高温雷达吸波材料研究现状与展望

doi:10.3724/SP.J.1077.2014.13471

无机材料学报 ›› 2014, Vol. 29 ›› Issue (5): 461-469.DOI: 10.3724/SP.J.1077.2014.13471

高温雷达吸波材料研究现状与展望

丁冬海^1,2, 罗发², 周万城², 史毅敏², 周亮³

(1. 西安建筑科技大学材料与矿资学院, 西安710055; 2. 西北工业大学凝固技术国家重点实验室, 西安710072; 3. 长安大学材料科学与工程学院, 西安710061)

收稿日期:2013-09-17 修回日期:2013-11-08 出版日期:2014-05-20 网络出版日期:2014-04-24
作者简介:丁冬海(1983–), 男, 博士, 讲师. E-mail:dingdongnwpu@qq.com
基金资助:
国家自然科学基金(51302206); 教育部博士点基金(20126120120016); 凝固技术国家重点实验室开放课题(SKLSP201305); 陕西省教育厅科研专项(2013JK0921, 2013JK0922, 2010JK643); “濮耐”教育奖学金青年教师科研基金

Research Status and Outlook of High Temperature Radar Absorbing Materials

DING Dong-Hai^1,2, LUO Fa², ZHOU Wan-Cheng², SHi Yi-Min², ZHOU Liang³

(1. College of Materials and Mineral Resources, Xi’an University of Architecture and Technology, Xi’an 710055, China; 2. State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China; 3. Materials Science and Engineering, Chang'an University, Xi'an 710061, China)

Received:2013-09-17 Revised:2013-11-08 Published:2014-05-20 Online:2014-04-24
About author:DING Dong-Hai. E-mail:dingdongnwpu@qq.com
Supported by:
National Natural Science Foundation of China (51302206); Research Fund for the Doctoral Program of Higher Education of China(20126120120016); State Key Laboratory of Solidification Processing in NWPU (SKLSP201305); Scientific Research Program Funded by Shaanxi Provincial Education Department (2013JK0921, 2013JK0922, 2010JK643); Scientific Research Fund for Young Teachers of Puyang Refractories Education Sducation Scholarship

摘要/Abstract

摘要： “薄、宽、轻、强”已经不能完全满足新型武器装备对雷达吸波材料提出的耐高温、抗氧化、高强度及高韧性等新要求。高温雷达吸波材料受到广泛关注, 本文首先综述了C、ZnO、SiC三类高温吸收剂研究现状, 主要介绍了它们吸波性能改进途径及电磁参数的温度响应机理; 然后对比了涂覆型与结构型高温吸波材料的特点; 在此基础上, 阐述了连续纤维增强陶瓷基复合材料作为高温结构吸波材料的优势、研究现状及存在的问题; 最后, 提出了高温吸波材料未来潜在的发展方向。

关键词: 碳吸收剂, SiC吸收剂, ZnO吸收剂, 高温吸波, 综述

Abstract: Traditional radar adsorbing materials characterized by thin broad, light and strong can not fully satisfy requirements of advanced weapons with heat resistance, anti-oxidation, high strength and fracture toughness. Recently, high temperature radar absorbing materials have attracted much attention. Research progresses of three high temperature absorbers, including C, SiC and ZnO, were reviewed. Then ways to improve their microwave properties and mechanisms of their temperature respond behaviors were introduced. In addition, the coating and structural microwave absorbing materials were compared. On this basis, superiorities, research status and main problems of continuous fibers- reinforced ceramic matrix composites were elaborated. Based on these progresses, potential development directions of high temperature microwave absorbing materials were proposed.

Key words: carbon absorber, SiC absorber, ZnO absorber, high temperature absorbers, review

中图分类号:

TQ174

丁冬海, 罗发, 周万城, 史毅敏, 周亮. 高温雷达吸波材料研究现状与展望[J]. 无机材料学报, 2014, 29(5): 461-469.

DING Dong-Hai, LUO Fa, ZHOU Wan-Cheng, SHi Yi-Min, ZHOU Liang. Research Status and Outlook of High Temperature Radar Absorbing Materials[J]. Journal of Inorganic Materials, 2014, 29(5): 461-469.

