硫化亚锡敏化纳晶TiO2膜的制备及光电性能研究

doi:10.3724/SP.J.1077.2013.12757

无机材料学报 ›› 2013, Vol. 28 ›› Issue (10): 1093-1097.DOI: 10.3724/SP.J.1077.2013.12757

硫化亚锡敏化纳晶TiO₂膜的制备及光电性能研究

张晓萍, 兰章, 陈琳, 高素雯, 吴晚霞, 阙兰芳, 张晓佩

(华侨大学材料科学与工程学院, 环境友好功能材料教育部工程中心, 厦门361021)

收稿日期:2012-12-15 修回日期:2013-02-23 出版日期:2013-10-20 网络出版日期:2013-09-18
作者简介:张晓萍(1986-), 女, 硕士研究生. E-mail: z15152785330@126.com
基金资助:
国家自然科学基金(51002053); 教育部科技重点项目(212206)

Preparation and Photovoltaic Performance of SnS Sensitized Nanocrystallite TiO₂ Photoanode

ZHANG Xiao-Ping, LAN Zhang, CHEN Lin, GAO Su-Wen, WU Wan-Xia, QUE Lan-Fang, ZHANG Xiao-Pei

(Engineering Research Center of Environment-friendly Functional Materials, Ministry of Education, Institute of Material physical Chemistry, Huaqiao University, Xiamen 361021, China)

Received:2012-12-15 Revised:2013-02-23 Published:2013-10-20 Online:2013-09-18
About author:ZHANG Xiao-Ping. E-mail: z15152785330@126.com
Supported by:
National Natural Science Foundation of China (51002053); Key Project of the Chinese Ministry of Education (212206)

摘要/Abstract

摘要： 采用简单的离子交换沉积法制备了SnS敏化的纳晶TiO₂光阳极。通过SEM、XRD、UV-Vis等手段对光阳极的表面形貌, 晶态结构, 紫外-可见吸收和散射性能进行表征。并分别以聚苯胺和铂为催化剂制备对电极, 以含碘氧化还原电对和硫氧化还原电对溶液为电解质, 组装SnS敏化太阳能电池, 对其光电性能进行研究。通过比较不同光阳极、电解质和对电极的组合, 发现用光阳极为离子交换沉积9次SnS的纳晶TiO₂膜, 对电极为聚苯胺不锈钢网压片膜, 电解质为含硫氧化还原电对溶液组装的太阳能电池光电性能最佳, 其短路电流、开路电压、填充因子和光电转换效率分别达到4.59 mA/cm²、0.547 V、0.505和1.27%。

关键词: 硫化亚锡敏化太阳能电池, 离子交换沉积, 聚苯胺, 光电性能

Abstract: A simple method of successive ionic layer adsorption and reaction (SILAR) was employed to prepare SnS sensitized nanocrystallite TiO₂ photoanodes. The characteristics of these photoanodes, such as surface morphology, crystal structure, UV-Vis adsorption and diffusion properties, were measured with XRD, TEM, UV-Vis adsorption and diffusion spectra, respectively. The photovoltaic performances of SnS sensitized solar cells with these photoanodes were measured. The effects of counter electrodes with polyaniline or platinum catalyst and liquid electrolytes with iodine or sulfur redox couple on the photovoltaic performance were also studied. The cells assembled with these different components showed different photovoltaic performance. It was found that the cell assembled with the photoanode fabricated by 9 times of SILAR circulation, the counter electrode with polyaniline-stainless steel net, and the liquid electrolyte containing sulfur redox couple showed the highest photovoltaic performance. The short-circuit current density, open-circuit voltage, fill factor, and power conversion efficiency could reach 4.59 mA/cm², 0.547 V, 0.505 and 1.27%, respectively.

Key words: SnS sensitized solar cell, SILAR, polyaniline, photovoltaic performance

中图分类号:

O646

张晓萍, 兰章, 陈琳, 高素雯, 吴晚霞, 阙兰芳, 张晓佩. 硫化亚锡敏化纳晶TiO₂膜的制备及光电性能研究[J]. 无机材料学报, 2013, 28(10): 1093-1097.

ZHANG Xiao-Ping, LAN Zhang, CHEN Lin, GAO Su-Wen, WU Wan-Xia, QUE Lan-Fang, ZHANG Xiao-Pei. Preparation and Photovoltaic Performance of SnS Sensitized Nanocrystallite TiO₂ Photoanode[J]. Journal of Inorganic Materials, 2013, 28(10): 1093-1097.

