滤纸为模板制备中空SnO2纳米管锂离子电池负极材料

doi:10.3724/SP.J.1077.2013.13124

无机材料学报 ›› 2013, Vol. 28 ›› Issue (11): 1213-1216.DOI: 10.3724/SP.J.1077.2013.13124

滤纸为模板制备中空SnO₂纳米管锂离子电池负极材料

毛瑞¹, 郭洪^{1, 2}, 田冬雪¹, 杨项军¹, 王世雄¹, 陈景¹

(1. 云南大学化学科学与工程学院, 昆明 650091; 2. 曲靖师范学院化学科学与工程学院, 曲靖 655000)

收稿日期:2013-03-06 修回日期:2013-04-26 出版日期:2013-11-20 网络出版日期:2013-10-18
作者简介:毛瑞(1987-), 女, 硕士研究生. E-mail:maorui33@126.com
基金资助:
国家自然科学基金(U0937601); 教育部国家重点项目(210204); 国家重点基础研究发展规划 (863计划) (2011AA03A405)

Hollow Nanotubular SnO₂ Templated by Cellulose Fibers for Lithium Ion Batteries

MAO Rui¹, GUO Hong^{1, 2}, TIAN Dong-Xue¹, YANG Xiang-Jun¹, WANG Shi-Xiong¹, CHEN Jing¹

(1. School of Chemistry Science and Engineering, Yunnan University, Kunming 650091, China; 2. School of Chemistry and Chemical Engineering, Qujing Normal University, Qujing 655000, China)

Received:2013-03-06 Revised:2013-04-26 Published:2013-11-20 Online:2013-10-18
About author:MAO Rui. E-mail:maorui33@126.com
Supported by:
National Natural Science Foundation of China (U0937601); Financial support provided by Department Science Foundation of China (210204); 863 Program of National High Technology Research Development Project of China (2011AA03A405)

摘要/Abstract

摘要： 以植物纤维素(滤纸)为模板, 制备了中空SnO₂纳米管作为锂离子电池负极材料。通过XRD、SEM、TEM和HR?TEM表征产物的组分、形貌和结构, 表明合成材料是由粒度大小为5~15 nm SnO₂粒子组装成的中空纳米管。同时, N₂吸附/脱附测试表明此材料为疏松的介孔结构。材料在电流密度100 mA/g 时, 可逆容量稳定在580 mAh/g, 60次循环后容量仍保持为550 mAh/g。制备的中空SnO₂纳米管作为锂离子电池负极材料, 具有较高的放电容量和良好的电化学循环性能。

关键词: SnO₂, 纳米管, 纤维素, 锂离子电池

Abstract: An effective method of using cellulosic substances (filter paper) as template was employed to prepare SnO₂ nanotubular materials examined as anode for Li-ion battery. According to XRD, SEM, TEM and HR-TEM analysis, the synthesized nanotubular materials retained morphological hierarchy of the filter paper, and each nanotube was composed of nano-sized SnO₂ ranged from 5 nm to 15 nm. At the same time, the N₂ adsorption/desorption tests show that the materials are mesoporous structure. It exhibits a stable reversible capacity of 580 mAh/g at constant current density of 100 mA/g, and the reversible capacity remains at 550 mAh/g after 60 cycles, showing a high reversible capacity and stable cycle performance as anode for Li-ion battery.

Key words: tin oxide, nanotube, natural cellulose, Li-ion batteries

中图分类号:

O611

毛瑞, 郭洪, 田冬雪, 杨项军, 王世雄, 陈景. 滤纸为模板制备中空SnO₂纳米管锂离子电池负极材料[J]. 无机材料学报, 2013, 28(11): 1213-1216.

MAO Rui, GUO Hong, TIAN Dong-Xue, YANG Xiang-Jun, WANG Shi-Xiong, CHEN Jing. Hollow Nanotubular SnO₂ Templated by Cellulose Fibers for Lithium Ion Batteries[J]. Journal of Inorganic Materials, 2013, 28(11): 1213-1216.

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滤纸为模板制备中空SnO₂纳米管锂离子电池负极材料

Hollow Nanotubular SnO₂ Templated by Cellulose Fibers for Lithium Ion Batteries

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