前处理温度与氯化钠浓度对ZSM-5沸石能量耗散特性的影响

doi:10.3724/SP.J.1077.2014.13447

无机材料学报 ›› 2014, Vol. 29 ›› Issue (5): 523-528.DOI: 10.3724/SP.J.1077.2014.13447

前处理温度与氯化钠浓度对ZSM-5沸石能量耗散特性的影响

孙岳霆¹, 许骏², 李一兵¹, 徐晓庆¹, 刘成³

(1. 清华大学汽车安全与节能国家重点实验室, 北京 100084; 2. 哥伦比亚大学地球与环境工程系, 美国纽约10027; 3. 装甲兵工程学院, 北京 100072)

收稿日期:2013-09-02 修回日期:2013-11-13 出版日期:2014-05-20 网络出版日期:2014-04-24
作者简介:孙岳霆(1988–), 男, 博士研究生. E-mail: syt06@mails.tsinghua.edu.cn
基金资助:
清华大学自主科研计划国际合作基础研究专项(20121080050); 汽车安全与节能国家重点实验室(ZZ2011-112)

Effect of Pretreatment Temperature and Sodium Chloride Concentration on Energy Dissipation Characteristics of ZSM-5/Water System

SUN Yue-Ting¹, XU Jun², LI Yi-Bing¹, XU Xiao-Qing¹, LIU Cheng³

(1. State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China; 2. Department of Earth and Environmental Engineering, Columbia University, New York NY 10027, USA; 3. Academy of Armored Force Engineering, Beijing 100072, China)

Received:2013-09-02 Revised:2013-11-13 Published:2014-05-20 Online:2014-04-24
About author:SUN Yue-Ting. E-mail: syt06@mails.tsinghua.edu.cn
Supported by:
International Joint Research Project Sponsored by Tsinghua University (20121080050); Individual-research Founding State Key Laboratory of Automotive Safety & Energy, Tsinghua University (ZZ2011-112)

摘要/Abstract

摘要： 高能量耗散密度材料的研发是防护工程领域的研究热点。纳米多孔材料具有超大的比表面积, 其与液体的相互作用能够耗散大量外界能量, 因此在车辆碰撞安全等领域具有出色的应用前景。本研究选取ZSM-5沸石/NaCl溶液系统, 通过准静态实验研究该系统的能量耗散行为, 并阐明其机理, 同时参数化地研究了沸石的前处理温度(600~1100℃)及溶液的NaCl浓度(0~2 mol/kg)对系统能量耗散性能的影响。结果表明: 该系统在准静态加载条件下具有较高的能量耗散密度, 达到12 J/g, 且可重复使用; 该系统的工作性能可在较大范围内调节, 其能量耗散密度与沸石前处理温度正相关, 与NaCl浓度负相关; 其工作压强与沸石前处理温度及NaCl浓度均正相关。本研究为开发智能、可控和高效的能量耗散系统提供了必要的基础理论与实验依据。

关键词: 纳米多孔材料, 能量耗散, 前处理温度, 离子浓度, 安全防护

Abstract: Research and development of new materials with high energy dissipation density is of intriguing interest in protective engineering fields. With ultra-large specific surface area, nanoporous material enables a high-efficiency energy dissipation system by interaction with liquids, which has a promising application in vehicle crash safety and anti-explosion for armored vehicles. In this paper, ZSM-5 zeolite / NaCl solution system, a mixture with ZSM zeolite immersed in sodium chloride solution was experimentally investigated. Its energy dissipation characteristics and working mechanism were explored by quasi-static compression experiments. Effect of pretreatment temperature of ZSM-5 zeolite (600–1100℃) and NaCl concentration of the solution (0–2 mol/kg) were examined parametrically. Results show that the energy dissipation density of ZSM-5 zeolite / NaCl solution system can reach 12 J/g, as a reusable system under quasi-static loading. Its performance characteristics can be finely tuned by pretreatment of ZSM-5 and adding different concentrations of NaCl. The energy dissipation density increases with pretreatment temperature and decreases with NaCl concentration, while its working pressure increases with both of them. This work is of significance for the development of intelligent, controllable and efficient energy dissipation devices.

Key words: nanoporous material, energy dissipation, pretreatment temperature, ion concentration, safety protection

中图分类号:

O647

孙岳霆, 许骏, 李一兵, 徐晓庆, 刘成. 前处理温度与氯化钠浓度对ZSM-5沸石能量耗散特性的影响[J]. 无机材料学报, 2014, 29(5): 523-528.

