高声子能量氧化物对掺铒碲酸盐玻璃光谱性质的影响

doi:10.3724/SP.J.1077.2012.11572

无机材料学报 ›› 2012, Vol. 27 ›› Issue (8): 865-870.DOI: 10.3724/SP.J.1077.2012.11572

高声子能量氧化物对掺铒碲酸盐玻璃光谱性质的影响

王森, 周亚训, 戴世勋, 王训四, 沈祥, 陈飞飞

(宁波大学信息科学与工程学院, 宁波 315211)

收稿日期:2011-09-01 修回日期:2011-10-31 出版日期:2012-08-20 网络出版日期:2012-07-09
作者简介:王森(1986-), 男, 硕士研究生. E-mail: wangsen8091563@163.com
基金资助:
国家自然科学基金(61178063); 浙江省研究生创新科研项目(YK2010048); 宁波市自然科学基金(2010A610172); 宁波“新型光电功能材料及器件”创新团队项目(2009B21007); 宁波大学王宽诚幸福基金; 胡岚优秀博士基金

Influence of High Phonon Energy Oxide on Spectroscopic Properties of Er³⁺/Ce³⁺ Co-doped Tellurite Glasses

WANG Sen, ZHOU Ya-Xun, DAI Shi-Xun, WANG Xun-Si, SHEN Xiang, CHEN Fei-Fei

(College of Information Science and Engineering, Ningbo University, Ningbo 315211, China)

Received:2011-09-01 Revised:2011-10-31 Published:2012-08-20 Online:2012-07-09
About author:WANG Sen. E-mail: wangsen8091563@163.com
Supported by:
National Natural Science Foundation of China (61178063); The Graduate Innovative Scientific Research Project of Zhejiang Province (YK2010048); Natural Science Foundation of Ningbo City (2010A610172); Ningbo Optoelectronic Materials and Devices Creative Team (2009B21007); K. C. Wong Magna Fund; Hu Lan Outstanding Doctoral Fund in Ningbo University

摘要/Abstract

摘要： 在研制的Er³⁺/Ce³⁺共掺低声子能量碲酸盐玻璃(TeO₂-Bi₂O₃-TiO₂)中, 分别引入高声子能量WO₃、SiO₂和B₂O₃氧化物组分, 测试了玻璃样品400~1700 nm范围内的吸收光谱、1.53 μm波段荧光谱、Er³⁺离子荧光寿命和拉曼光谱, 结合McCumber理论计算了Er³⁺离子光谱参数. 结果表明: 高声子能量氧化物组分的引入, 能使声子参与的Er³⁺/Ce³⁺离子间能量传递过程变得更为有效, 增加了Er³⁺离子亚稳态能级⁴I_13/2上粒子数积累, 从而增强1.53 μm波段荧光发射. 另外, 高声子能量氧化物组分的引入还可以增加荧光半高宽(FWHM)和带宽品质因子(σ_e×FWHM). 研究结果对于获取具有优异光谱特性的掺Er³⁺光纤放大器(EDFA)的玻璃基质具有实际意义.

关键词: 碲酸盐玻璃, Er³⁺/Ce³⁺共掺, 能量传递, 1.53 μm波段荧光

Abstract: High phonon energy oxides of WO₃, SiO₂ and B2O3 were introduced into the Er³⁺/Ce³⁺ co-doped tellurite glass (TeO₂-Bi₂O₃-TiO₂) with low phonon energy, respectively. The absorption spectra in the wavelength region of 400–1700 nm, fluorescence spectra of 1.53 μm band, fluorescence lifetimes of Er³⁺ and Raman spectra of the glasses were measured. The spectral parameters of Er³⁺ were calculated with the help of McCumber theory. It is shown that the energy transfer process between Er³⁺ and Ce³⁺ becomes more effectively when introducing the high phonon energy oxide, and the 1.53 μm band fluorescence emission corresponding to Er³⁺:⁴I_13/2→⁴I_15/2 transition enhances accordingly due to the increased population of Er³⁺ in the ⁴I_13/2 level. Meanwhile, the fluorescence width at half magnitude (FWHM) and bandwidth quality factor (σ_e×FWHM) can be improved with the introducing of high phonon energy oxide. The results provide practical significance to obtain the excellent spectroscopic glass host applied for the Er³⁺-doped fiber amplifier (EDFA).

Key words: tellurite glass, Er³⁺/Ce³⁺ co-doping, energy transfer, 1.53 μm band fluorescence

中图分类号:

TQ171

王森, 周亚训, 戴世勋, 王训四, 沈祥, 陈飞飞. 高声子能量氧化物对掺铒碲酸盐玻璃光谱性质的影响[J]. 无机材料学报, 2012, 27(8): 865-870.

WANG Sen, ZHOU Ya-Xun, DAI Shi-Xun, WANG Xun-Si, SHEN Xiang, CHEN Fei-Fei. Influence of High Phonon Energy Oxide on Spectroscopic Properties of Er³⁺/Ce³⁺ Co-doped Tellurite Glasses[J]. Journal of Inorganic Materials, 2012, 27(8): 865-870.

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高声子能量氧化物对掺铒碲酸盐玻璃光谱性质的影响

Influence of High Phonon Energy Oxide on Spectroscopic Properties of Er³⁺/Ce³⁺ Co-doped Tellurite Glasses

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高声子能量氧化物对掺铒碲酸盐玻璃光谱性质的影响

Influence of High Phonon Energy Oxide on Spectroscopic Properties of Er3+/Ce3+ Co-doped Tellurite Glasses

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Influence of High Phonon Energy Oxide on Spectroscopic Properties of Er³⁺/Ce³⁺ Co-doped Tellurite Glasses