Bi2O3-SiO2玻璃及玻璃陶瓷近红外发光性能的研究

doi:10.15541/jim20130604

摘要/Abstract

摘要：

采用高温熔融法制备了Bi₂O₃-SiO₂玻璃及玻璃陶瓷, 测试了样品的近红外光区及可见光区的发射谱、激发谱及荧光寿命。在808 nm波长光的激发下, Bi₂O₃-SiO₂玻璃及玻璃陶瓷中均发现了近红外发光。当Bi₂O₃含量较低时(30mol%、40mol%、50mol%), 发光中心位于1336 nm(或1300 nm), 为宽带发光; 随Bi₂O₃含量的增加, 1070 nm左右出现了窄带近红外发光峰, 且逐渐成为最强发光峰, 与此同时, 1336 nm(或1300 nm)的宽带发光转变为窄带发光。1336 nm (或1300 nm)与1070 nm发射峰的荧光寿命及激发谱均存在较大的区别, 初步分析认为这两个发射峰归属于不同的发光中心, 1336 nm(或1300 nm)发射峰源于低价态Bi离子。

关键词: 近红外发光, Bi离子, 玻璃陶瓷

Abstract:

Bi₂O₃-SiO₂glasses and glass ceramics were prepared by melting method. Infrared and VIS luminescence spectra, excitation spectra and fluorescence decay curves were measured. Near infrared (NIR) luminescence of Bi₂O₃-SiO₂glasses and glass ceramics was observed under 808 nm Laser Diode pumping. When the content of Bi₂O₃ is low (30mol%, 40mol%, 50mol%), NIR luminescence peak at 1336 nm (or 1300 nm) with full width at half maximum (FWHM) about 200 nm is observed. With the increase of Bi₂O₃ content, another peak at about 1070 nm with narrow FWHM appears and becomes the main peak, while the FWHM of the NIR emission centered at 1336 nm (or 1300 nm) decreases to only tens of nanometer. Two emission bands have different excitation bands and lifetime. We propose NIR emissions located at 1070 nm and 1336 nm (or 1300 nm) originate from different bismuth centers. The infrared emission peaked at about 1336 nm (or 1300 nm) derives from low valence Bi ions.

Key words: near infrared emission, Bi ions, glass ceramics

中图分类号:

TB321

刘军芳, 苏良碧, 徐军. Bi₂O₃-SiO₂玻璃及玻璃陶瓷近红外发光性能的研究[J]. 无机材料学报, 2014, 29(8): 859-863.

LIU Jun-Fang, SU Liang-Bi, XU Jun. Near-infrared Luminescence Properties of Bi₂O₃-SiO₂Glasses and Glass Ceramics[J]. Journal of Inorganic Materials, 2014, 29(8): 859-863.

图/表 6

图1 Bi2O3 -SiO2 玻璃陶瓷的XRD图谱

Fig. 1 XRD patterns of Bi2O3 -SiO2 glass-ceramics

图2 Bi2O3 -SiO2 玻璃及玻璃陶瓷在808 nm抽运源下的发射光谱

Fig. 2 Emission spectra of Bi2O3-SiO2 glasses and glass- ceramics under excitation at 808 nm

图3 1070 nm与1336 nm发光峰强度的比值I1070/I1336随Bi2O3浓度变化关系曲线

Fig. 3 Dependence of I1070/I1336 on the Bi2O3 concentration

图4 30Bi2O3-70SiO2玻璃1300 nm和70Bi2O3-30SiO2玻璃陶瓷1063 nm荧光峰的激发谱及30Bi2O3 -70SiO2玻璃吸收谱

Fig. 4 Excitation spectra for emission at 1300 nm in 30Bi2O3-70SiO2 glass and 1063 nm in 70Bi2O3-30SiO2 glass ceramics and the absorption spectrum of 30Bi2O3-70SiO2 glass

图5 30Bi2O3-70SiO2玻璃在1300 nm处的衰减曲线(a)和70Bi2O3-30SiO2玻璃陶瓷在1063 nm处的衰减曲线(b)

Fig. 5 Fluorescence decay curves of 30Bi2O3-70SiO2 glass at 1300 nm (a) and 70Bi2O3-30SiO2 glass ceramics at 1063 nm (b)

图6 70Bi2O3 -30SiO2 玻璃陶瓷在330 nm激发下的发射光谱

Fig. 6 Luminescence spectrum of 70Bi2O3-30SiO2 glass- ceramics excited by 330 nm

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Bi₂O₃-SiO₂玻璃及玻璃陶瓷近红外发光性能的研究

Near-infrared Luminescence Properties of Bi₂O₃-SiO₂Glasses and Glass Ceramics

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