SUN Yue-Ting, XU Jun, LI Yi-Bing, XU Xiao-Qing, LIU Cheng. Effect of Pretreatment Temperature and Sodium Chloride Concentration on Energy Dissipation Characteristics of ZSM-5/Water System[J]. Journal of Inorganic Materials, 2014, 29(5): 523-528.

参考文献

[1] XU JUN, LI YI-BING. Study of damage in windshield glazing subject to impact by a pedestrian's head. Proceedings of the Institution of Mechanical Engineers Part D-Journal of Automobile Engineering, 2009, 223: 77–84.

[2] XU JUN, XU BAO-XING, SUN YUE-TING, et al. Mechanical energy absorption characteristics of hollow and water-filled carbon nanotubes upon low-speed crushing. Journal of Nanomechanics and Micromechanics, 2012, 2(4): 65–70.

[3] XU JUN, SUN YUE-TING, LIU BO-HAN, et al. Experimental and macroscopic investigation of dynamic crack patterns in PVB laminated glass sheets subject to light-weight impact. Engineering Failure Analysis, 2011, 18(6): 1605–1612.

[4] Traffic Management Bureau, China Road Traffic Safety Statistical Yearbook (2012), Jiangsu, 2013: 139.

[5] TIMMEL M, KOLLING S, OSTERRIEDER P, et al. A finite element model for impact simulation with laminated glass. International Journal of Impact Engineering, 2007, 34(8): 1465–1478.

[6] QI W G, JIN X L, ZHANG X Y. Improvement of energy-absorbing structures of a commercial vehicle for crashworthiness using finite element method. International Journal of Advanced Manufacturing Technology, 2006, 30(11/12): 1001–1009.

[7] QIAO YU, LIU LING, CHEN XI. Pressurized liquid in nanopores: a modified laplace-Young equation. Nano Letters, 2009, 9(3): 984–988.

[8] LIU LING, CHEN XI, LU WEI-YI, et al. Infiltration of electrolytes in molecular-sized nanopores. Physical Review Letters, 2009, 102(18): 184501–1–4.

[9] KOO KYUNG-HOAE, CHO HOYEOL, KAPUR PAWAN, et al. Performance comparisons between carbon nanotubes, optical, and Cu for future high-performance on-chip interconnect applications. IEEE Transactions on Electron Devices, 2007, 54(12): 3206–3215.

[10] LEE DEUK-YONG, LEE MYUNG-HYUN, KIM KWANG J, et al. Effect of multiwalled carbon nanotube (M-CNT) loading on M-CNT distribution behavior and the related electromechanical properties of the M-CNT dispersed ionomeric nanocomposites. Surface & Coatings Technology, 2005, 200(5/6): 1920–1925.

[11] LEE DEUK-YONG, PARK I1-SEOK, LEE MYUNG-HYUN, et al. Ionic polymer-metal composite bending actuator loaded with multi-walled carbon nanotubes. Sensors and Actuators A-physical, 2007, 133(1): 117–127.

[12] SUN YUE-TING, XU JUN, LI YI-BING, et al. Experimental study on energy dissipation characteristics of ZSM-5 zeolite/water system. Advanced Engineering Materials, 2013, 15(8): 740–746.

[13] GUSEV VLADIMIR YU. On thermodynamics of permanent hysteresis in capillary lyophobic systems and interface characterization. Langmuir, 1994, 10(1): 235–240.

[14] EROSHENKO V A, FADEEV A Y. Intrusion and extrusion of water in hydrophobized porous silica. Colloid Journal,?1995, 57(4): 446-449.

[15] XU BAO-XING, QIAO YU, PARK TAEHYO, et al. A conceptual thermal actuation system driven by interface tension of nanofluids. Energy & Environmental Science, 2011, 4(9): 3632–3639.

[16] ROTH WIESLAW J, NACHTIGALL PETR, MORRIS RUSSELL E, et al. A family of zeolites with controlled pore size prepared using a top-down method. Nature Chemistry, 2013, 5(5): 628–633.

[17] HAN AI-JIE, QIAO YU. Pressure-induced infiltration of aqueous solutions of multiple promoters in a nanoporous silica. Journal of The American Chemical Society, 2006, 128(32): 10348–10349.

