纳米铁钴合金/石墨复合材料的微波吸收性能研究

doi:10.3724/SP.J.1077.2014.13367

无机材料学报 ›› 2014, Vol. 29 ›› Issue (5): 470-474.DOI: 10.3724/SP.J.1077.2014.13367

纳米铁钴合金/石墨复合材料的微波吸收性能研究

李佳, 刘洪波, 杨丽

(湖南大学材料科学与工程学院, 长沙 410082)

收稿日期:2013-07-16 修回日期:2013-09-17 出版日期:2014-05-20 网络出版日期:2014-04-24
作者简介:李佳(1983–), 男, 博士研究生. E-mail: Lijia0330@163.com
基金资助:
湖南省自然科学基金(10JJ3019)

Research on Microwave Absorption Properties of FeCo/Graphite Nanocomposite

LI Jia, LIU Hong-Bo, YANG Li

(College of Material Science and Engineering, Hunan University, Changsha 410082, China)

Received:2013-07-16 Revised:2013-09-17 Published:2014-05-20 Online:2014-04-24
About author:LI Jia. E-mail: Lijia0330@163.com
Supported by:
Natural Science Foundation of Hunan Province (10JJ3019)

摘要/Abstract

摘要： 利用氧化石墨的吸附性能将Fe³⁺和Co²⁺吸附到氧化石墨层间制备出Fe³⁺Co²⁺/氧化石墨复合物, 再通过氢气还原制备出纳米铁钴合金/石墨复合材料, 采用XRD和SEM以及磁滞回线测试等手段对其晶体结构、微观形貌以及磁学性能进行表征, 探讨了FeCo合金含量对其微波吸收性能的影响。结果表明: 所制备的产物为石墨和纳米FeCo合金颗粒组成的二元复合材料, FeCo合金分散在石墨表面和层间, 粒径为30~150 nm。纳米铁钴合金/石墨复合材料是典型的软磁性材料, 饱和磁化强度随FeCo合金含量的减小而降低。随着FeCo合金含量的减少, 纳米FeCo/石墨复合材料的介电损耗逐渐增加, 磁损耗逐渐减小。FeCo合金含量适当时, 介电损耗和磁损耗的协同作用使复合材料具有较好的微波吸收性能。

关键词: FeCo, 氧化石墨, 纳米复合材料, 微波吸收

Abstract: Fe³⁺Co²⁺/graphite oxide composites were firstly prepared by absorbing Fe³⁺ and Co²⁺ into the layers of graphite oxide based on absorption property of graphite oxide. And then FeCo/graphite nanocomposites were synthesized by reducing the Fe³⁺Co²⁺/graphite oxide compounds with H₂. The crystal structure, morphology and magnetic properties were characterized by XRD, SEM and magnetic loop analysis, and the microwave absorption properties, caused by content variation of FeCo alloy, was investigated. Results indicated that the FeCo/graphite nanocomposite was two-phase material composed by graphite and nano FeCo particles. With diameter ranging from 30 nm to 150 nm, the FeCo particles dispersed both on the surface of and between the graphite layers, which made the FeCo/graphite nanocomposite a typical soft magnetic material. With the FeCo alloy content decrease, the saturation magnetization and magnetic loss increased but the dielectric loss decreased. With proper FeCo alloy content, the synergistic effect of dielectric loss and magnetic loss could lead to the FeCo/graphite nanocomposite displaying good microwave absorption property.

Key words: FeCo, graphite oxide, nanocomposite, microwave absorption

中图分类号:

TM25

李佳, 刘洪波, 杨丽. 纳米铁钴合金/石墨复合材料的微波吸收性能研究[J]. 无机材料学报, 2014, 29(5): 470-474.

LI Jia, LIU Hong-Bo, YANG Li. Research on Microwave Absorption Properties of FeCo/Graphite Nanocomposite[J]. Journal of Inorganic Materials, 2014, 29(5): 470-474.

参考文献

[1] ZHOU, Z CHU L, HU S. Microwave absorption behaviors of tetra- needle-like ZnO whiskers. Mater. Sci. Eng., B, 2006, 126(1): 93–96.

[2] WANG G, CHANG Y, WANG L, et al. Synthesis, characterization and microwave absorption properties of Fe3O4/Co core/shell-type nanoparticles. Adv. Powder Technol., 2012, 23(6): 861–865.

[3] ZHANG T, HUANG D, YANG Y, et al. Fe3O4/carbon composite nanofiber absorber with enhanced microwave absorption performance. Mater. Sci. Eng., B, 2013, 178(1): 1–9.

[4] LIU J, ZHANG X, LI S, et al. Microwave absorption?properties of rod-shaped Co-Ni-P shells prepared by metallizing?Bacillus. Appl. Surf. Sci., 2011, 257(6): 2383–2386.

[5] ZHANG T, HUANG D, YANG Y, et al. Fe3O4/carbon composite nanofiber absorber with enhanced?microwave absorption?performance. Mater. Sci. Eng. B, 2013, 178(1): 1–9.

[6] HAYASHI K, SERIKAWA D, CHIJIMATSU Y, et al. Microwave absorption?of mixed-layer transition metal dichalcogenides. J. Alloys Compd., 1997,?262–263(14): 325–330.

[7] JIA K, ZHAO R, ZHONG J, et al. Preparation and?microwave absorption?properties of loose nanoscale Fe3O4?spheres. J. Magn. Magn. Mater.,?2010, 322(15):?2167–2171.

[8] LI S, CHEN Z, JIN Y, et al. A new approach for preparation of magnetite–graphite composite: Intercalation of polyhydroxy iron cation into graphite oxide in l-arginine medium. Solid State Sci., 2011, 13(5): 862–866.

[9] SZAB? T, SZERI A, D?K?NY I. Composite graphitic nanolayers prepared by self-assembly between finely dispersed graphite oxide and a cationic polymer. Carbon, 2005, 43(1): 87–94.

[10] ZOU YAN-HONG, LIU HONG-BO, YANG LI, et al．The influence of temperature on magnetic and microwave absorption properties of Fe/graphite oxide nanocomposites．J. Magn. Magn. Mater., 2006, 302: 343–347.

[11] CHE R C, PENG L M, DUAN X F, et al. Microwave absorption?enhancement and complex permittivity and permeability of?Fe?encapsulated within carbon nanotubes. Adv. Mater., 2004, 16(5): 401–404.

[12] ZHANG X F, DONG X L, HUANG H, et al. Microwave absorption properties of the carbon-coated nickel nanocapsules. Appl. Phys. Lett., 2006, 89(5): 053115.

[13] ZHANG X F, DONG X L, Huang H, et al. Microstructure and microwave absorption properties of carbon-coated iron nanocapsules. J. Phys. D: Appl. Phys., 2007, 40(17): 5383–5387.

[14] NI S, WANG X, ZHOU G, et al. Designed synthesis of wide range?microwave absorption?Fe3O4–carbon?sphere composite. J. Alloys Compd., 2010,?489(1): 252–256.

[15] ZHENG Z, XU B, HUANG L, et al. Novel composite of Co/carbon?nanotubes: Synthesis, magnetism and?microwave absorption?properties. Solid State Sci., 2008, 10(3): 316–320.

纳米铁钴合金/石墨复合材料的微波吸收性能研究

Research on Microwave Absorption Properties of FeCo/Graphite Nanocomposite

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