参考文献

[1] Dittrich T, Belaidi A, Ennaoui A, et al. Concepts of inorganic solid-state nanostructured solar cells. Sol. Energy Mater. Sol. Cells, 2011, 95(6): 1527–1536.

[2] ZHOU Feng-Ling, LI Xiao-Min, GAO Xiang-Dong, et al. Low cost preparation and photoelectric property study of PbSe nanocrystalline films. Journal of Inorganic Materials, 2009, 24(4): 778–782.

[3] Guang Z, Tao X, Tian L, et al. Graphene-incorporated nanocrystalline TiO2 films for CdS quantum dot-sensitized solar cells. J. Electroanal. Chem., 2011, 650(2): 248–251.

[4] Lee H J, Wang M K, Chen P. Efficient CdSe quantum dot-sensitized solar cells prepared by an improved successive ionic layer adsorption and reaction process. Nano Lett., 2009, 9(12): 4221– 4227.

[5] Hyun B R, Bartnik A C, Lee J K, et al. Role of solvent dielectric properties on charge transfer from PbS nanocrystals to molecules. Nano Lett., 2010, 10(1): 318–323.

[6] Choi J J, Lim Y F, Santiago-Berrios M E B, et al. PbSe nanocrystal excitonic solar cells. Nano Lett., 2009, 9(11): 3749–3755.

[7] Messina S, Nair M T S, Nair P K. Solar cells with Sb2S3 absorber films. Thin Solid Films, 2009, 517(7): 2503–2507.

[8] Robert W, Ogah E. Thermally evaporated thin films of SnS for application in solar cell devices. Thin Solid Film，2009，517(7)：4702–4705.

[9] Vequizo J J M, Ichimura M. Fabrication of electrodeposited SnS/ SnO2 heterojunction solar cells. J. Appl. Phys., 2012, 51(10): 381–384.

[10] Bashkirov S A, Gremenok V F, Ivanov V A, et al. Tin sulfide thin films and Mo/p-SnS/n-CdS/ZnO heterojunctions for photovoltaic applications. Thin Solid Films, 2012, 520(17): 5807–5810.

[11] Guo W, Shen Y H, Wu M X, et al. Highly efficient inorganic- organic heterojuction solar cells based on SnS-sensitized spherical TiO2 electrodes. Chem. Commun., 2012, 48: 6133–6135.

[12] Guo W, Shen Y H, Wu M X, et al. SnS-quantum dot solar cells using novel TiC counter electrode and organic redox couples. Chem. Eur. J., 2012, 18(25): 7862–7868.

[13] Santra P K, Kamat P V. Mn-doped quantum dot sensitized solar cells: a strategy to boost efficiency over 5%. J. Am. Chem. Soc., 2012, 134(5): 2508–2511.

[14] Tsukigase H, Suzuki Y, Berger M H. Synthesis of SnS nanoparticles by SILAR method for quantum dot-sensitized solar cells. J. Nanosci. Nanotech., 2011, 11(3): 1914–1922.

[15] Murakami T, Gr?tzel M. Counter electrodes for DSC: application of functional materials as catalysts. Inorganica Chimica Acta, 2008, 361(3): 572–580.

[16] Deepa K G, Nagaraju J. Growth and photovoltaic performance of SnS quantum dots. Mater. Sci. Eng. B, 2012, 177(13): 1023-1028.

[17] Kamat P V. Boosting the efficiency of quantum dot sensitized solar cells through modulation of interfacial charge transfer. Acc. Chem. Res., 2012, 45 (11): 1906–1915.

[18] Shalom M, Buhbut S, Tirosh S, et al. Design rules for high-efficiency quantum-dot–sensitized solar cells: a multilayer approach. J. Phys. Chem. Lett. 2012, 3(17): 2436–2441.

[19] Yang H, Fan W, Vaneski A, et al. Heterojunction engineering of CdTe and CdSe quantum dots on TiO2 nanotube arrays: intricate effects of size-dependency and interfacial contact on photoconversion efficiencies. Adv. Funct. Mater., 2012, 22(13): 2821–2829.

[20] Chang C H, Lee Y L. Efficient polysulfide electrolyte for CdS quantum dot-sensitized solar cells. J. Power Sources, 2008, 185(1): 584–588.

[21] Tsao H N, Burschka J, Yi C, et al. Influence of the interfacial charge transfer resistance at the counter electrode in dye-sensitized solar cells employing cobalt redox shuttles. Energy Environ. Sci. 2011, 4: 4921–4924.

硫化亚锡敏化纳晶TiO₂膜的制备及光电性能研究

Preparation and Photovoltaic Performance of SnS Sensitized Nanocrystallite TiO₂ Photoanode

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