参考文献

[1] CHEN XUE-GANG, YE YING, CHENG JI-PENG. Recent progress in electromagnetic wave absorbers. Journal of Inorganic Materials, 2011, 26(5): 449–457.

[2] LIU HAI-TAO, CHENG HAI-FENG, WANG JUN, et al. Review on high-temperature structural radar absorbing materials. Materials Review, 2009, 23(10): 24–27.

[3] XIE WEI, CHENG HAI-FENG, KUANG JIA-CAI. Effect of heating rate on the complex permittivity of hollow-porous carbon fibers. Journal of Inorganic Materials, 2011, 26(9): 939–943.

[4] XIE W, CHENG H F, CHU Z Y, et al. Effect of carbonization temperature on the structure and microwave absorbing properties of hollow carbon fibres. Ceramics International, 2011, 37(6): 1947–1951.

[5] XIE W, CHENG H F, CHU Z Y, et al. Effect of carbonization time on the structure and electromagnetic parameters of porous-hollow carbon fibres. Ceramics International, 2009, 35(7): 2705–2710.

[6] HUANG Z B, ZHOU W C, KANG W B, et al. Dielectric and microwave-absorption properties of the partially carbonized PAN cloth/epoxy–silicone composites. Composites: Part B, 2012, 43(8): 2980–2954.

[7] DU Y C, WANG J Y, CUI C K, et al. Pure carbon microwave absorbers from anion-exchange resin pyrolysis. Synthetic Metals, 2010, 160(19/20): 2191–2196.

[8] SUN LIANG-KUI, CHENG HAI-FENG, CHU ZENG-YONG, et al. Preparation and properties of C/SiO2 coaxial fibers. Journal of Inorganic Materials, 2009, 24(2): 310–314.

[9] YAN JIA, CHU ZENG-YONG, CHENG HAI-FENG, et al. Microwave absorbing property of pre-oxidized PAN fibers carbonized in BCl3. Journal of Inorganic Materials, 2012, 27(8): 813–816.

[10] ZHOU W, XIAO P, LI Y, et al. Dielectric properties of BN modified carbon fibers by dip-coating. Ceramics International, 2013, 39(6): 6569–6576.

[11] ZHOU W, XIAO P, LI Y. Preparation and study on microwave absorbing materials of boron nitride coated pyrolytic carbon particles. Appl. Surf. Sci., 2012, 258(22): 8455–8459.

[12] CAO M S, SONG W L, HOU Z L, et al. The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites. Carbon, 2010, 48(3):788–796

[13] KOU HUAMIN, ZHU YONG, CHEN MINGXIA, et al. Microwave absorbing performance of silica matrix composites reinforced by carbon nanotubes and carbon fiber. Int. J. Appl. Ceram. Technol., 2012, 10(2): 245–250.

[14] WANG X Y, LUO F, YU X M, et al. Influence of short carbon fiber content on mechanical anddielectric properties of Cfiber/Si3N4 composites. Scripta Materialia, 2007, 57(4): 309–312.

[15] LI X M, ZHANG L T, YIN X W. Synthesis, Electromagnetic reflection loss and oxidation resistance of pyrolytic carbon-Si3N4 ceramics with dense Si3N4. J. Eur. Ceram. Soc. 2012, 32(8): 1485–1489

[16] FENG G Y, FANG X Y, WANG J J, et al. Effect of heavily doping with boron on electronic structures and optical properties of β-SiC. Physica B, 2010, 405(12): 2625–2631.

[17] LIU H S, FANG X Y, SONG W L, et al. Modification of band gap of β-SiC by N-doping. Chinese Physics Letters, 2009, 26(6): 067101.

[18] LI ZHI-MIN, SHI JIAN-ZHANG, WEI XIAO-HEI, et al. First principles calculation of electronic structure for Al-doped 3C-SiC and its microwave dielectric properties. Acta Phys. Sin., 2012, 61(23): 237103.

[19] DOU Y K, JIN H B, CAO M S, et al. Structural stability, electronic and optical properties of Ni-doped 3C–SiC by first principles calculation. Journal of Alloys and Componds, 2011, 509(20): 6117–6122.

