TiO2/SnO2纳米晶膜的制备及其电学性能研究

doi:10.3724/SP.J.1077.2013.13104

无机材料学报 ›› 2013, Vol. 28 ›› Issue (11): 1233-1236.DOI: 10.3724/SP.J.1077.2013.13104

TiO₂/SnO₂纳米晶膜的制备及其电学性能研究

崔旭梅^{1, 2}, 左承阳², 蓝德均², 王军²

(1. 电子科技大学电子薄膜与集成器件国家重点实验室, 成都 610054; 2. 攀枝花学院钒钛资源综合利用四川省重点实验室, 攀枝花 617000)

收稿日期:2013-03-01 修回日期:2013-04-26 出版日期:2013-11-20 网络出版日期:2013-10-18
基金资助:
国家博士后基金(2011M501294); 教育部新世纪优秀人才支持计划(NECT-10-0946); 四川省科技创新研究团队建设项目(2011JTD0039)

Preparation and Electrical Properties of TiO₂/SnO₂ Nanocrystalline Films

CUI Xu-Mei^1,2, ZUO Cheng-Yang², LAN De-Jun², WANG Jun²

(1. State Key Lab of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China; 2. Sichuan Key Lab of Comprehensive Utilization of Vanadium and Titanium Resources, Panzhihua University, Panzhihua 617000, China)

Received:2013-03-01 Revised:2013-04-26 Published:2013-11-20 Online:2013-10-18
Supported by:
China Postdoctoral Science Foundation(2011M501294); Program for New Century Excellent Talents in Univesity(NECT-10-0946); Science and Technology Innovation Research Team Construction Project of Sichuan Province(2011JTD0039)

摘要/Abstract

摘要： 采用丝网印刷的方式制备了TiO₂纳米晶薄膜, 然后在其上采用浸泡的方式制备了SnO₂纳米晶薄膜, 形成TiO₂/SnO₂膜结构的光阳极并应用于染料敏化太阳能电池。用SEM对样品进行了结构形貌分析, 用电化学工作站研究表征了SnO₂的浸泡溶液浓度和浸泡时间对光阳极的调制改性作用。SEM分析表明在TiO₂纳米晶薄膜表面生长的SnO₂纳米晶薄膜晶粒比TiO₂更加细小, 电学性能研究表明TiO₂薄膜经过0.4 mol/L SnO₂溶液浸泡处理50 min能对TiO₂薄膜的结构及性能起到很好的改善作用, 电池的光电转化效率提高了约7%。

关键词: 染料敏化太阳能电池, TiO₂光阳极, SnO₂, J-V曲线, 转化效率

Abstract: The effect of SnO₂ nanocrystalline coatings on the performance of dye-sensitized solar cells (DSSC) based on TiO₂-nanoparticle photoanode was studied. The TiO₂-nanoparticle photoanode was prepared by screen-printing technique, and the SnO₂ nanocrystalline films were coated on TiO₂ nanoparticles by soaking TiO₂ photoanodes in SnO₂ solution with different concentrations or different time. SEM images indicate SnO₂ nanocrystalline films have smaller surface grains than the TiO₂ nanocrystalline films. The electrical properties of the films indicate that SnO₂ thin films growing on the TiO₂ films by soaking TiO₂ films in 0.4 mol /L SnO₂ solution for 50 min play a positive role on the structure and performance of the TiO₂ films, and the conversion efficiency of the solar cell with TiO₂/SnO₂ photoanode is about 7% higher than that of TiO₂ films.

Key words: dye-sensitized solar cell, TiO₂ photoanode, SnO₂, J-V curve, conversion efficiency

中图分类号:

TU502

崔旭梅, 左承阳, 蓝德均, 王军. TiO₂/SnO₂纳米晶膜的制备及其电学性能研究[J]. 无机材料学报, 2013, 28(11): 1233-1236.

CUI Xu-Mei, ZUO Cheng-Yang, LAN De-Jun, WANG Jun. Preparation and Electrical Properties of TiO₂/SnO₂ Nanocrystalline Films[J]. Journal of Inorganic Materials, 2013, 28(11): 1233-1236.

参考文献

[1] O' regan Brian, Gratzel Michael. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353: 737-740.

[2] Hod Idan, Shalom Menny, Tachan Zion, et al. SrTiO3 recombination- inhibiting barrier layer for type II dye-sensitized solar cells. J. Phys. Chem. C, 2010, 114(21): 10015-10018.

[3] TAO Yong, LIAO Zi-jun, WU Deng-xue, et al. Fabrication and in vestigation of blocking layer in dye-sensitized solar cell. Journal of Functional Materials, 2011,42(7):1177-1179.

[4] Nguyen The-Vinh, Lee Hyun-Cheol, Yang O-Bong. The effect of pre-thermal treatment of TiO2 nano-particles on the performances of dye-sensitized solar cells. Solar Energy Materials & Solar Cells, 2006, 90(7/8): 967–981.

[5] Alivov Yahya, Fan Z Y. Efficiency of dye sensitized solar cells based on TiO2 nanotubes filled with nanoparticles. Applied Physics Letters, 2009, 95(6): 063504-063506.

[6] Nemec H, Rochford J, Taratula O. Influence of the electron-cation interaction on electron mobility in dye-sensitized ZnO and TiO2 nanocrystals: a study using ultrafast terahertz spectroscopy. Physcial Review Letters, 2010, 104(19):197401-197404.

[7] Mane R S, Lee W J, Pathan H M. Fabrication and application to dye-densitized solar cells. J.?Phys.?Chem.?B,?2005,?109(51): 24254- 24259.

[8] Lee Tao-Hua, Sun Dazhi, Zhang Xi. Solid-state dye-sensitized solar cell based on semiconducting nanomaterials. J. Vac. Sci. Technol. B, 2009, 27(6): 3073-3076.

[9] Vinodgopal K, Bedja I, Kamat P V. Photoelectrochemical behavior of SnO2/TiO2 composite systems and its role in photocatalytic deradation of a textile azo dye. Chem. Mater., 1996, 8(8): 2180-2187.

[10] Kamat P V, Bedja I, Hotchandani S. Modulation of electron transfer between excited ruthenium complex and SnO2 nanocrystallites with an externally applied bias. Phys. Chem., 1996, 100(12): 4900-4908.

[11] QIAN Jiangfeng, CAO Yuliang, AI Xinping, et al. TiO2-coated Multilayered SnO2 Hollow Microspheres for Dye-Sensitized Solar Cells. The Proceeding of Fifteenth National Electrochemical Symposium, the Fifteenth National Academic Meeting ElectroChemical, Changchun, China, 2009: 36-37.

[12] CUI Xu-mei, ZUO Cheng-yang, LAN De-jun, et al. Study on the modulation of TiO2 photoanode of dye-sensitized solar cell by ZnO. Journal of Functional Materials, 2012, 43(11): 1386-1388.

[13] ZUO Cheng-yang, CUI Xu-mei, LAN De-jun. Study on the dye absorption property of TiO2 photoanode of dye-sensitized cell. Electronic Components and Materials, 2011, 30(12): 21-23.

[14] ZHENG Wei, CUI Sai, ZHANG Xiao-Na, et al. Nanocrystalline MgO/TiO2 core-shell film for dye-sensitized solar cell. Journal of Harbin University of Science and Technology, 2012,17(5): 5-9.

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TiO₂/SnO₂纳米晶膜的制备及其电学性能研究

Preparation and Electrical Properties of TiO₂/SnO₂ Nanocrystalline Films

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