of Ti₃AlC₂ in hydrogen. These results can be attributed to the formation of oxides on the surface of specimens.

Key words: Ti3AlC2, hydrogen atmosphere, thermal stability, hydrogen resistance

中图分类号:

TQ174

陈辰, 张海斌, 彭述明, 赵林杰, 朱建国. Ti₃AlC₂体材料的高温临氢行为研究[J]. 无机材料学报, 2014, 29(8): 864-868.

CHEN Chen, ZHANG Hai-Bin, PENG Shu-Min, ZHAO Lin-Jie, ZHU Jian-Guo. High Temperature Hydrogenation Behavior of Bulk Titanium Aluminum Carbide[J]. Journal of Inorganic Materials, 2014, 29(8): 864-868.

图/表 6

图1 Ti3AlC2在700~1000℃的1mol%氢气和99mol%氩气的混合气氛(含10-6wt% O2)中反应10 h后的XRD图谱

Fig. 1 XRD patterns of Ti3AlC2 specimens after treatment at 700-1000℃ for 10 h in 1mol% H2 and 99mol% Ar(contain-ing 10-6wt% O2)

图2 Ti3AlC2在700~1000℃的1mol%氢气和99mol%氩气的混合气氛(含10-6wt% O2)中反应后的拉曼光谱

Fig. 2 Raman spectra of bulk Ti3AlC2 after treatment at 700- 1000℃ in 1mol% H2 and 99mol% Ar(containing 10-6wt% O2)

图3 Ti3AlC2标样在800℃和1000℃临氢(含10-6 wt% O2)后的XPS分析

Fig. 3 XPS surface analysis of Ti3AlC2 after hydrogen treatment (containing 10-6 wt% O2) at 800℃ and 1000℃ (a) Al2p; (b) O1s; and (c) Ti2p contrast

图4 Ti3AlC2 在(a)700℃、(b)800℃、(c)900℃和(d)1000℃的1mol%氢气和99mol%氩气的混合气氛(含10-6wt% O2)中恒温10 h后的表面SEM形貌

Fig. 4 Surface morphologies of the Ti3AlC2 specimens after treatment for 10 h at (a) 700℃, (b) 800℃, (c) 900℃ and (d) 1000℃ in the 1mol% H2 and 99mol% Ar (containing 10-6wt% O2)

表1 图4中A、B、C、D、E五点的EDS能谱数据

Table 1 EDS analyses of spots A, B, C, D, E in Fig. 4

	A	B	C	D	E
O/wt%	20.29	36.23	46.57	42.27	56.53
Al/wt%	14.30	41.67	12.97	31.33	35.99
Ti/wt%	51.54	18.38	32.59	19.22	7.48

图5 1.013×105 Pa, 500~1200℃ Ti3AlC2与H2反应的气态产物的模拟结果

Fig. 5 Simulated result of gaseous reaction product of Ti3AlC2 and H2 at 500-1200℃

参考文献 8

[1]	GRAEME ACKLAND. Controlling radiation damage. Materials Science, 2010, 327(5973): 1587-1588.
[2]	BARNES L A, DIETZ RAGO N L, LEIBOWITZ L. Corrosion of ternary carbides by molten lead. Journal of Nuclear Materials, 2008, 373(1/2/3): 424-428.
[3]	HEINZEL A, MÜLLER G, WEISENBURGER A. Compatibility of Ti3SiC2 with liquid Pb and PbBi containing oxygen. Journal of Nuclear Materials, 2009, 392(2): 255-258.
[4]	张磊. 辐照损伤材料的实验模拟研究:含氦薄膜制备及MAX相材料离子辐照行为. 上海: 复旦大学博士学位论文, 2011.
[5]	WHITTLE K R, BLACKFORD M G, AUGHTERSON R D, et al. Radiation tolerance of Mn+1AXn phases, Ti3AlC2 and Ti3SiC2. Acta Materialia, 2010, 58(13): 4362-4368.
[6]	王晓辉. 层状可加工陶瓷Ti3AlC2、Ti2AlC的合成与性能. 沈阳: 中国科学院沈阳金属研究所博士学位论文, 2005.
[7]	QU X D, WANG Y X, SHI L Q, et al. Effect of hydrogen-doping on bonding properties of Ti3SiC2. Physica B, 2011, 406(23): 4460-4465.
[8]	ZHANG HAIBIN, VOLKER PRESSER, CHRISTOPH BERTH-OLD, et al. Mechanisms and kinetics of the hydrothermal oxidation of bulk titanium silicon carbide. Journal of American Ceramic Society, 2010, 93(4): 1148-1155.

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Ti₃AlC₂体材料的高温临氢行为研究

High Temperature Hydrogenation Behavior of Bulk Titanium Aluminum Carbide

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