[20] LI ZHI-MIN, DU HONG-LIANG, LUO FA, et al. Study process of silicon carbide as high temperature microwave absorber. Rare Metal Material and Engineering, 2007, 36(Suppl.3): 96–99.

[21] SU X L, ZHOU W C, WANG J B. Preparation and dielectric property of Al and N Co-doped SiC powder by combustion synthesis. Journal of the American Ceramic Society, 2012, 95(4):1388–1393.

[22] SU X L, ZHOU W C, XU J, et al. Preparation and dielectric property of B and N-codoped SiC powder by combustion synthesis. Journal of Alloys and Compounds, 2013, 551(25): 343–347.

[23] BUNSELL A R, PIANT A. A review of the development of the three generations of small diameter silicon carbide fibres. Journal of Materials Science, 2006, 41(3): 823–839.

[24] DING D H, ZHOU W C, ZHANG B, et al. Complex permittivity and microwave absorbing properties of SiC fiber woven fabrics. Journal of Materials Science, 2011, 46(8): 2709–2714.

[25] WANG D Y, SONG Y C, LI Y Q. Effect of composition and structure on specific resistivity of SiC fibers. Transactions of Nonferrous Metals Society of China, 2012, 22(5): 1133–1139.

[26] HU T J, LI X D, LI G Y, et al. Axial graded carbon fiber and silicon carbide fiber with sinusoidal electrical resistivity. Journal of the American Ceramic Society, 2011, 94(9): 2808–2811.

[27] DING DONG-HAI, ZHOU WAN-CHENG, ZHOU XUAN, et al. Structure and microwave absorbing property of polycarbosilane derived silicon carbide ceramic. Chinese Journal of Inorganic Chemistry, 2012, 28(5): 922–926.

[28] LI Q, YIN X W, DUAN W Y, et al. Electrical, dielectric and microwave-absorption properties of polymer derived SiC ceramics in X band. Journal of Alloys and Compounds, 2013, 565(15): 66–72.

[29] 王军. 含过渡金属的碳化硅纤维的制备及其电磁性能. 长沙: 国防科学技术大学博士论文, 1997.

[30] CHEN ZHI-YAN, WANG JUN, LI XIAO-DONG, et al. Preparation of continuous Fe containing carbide silicon fibers and their structural radar-wave absorbing materials. Acta Materiae Compositae Sinica, 2007, 24(5): 72–76.

[31] CHEN X J, SU Z M, ZHANG L, et al. Iron nanoparticle- containing silicon carbide fibers prepared by pyrolysis of Fe(CO)5-doped polycarbosilane fibers. Journal of the American Ceramic Society, 2010, 93(1): 89–95.

[32] 刘旭光. 异形截面碳化硅纤维制备及其吸波性能. 长沙: 国防科学技术大学博士学位论文, 2010.

[33] HUANG Yun-Xia, CAO Quan-Xi, LI Zhi-Min, et al. First-principles calculation of microwave dielectric properties of Al-doping ZnO powders. Acta Physical Sinica, 2009, 58(11): 8002–8007.

[34] WANG Y, LUO F, ZHANG L, et al. Microwave dielectric properties of Al-doped ZnO powders synthesized by coprecipitation method. Ceramics International, 2013, 39(8): 8723–8727.

[35] KONG L, YIN X W, ZHANG L T, et al. Effect of aluminum doping on microwave absorption properties of ZnO/ZrSiO4 composite ceramics. Journal of the American Ceramic Society, 2012, 95(10): 3158–3165.

[36] KONG L, YIN X W, LI Q, et al. High-temperature electromagnetic wave absorption properties of ZnO/ZrSiO4 composite ceramics. Journal of the American Ceramic Society, 2013, 96(7): 2211–2217.

[37] 刘汉东. 四针状氧化锌晶须的掺杂及其性能研究. 国防科学技术大学硕士学位论文, 2008, 长沙.

[38] CHEN Y J, CAO M S, WANG T H, et al. Microwave absorption properties of the ZnO nanowire-polyester composites. Applied Physics Letters, 2004, 84(17): 3367–3369.

[39] ZHOU Z W, CHU L S, HU S C. Microwave absorption behaviors of tetra-needle-like ZnO whiskers. Materials Science and Engineering B, 2006, 126: 93-96.

