微乳液水热法制备钨酸铋光催化剂及性能研究

doi:10.3724/SP.J.1077.2012.11658

无机材料学报 ›› 2012, Vol. 27 ›› Issue (9): 945-950.DOI: 10.3724/SP.J.1077.2012.11658

微乳液水热法制备钨酸铋光催化剂及性能研究

赖树挺, 张鹏, 周武艺, 谢振华, 杨卓鸿

(华南农业大学理学院, 生物材料研究所, 广州 510642)

收稿日期:2011-10-22 修回日期:2012-01-08 出版日期:2012-09-20 网络出版日期:2012-08-28
作者简介:赖树挺(1986-), 男, 硕士研究生. E-mail: Lai-Shuting@hotmail.com
基金资助:
国家自然科学基金(31101854)

Synthesis and Properties of Visible-light Photocatalytic Bi₂WO₆ via Microemulsion- assisted Hydrothermal Method

LAI Shu-Ting, ZHANG Peng, ZHOU Wu-Yi, XIE Zhen-Hua, YANG Zhuo-Hong

(Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou 510642, China)

Received:2011-10-22 Revised:2012-01-08 Published:2012-09-20 Online:2012-08-28
About author:LAI Shu-Ting.E-mail: Lai-Shuting@hotmail.com
Supported by:
National Natural Science Foundation of China(31101854)

摘要/Abstract

摘要： 采用微乳液介导水热法制备Bi₂WO₆和Fe/Bi₂WO₆光催化剂, 并研究水热反应温度、前驱体pH值、水相与表面活性剂的摩尔比w值和Fe³⁺掺杂量对光催化剂结构、形貌和光催化活性等方面的影响. 结果表明: 合成的Bi₂WO₆为15~25 nm的纳米球状结构; 当前驱体pH=1、水热温度为150℃下合成的Bi₂WO₆催化剂对亚甲基蓝(MB)的降解率达到93.8%; 当ω=27时合成的Bi₂WO₆对MB光催化降解率达到了97.8%. 研究发现当掺入1.03%的Fe³⁺的 Bi₂WO₆比纯Bi₂WO₆对MB的降解率提高了2倍, 达到90.2%.

关键词: Bi₂WO₆, 微乳液, Fe³⁺掺杂, 光催化

Abstract: The novel Bi₂WO₆ and Fe³⁺/Bi₂WO₆ photocatalysts were fabricated separately via a reverse microemulsion method. The effect factors including synthesis temperature, pH value, molar ratio of water to surfactant (ω) and Fe³⁺doping on the structure, morphologies and photocatalysis performance of photocatalysts were studied in detail. These results show that Bi₂WO₆ possesses a high degree of crystallinity of nano-spherical structure with the size of 15–25 nm. The photodegradation rate of methylene blue (MB) is 93.8% as the Bi₂WO₆ photocatalyst was synthesized at 150℃. The results reveal that the photodegradation rate of MB reaches 97.8% as ω is 27. It’s found that the photodegradation rate of MB for 1.03% Fe-doped Bi₂WO₆ sample has increased to 90.2%, which is two times higher than that of pure Bi₂WO₆.

Key words: Bi₂WO₆, microemulsion, Fe-doped, photocatalysis

中图分类号:

TQ135

赖树挺, 张鹏, 周武艺, 谢振华, 杨卓鸿. 微乳液水热法制备钨酸铋光催化剂及性能研究[J]. 无机材料学报, 2012, 27(9): 945-950.

LAI Shu-Ting, ZHANG Peng, ZHOU Wu-Yi, XIE Zhen-Hua, YANG Zhuo-Hong. Synthesis and Properties of Visible-light Photocatalytic Bi₂WO₆ via Microemulsion- assisted Hydrothermal Method[J]. Journal of Inorganic Materials, 2012, 27(9): 945-950.

参考文献

[1] Woan K, Pyrgiotakis G, Sigmund W. Photocatalytic carbon- nano¬tube-TiO2 composites. Adv. Mater., 2009, 21(21): 2233-2239.

[2] Irie H, Watanabe Y, Hashimoto K. Nitrogen-concentration dependence on photocatalytic activity of TiO2-xNx powders. J. Phys. Chem. B, 2003, 107(23): 5483-5486.

