ZrB2-SiC超高温陶瓷涂层的抗烧蚀性能研究

doi:10.3724/SP.J.1077.2013.12208

无机材料学报 ›› 2013, Vol. 28 ›› Issue (3): 256-260.DOI: 10.3724/SP.J.1077.2013.12208

ZrB₂-SiC超高温陶瓷涂层的抗烧蚀性能研究

周海军^1,2,3, 张翔宇^2,3, 高乐^2,3, 胡建宝^2,4, 吴斌^2,4, 董绍明^2,3

(1. 中国科学院特种无机涂层重点实验室, 上海 200050; 2. 中国科学院上海硅酸盐研究所结构陶瓷与复合材料工程研究中心, 上海 200050; 3. 中国科学院高性能陶瓷和超微结构国家重点实验室, 上海 200050; 4. 中国科学院大学, 北京 100049)

收稿日期:2012-04-05 修回日期:2012-07-11 出版日期:2013-03-20 网络出版日期:2013-02-20
基金资助:
中国科学院特种无机涂层重点实验室开放基金(KLICM-2011-08)

Ablation Properties of ZrB₂-SiC Ultra-high Temperature Ceramic Coatings

ZHOU Hai-Jun^1,2,3, ZHANG Xiang-Yu^2,3, GAO Le^2,3, HU Jian-Bao^2,4, WU Bin^2,4, DONG Shao-Ming^2,3

(1. The Key Laboratory of Inorganic Coating Materials, Chinese Academy of Sciences, Shanghai 200050, China; 2. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; 3. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; 4. Graduate University of Chinese Academy of Sciences, Beijing 100049, China)

Received:2012-04-05 Revised:2012-07-11 Published:2013-03-20 Online:2013-02-20
Supported by:
Key Laboratory of Inorganic coating materials, Chinese Academy of Sciences (KLICM-2011-08)

摘要/Abstract

摘要： 为了提高C/C复合材料的抗氧化烧蚀性能, 采用浆料浸涂与原位反应复合工艺在材料表面制备了ZrB₂-SiC超高温陶瓷涂层, 利用氧-丙烷火焰测试了涂层的抗烧蚀性能。结果表明: 采用复合工艺所制备的ZrB₂-SiC超高温陶瓷涂层与基材具有较高的结合强度; 在氧-丙烷火焰冲刷条件下, 涂层具有良好的抗烧蚀性能, 涂层经1500℃下烧蚀600 s, ZrB₂-SiC涂层无明显烧蚀, C/C复合材料保持完好。微观结构观察表明: 烧蚀测试后, 涂层中存在ZrO₂和大量超高温陶瓷相, 涂层抗烧蚀形式主要表现为热化学烧蚀和机械剥蚀。

关键词: C/C复合材料, 超高温陶瓷涂层, 烧蚀性能

Abstract: To improve the anti-ablation properties, the ZrB₂-SiC ultra-high ceramic coatings were successfully fabricated on the C/C composites surface by slurry dipping and liquid silicon infiltration process. Their ablation resistances properties were determined by using an equipment of oxygen-propane torch test. The results show that the bonding strength between the coating and C/C matrix is relatively high due to the formation of reactive SiC layer. The ZrB₂-SiC coating has a well protection from oxygen-propane fire ablation at 1500℃ for 600 s. The whole coating keep integrity avoiding the C/C matrix from oxidation and ablation during the test. The microstructure indicates that ZrB₂-SiC coating has some ZrO₂ phase and ultra-high temperature ceramics phase after the test, which proves that the coating also has much longer life for the protection of C/C composites at high temperature airflow erosion environment. The anti-ablation forms of the ZrB₂-SiC coating are mainly thermo chemistry corrosion and mechanical erosion.

Key words: C/C composites, ultra-high temperature ceramic coatings, ablation properties

中图分类号:

TB332

周海军, 张翔宇, 高乐, 胡建宝, 吴斌, 董绍明. ZrB₂-SiC超高温陶瓷涂层的抗烧蚀性能研究[J]. 无机材料学报, 2013, 28(3): 256-260.

ZHOU Hai-Jun, ZHANG Xiang-Yu, GAO Le, HU Jian-Bao, WU Bin, DONG Shao-Ming. Ablation Properties of ZrB₂-SiC Ultra-high Temperature Ceramic Coatings[J]. Journal of Inorganic Materials, 2013, 28(3): 256-260.

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ZrB₂-SiC超高温陶瓷涂层的抗烧蚀性能研究

Ablation Properties of ZrB₂-SiC Ultra-high Temperature Ceramic Coatings

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