[40] LI H F, HUANG Y H, SUN G B, et al. Directed growth and microwave absorption property of crossed ZnO netlike micro-nanostructures. The Journal of Physical Chemistry C, 2010, 114(22): 10088–10091.

[41] ZHUO R F, QIAO L, FENG H T, et al. Microwave absorption properties and the isotropic antenna mechanism of ZnO nanotrees. Journal of Applied Physics, 2008, 104(9): 094101–1–5.

[42] CAO M S, SHI X L, FANG X Y, et al. Microwave absorption properties and mechanism of cagelike ZnO/SiO2 nanocomposites. Applied Physics Letters, 2007, 91(20): 203110–1–3.

[43] FANG X Y, SHI X L, CAO M S, et al. Micro-current attenuation modeling and numerical simulation for cage-like ZnO/SiO2 nanocomposite. Journal of Applied Physics, 2008, 104(9): 096101–1–3.

[44] FANG X Y, CAO M S, SHI X L, et al. Microwave responses and general model of nanotetraneedle ZnO: Integration of interface scattering, microcurrent, dielectric relaxation, and microantenna. Journal of Applied Physics, 2010, 107(5): 054304–1–11.

[45] ZHUO R F, FENG H T, CHEN J T, et al. Multistep synthesis, growth mechanism, optical, and microwave absorption properties of ZnO dendritic nanostructures. The Journal of Physical Chemistry C, 2008, 112(31): 11767–11775.

[46] YANG H J, YUAN J, LI Y, et al. Silicon carbide powders: Temperature-dependent dielectric properties and enhanced microwave absorption at gigahertz range. Solid State Communications, 2013, 163: 1–6.

[47] YUAN J, YANG H J, HOU Z L, et al. Ni-decorated SiC powders: Enhanced high-temperature dielectric properties and microwave absorption performance. Powder Technology, 2013, 237: 309–313.

[48] LIU H T, TIAN H, CHENG H F. Dielectric properties of SiC fiber- reinforced SiC matrix composites in the temperature range from 25 to 700℃ at frequency between 8.2 and 18 GHz. Journal of Nuclear Materials, 2013, 432(1/3): 57–60.

[49] YUAN J, SONG W L, FANG X Y, et al. Tetra-needle zinc oxide/ silica composites: High-temperature dielectric properties at X-band. Solid State Communications, 2013, 154: 64–68.

[50] QING Y C, ZHOU W C, LUO F, et al. Epoxy-silicone filled with multi-walled carbon nanotubes and carbonyl iron particles as a microwave absorber. Carbon, 2010, 48(14): 4074–4080.

[51] HUA SHAO-CHUN, WANG HAN-GONG, WANG LIU-YING, et al. Absorption properties of micro-plasma sprayed carbon nanotube-nano structure Al2O3-TiO2 composite coatings. Acta Physical Sinica, 2009, 58(9): 6534–6541.

[52] ZHOU L, ZHOU W C, SU J B, et al. Plasma sprayed Al2O3/FeCrAl composite coatings for electromagnetic wave absorption application. Applied Surface Science, 2012, 258(7): 2691–2696.

[53] 刘海韬. 夹层结构SiCf/SiC雷达吸波材料设计、制备及性能研究. 长沙: 国防科学技术大学博士学位论文, 2010.

[54] HUANG Z B, KANG W B, QING Y C, et al. Influences of SiCf content and length on the strength, toughness and dielectric properties of SiCf/LAS glass-ceramic composites. Ceramics International, 2013, 39(3): 3135–3140.

[55] LI X M, ZHANG L T, YIN X W. Effect of chemical vapor infiltration of Si3N4 on the mechanical and dielectric properties of porous Si3N4 ceramic fabricated by a technique combining 3-D printing and pressureless sintering. Scripta Materiala, 2012, 67: 380–383.

[56] YU X M, ZHOU W C, LUO F, et al. Effect of fabrication atmosphere on the dielectric properties of SiC/SiC composites. Journal of Alloys and Compounds, 2009, 479(1/2): L1–L3.

[57] DING D H, SHI Y M, WU Z H, et al. Electromagnetic interference shielding and dielectric properties of SiCf/SiC composites containing pyrolytic carbon interphase. Carbon, 2013, 60(538/561): 552–555.