[18] QIAO YU, PUNYAMURTULA VENKATA K, HAN AI-JIE, et al. Temperature dependence of working pressure of a nanoporous liquid spring. Applied Physics Letters, 2006, 89(25): 251905–1–3.

[19] CHEN XI, CAO GUO-XIN, HAN AI-JIE, et al. Nanoscale fluid transport: size and rate effects. Nano Letters, 2008, 8(9): 2988–2992.

[20] MU XU-HONG, WANG DIAN-ZHONG, WANG YONG-RUI, et al. Nanosized molecular sieves as petroleum refining and petrochemical catalysts. Chinese Journal of Catalysis, 2013, 34(1): 69–79.

[21] YUE MING-BO, YANG NA, WANG YI-MENG. Synthesis of shaped ZSM-5 zeolites by dry-gel conversion with seed gel as directing agent. Acta Physico-chimica Sinica, 2012, 28(9): 2115–2121.

[22] Structure Commission of the International Zeolite Association. Database of zeolite structure[EB/OL] http://izasc.ethz.ch/fmi/xsl/ IZA-SC/ftc_tm.xsl?-db=Atlas_main&-lay=tm&STC=MFI&-find, 2013–06–30.

[23] MAVKO GARY, MUKERJY TAPAN, DVORKIN JACK. Rock Physics Handbook: Tools for Seismic Analysis of Porous Media, 2nd ed.; Cambridge: Cambridge University Press, 2009: 176.

[24] QUARTIERI SIMONA, MONTAGNA GABRIELE, ARLETTI ROSSELLA, et al. Elastic behavior of MFI-type zeolites: compressibility of H-ZSM-5 in penetrating and non-penetrating media. Journal of Solid State Chemistry, 2011, 184(6): 1505–1516.

[25] ARLETTI ROSSELLA, VEZZALINI GIOVANNA, MORSLI AMINE, et al. Elastic behavior of MFI-type zeolites: 1-Compressibility of Na-ZSM-5 in penetrating and non-penetrating media. Microporous and Mesoporous Materials, 2011, 142(2/3): 696–707.

[26] IEVTUSHENKO OLEKSII V, EROSHENKO VALENTIN A, GROSU YAROSLAV G, et al. Evolution of the energetic characteristics of {silicalite-1 plus water} repulsive clathrates in a wide temperature range. Physical Chemistry Chemical Physics, 2013, 15(12): 4451–4457.

[27] COIFFARD LO?C, EROSHENKO VALENTIN. Temperature effect on water intrusion/expulsion in grafted silica gels. Journal of Colloid and Interface Science, 2006, 300(1): 304–309.

[28] MAO DONG-SEN, GUO QIANG-SHENG, MENG TAO, et al. Effect of hydrothermal treatment on the acidity and catalytic performance of nanosized HZSM-5 zeolites for the conversion of methanol to propene. Acta Physico-chimica Sinica, 2010, 26(2): 338–344.

[29] LI YAN-FENG, ZHU JI-QIN, LIU HUI, et al. Increase in the hydrothermal stability of the La-modified ZSM-5 zeolite. Acta Physico-chimica Sinica, 2011, 27(1): 52–58.

[30] LANE CHRISTOPHER D, HATHCOCK DAVID J, LEAVITT ANDREW J, et al. Measurement of the bulk modulus of a liquid using a pump-probe laser technique. The Chemical Educator, 2001, 6(4): 235–237.

[31] JARVIS N L, SCHEIMAN M A. Surface potentials of aqueous electrolyte solutions. Journal of Physical Chemistry, 1968, 72(1): 74–78.

[32] WEISSENBORN PETER K., PUGH ROBERT J. Surface tension of aqueous solutions of electrolytes: relationship with ion hydration, oxygen solubility, and bubble coalescence. Journal of Colloid and Interface Science, 1996, 184(2): 550–563.

[33] KONG XIN-GUO, SURANI FALGUN B, QIAO YU. Energy absorption of nanoporous silica particles in aqueous solutions of sodium chloride. Physica Scripta, 2006, 74(5): 531–534.

[34] KONG XIN-GUO, QIAO YU. Improvement of recoverability of a nanoporous energy absorption system by using chemical admixture. Applied Physics Letters, 2005, 86(15): 151919–1–3.

前处理温度与氯化钠浓度对ZSM-5沸石能量耗散特性的影响

Effect of Pretreatment Temperature and Sodium Chloride Concentration on Energy Dissipation Characteristics of ZSM-5/Water System

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价