[3] Shao G S, Zhang X J, Yuan Z Y. Preparation and photocatalytic activity of hierarchically mesoporous-macroporous TiO2-xNx. Appl. Catal. B: Environ., 2008, 82(3/4): 208-218.

[4] Zhang Q W, Wang J, Yin S, et al. Synthesis of a visible-light active TiO2-xSx photocatalyst by means of mechanochemical doping. J. Am. Chem. Soc., 2004, 87(6): 1161-1163.

[5] Es-Souni M, Es-Souni M, Habouti S, et al. Brookite formation in TiO2-Ag nanocomposites andvisible-light-induced templated growth of Ag nanostructures in TiO2. Adv. Funct. Mater., 2010, 20(3): 377-385.

[6] LIU Hong-Lv, ZHANG Ai-Qian, WU Hai-Suo, et al. Solar photocatalytic degradation of p-nitrophenol assisted by cuprous oxide. Environmental Chemistry, 2004, 23(5): 490-494.

[7] Jing D W, Guo L J. A novel method for the preparation of a highly stable and active CdS photocatalyst with a special surface nano- structure. J. Phys. Chem. B, 2006, 110(23): 11139-11145.

[8] ZHANG Yong-Lai, DING Hong, LIU Fu-Jian, et al. Synthesis of nanosized Ag3VO4 particles and their photocatalytic activity for degradation of rhodamine B under visible light. Chinese Journal of Catalysis, 2008, 29(8): 783-787.

[9] Zhang A P, Zhang J Z, Cui N Y, et al. Effects of pH on hydrothermal synthesis and characterization of visible-light-driven BiVO4 photo-catalyst. J. Mol. Catal. A: Chem., 2009, 304(1/2): 28-32.

[10] Zhang Z J, Wang W Z, Yin W Z, et al. Inducing photocatalysis by visible light beyond the absorption edge: effect ofupconversion agent on the photocatalytic activity of Bi2WO6. Appl. Catal. B:Environ., 2010, 101(1/2): 68-73.

[11] Tang J W, Zou Z G, Yin J, et al. Photocatalytic degradation of methylene blue on CaIn2O4 under visible light irradiation. Chem. Phys. Lett., 2003, 382(1/2): 175-179.

[12] WANG Wen-Zhong, SHANG Meng, YIN Wen-Zong, et al. Recent progress on the bismuth containing complex oxide photocatalysts. Journal of Inorganic Materials, 2012, 27(1): 11-18.

[13] CHEN Hui, ZHU Kun. Photocatalytic oxidation degradation of acridine orange by TiO2 nanoparticles doped with metal ion. China Environmental Science, 2000, 20(6): 561-564.

[14] GE Lei, ZHANG Xian-Hua. Novel visible light driven Bi2WO6 photocatalysts synthesized via the microemulsion process and its photocatalytic performance. Journal of the Chinese Ceramic Society, 2010, 30(3): 457-462.

[15] LIU Ying, WANG Wei-Min, FU Zheng-Yi, et al. Hydrothermal synthesis and photocatalytic properties of Bi2WO6 Journal of Inorganic Materials, 2011, 26(11): 1169-1174.

[16] Zhou M H, Yu J G, Cheng B, et al. Preparation and photo-catalytic activity of Fe-doped mesoporous titanium dioxide nano-crystalline photocatalysts. Materials Chemistry and Physics, 2005, 93(1): 159-163.

[17] Zhu J F, Zheng W, He B, et al. Characterization of Fe-TiO2 photocatalysts synthesized by hydrothermal method and their photocatalytic reactivity for photodegradation of XRG dye diluted in water. J. Mol. Catal. A:Chem., 2004, 216(1): 35-43.

微乳液水热法制备钨酸铋光催化剂及性能研究

Synthesis and Properties of Visible-light Photocatalytic Bi₂WO₆ via Microemulsion- assisted Hydrothermal Method

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微乳液水热法制备钨酸铋光催化剂及性能研究

Synthesis and Properties of Visible-light Photocatalytic Bi2WO6 via Microemulsion- assisted Hydrothermal Method

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Synthesis and Properties of Visible-light Photocatalytic Bi₂WO₆ via Microemulsion- assisted Hydrothermal Method