[58] 丁冬海. SiCf/SiC耐高温结构吸波材料性能研究. 西安: 西北工业大学博士学位论文, 2012.

[59] DING D H, ZHOU W C, LUO F, et al. Mechanical properties and oxidation resistance of SiCf/CVI-SiC composites with PIP-SIC interphase. Materials Science and Engineering A, 2012, 543(1): 1–5.

[60] LIU H T, CHENG H F, WANG J, et al. Dielectric properties of the SiC fiber-reinforced SiC matrix composites with the CVD SiC interphases. Journal of Alloys and Compounds, 2010, 491(1/2): 248–251.

[61] LIU H T, TIAN H. Mechanical and microwave dielectric properties of SiCf/SiC composites with BN interphase prepared by dip-coating process. Journal of European Ceramic Society, 2012, 32(10): 2502–2512.

高温雷达吸波材料研究现状与展望

Research Status and Outlook of High Temperature Radar Absorbing Materials

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	丁玲, 蒋瑞, 唐子龙, 杨运琼. MXene材料的纳米工程及其作为超级电容器电极材料的研究进展[J]. 无机材料学报, 2023, 38(6): 619-633.
[2]	杨卓, 卢勇, 赵庆, 陈军. X射线衍射Rietveld精修及其在锂离子电池正极材料中的应用[J]. 无机材料学报, 2023, 38(6): 589-605.
[3]	陈强, 白书欣, 叶益聪. 热管理用高导热碳化硅陶瓷基复合材料研究进展[J]. 无机材料学报, 2023, 38(6): 634-646.
[4]	林俊良, 王占杰. 铁电超晶格的研究进展[J]. 无机材料学报, 2023, 38(6): 606-618.
[5]	牛嘉雪, 孙思, 柳鹏飞, 张晓东, 穆晓宇. 铜基纳米酶的特性及其生物医学应用[J]. 无机材料学报, 2023, 38(5): 489-502.
[6]	苑景坤, 熊书锋, 陈张伟. 聚合物前驱体转化陶瓷增材制造技术研究趋势与挑战[J]. 无机材料学报, 2023, 38(5): 477-488.
[7]	杜剑宇, 葛琛. 光电人工突触研究进展[J]. 无机材料学报, 2023, 38(4): 378-386.
[8]	杨洋, 崔航源, 祝影, 万昌锦, 万青. 柔性神经形态晶体管研究进展[J]. 无机材料学报, 2023, 38(4): 367-377.
[9]	游钧淇, 李策, 杨栋梁, 孙林锋. 氧化物双介质层忆阻器的设计及应用[J]. 无机材料学报, 2023, 38(4): 387-398.
[10]	林思琪, 李艾燃, 付晨光, 李荣斌, 金敏. Zintl相Mg₃X₂(X=Sb, Bi)基晶体生长及热电性能研究进展[J]. 无机材料学报, 2023, 38(3): 270-279.
[11]	陈昆峰, 胡乾宇, 刘锋, 薛冬峰. 多尺度晶体材料的原位表征技术与计算模拟研究进展[J]. 无机材料学报, 2023, 38(3): 256-269.
[12]	张超逸, 唐慧丽, 李宪珂, 王庆国, 罗平, 吴锋, 张晨波, 薛艳艳, 徐军, 韩建峰, 逯占文. 新型GaN与ZnO衬底ScAlMgO₄晶体的研究进展[J]. 无机材料学报, 2023, 38(3): 228-242.
[13]	齐占国, 刘磊, 王守志, 王国栋, 俞娇仙, 王忠新, 段秀兰, 徐现刚, 张雷. GaN单晶的HVPE生长与掺杂进展[J]. 无机材料学报, 2023, 38(3): 243-255.
[14]	谢兵, 蔡金峡, 王铜铜, 刘智勇, 姜胜林, 张海波. 高储能密度聚合物基多层复合电介质的研究进展[J]. 无机材料学报, 2023, 38(2): 137-147.
[15]	刘岩, 张珂颖, 李天宇, 周菠, 刘学建, 黄政仁. 陶瓷材料电场辅助连接技术研究现状及发展趋势[J]. 无机材料学报, 2023, 38(2): 113-124.