激光双面区熔Al2O3/Y3Al5O12共晶自生复合陶瓷的制备与表征

doi:10.3724/SP.J.1077.2012.11627

无机材料学报 ›› 2012, Vol. 27 ›› Issue (8): 843-848.DOI: 10.3724/SP.J.1077.2012.11627

激光双面区熔Al₂O₃/Y₃Al₅O₁₂共晶自生复合陶瓷的制备与表征

于建政, 张军, 苏海军, 宋衎, 刘林, 傅恒志

(西北工业大学凝固技术国家重点实验室, 西安710072)

收稿日期:2011-10-10 修回日期:2011-12-13 出版日期:2012-08-20 网络出版日期:2012-07-09
作者简介:于建政(1985-), 男, 硕士研究生. E-mail: yjznpu@yahoo.cn
基金资助:
国家自然科学基金(51002122, 50772090); 陕西省自然科学基金(2010JQ6005); 航空科学基金(2010ZF53064); 西北工业大学基础研究基金(G9KY1016); 中国博士后科学基金(2012M510218); 凝固技术国家重点实验室自主课题(76-QP-2011)

Fabrication and Characterization of Al₂O₃/Y₃Al₅O₁₂ Eutectic in situ Composite Ceramics by Double Side Laser Zone Remelting Method

YU Jian-Zheng, ZHANG Jun, SU Hai-Jun, SONG Kan, LIU Lin, FU Heng-Zhi

(State Key Laboratory of Solidifcation Processing, Northwestern Polytechnical University, Xi’an 710072, China)

Received:2011-10-10 Revised:2011-12-13 Published:2012-08-20 Online:2012-07-09
About author:YU Jian-Zheng.
Supported by:
National Natural Science Foundation of China (51002122, 50772090); Provincial Natural Science Foundation of Shaanxi Province (2010JQ6005); Aeronautical Science Foundation of China (2010ZF53064); NPU Foundation for Fundamental Research (NPU-FFR-G9KY1016); China Postdoctoral Science Foundation (2012M510218); Research Fund of the State Key Laboratory of Solidification Processing in NWPU (76-QP-2011)

摘要/Abstract

摘要： 采用激光区熔凝固技术制备大尺寸Al₂O₃/Y₃Al₅O₁₂(YAG)共晶自生复合陶瓷, 考察双面区熔条件下大尺寸氧化物共晶陶瓷的熔化及凝固成形规律, 采用扫描电镜、能谱和X射线衍射对其凝固组织特征进行了表征和分析. 研究结果表明:在优化的凝固工艺下, 激光双面区熔增加了熔凝层的厚度, 获得了熔凝层厚度8.2 mm, 长度65.0 mm, 致密度达98.5%±1%的Al₂O₃/YAG共晶陶瓷; 共晶熔凝层厚度随激光扫描速率的减小而增加, 随激光功率的增大而增大, 并且致密度随着激光功率的增大呈现先增大后减小的趋势; 双面区熔后的Al₂O₃/YAG共晶陶瓷微观组织由均一分布、相互交织的Al₂O₃和YAG共晶相组成, 共晶层片间距较小(1.0~3.5 μm), 且与凝固速度满足Jackson-Hunt公式; 共晶间距随扫描速率的增大逐渐减小; 双面区熔界面处共晶组织生长具有连续性, 界面结合良好; 共晶陶瓷的Vickers硬度为(18.6±1.0) GPa.

关键词: Al₂O₃/YAG, 共晶陶瓷, 激光双面区熔, 制备, 表征

Abstract: Al₂O₃/YAG eutectic in situ composite ceramics were prepared by double side laser zone remelting (DSLZR) with aiming at investigate the melting and solidification rules of oxide eutectic ceramics with large size under DSLZR condition. The solidification microstructures were characterized by SEM, XRD and EDS. The results show that solidified layer thickness of eutectic ceramics is enhanced by DSLZR. The eutectic ceramic plates with density up to 98.5%±1% are obtained, in which the thickness is 8.2 mm, and the length is 65.0 mm. The thickness of solidified layer is increased with decreasing laser scanning rate and increasing laser power. The density is initially increased and then decreased with the increase of laser scanning rate. The eutectic ceramic obtained by DSLZR is only consisted of uniform and interweaved Al₂O₃ and YAG phases. The relation between the eutectic spacing (λ; only 1.0~3.5 μm) and solidification rate (v) agrees with the Jackson-Hunt formula. With the increase of laser scanning rate, the eutectic spacing reduces. Furthermore, the growth of eutectic at double side remelting interface is continuous, so the binded interface is very well. The eutectic ceramic obtained has high Vickers hardness ((18.6±1.0) GPa) due to the fine solidification microstructure.

Key words: Al₂O₃ /YAG, eutectic composite, laser zone remelting, preparation, characterization

中图分类号:

TQ174

于建政, 张军, 苏海军, 宋衎, 刘林, 傅恒志. 激光双面区熔Al₂O₃/Y₃Al₅O₁₂共晶自生复合陶瓷的制备与表征[J]. 无机材料学报, 2012, 27(8): 843-848.

YU Jian-Zheng, ZHANG Jun, SU Hai-Jun, SONG Kan, LIU Lin, FU Heng-Zhi. Fabrication and Characterization of Al₂O₃/Y₃Al₅O₁₂ Eutectic in situ Composite Ceramics by Double Side Laser Zone Remelting Method[J]. Journal of Inorganic Materials, 2012, 27(8): 843-848.

参考文献

[1] Waku Y, Nakagawa N, Wakamoto T, et al. A ductile ceramic eutectic composite with high strength at 1873 K. Nature, 1997, 389(6646): 49-52.

[2] PAN Zhen-Su, ZHANG Hui-Feng, GUO Jing-Kun, et al. Status on the unidirectionally solidified eutectic composite. Journal of Inorganic Materials,1999, 14(4): 513-519.

[3] Perrière L, Valle R, Mazerolles L, et al. Crack propagation in directionally solidified eutectic ceramics. Journal of the European Ceramic Society, 2008, 28(12): 2337-2343.

[4] Su Haijun, Zhang Jun, Yu Jianzheng, et al. Rapid solidification and fracture behavior of ternary metastable eutectic Al2O3/YAG/YSZ in situ composite ceramic. Materials Science and Engineering A, 2011, 528(4/5): 1967-1973.

[5] Waku Y, Sakuma T. Dislocation mechanism of deformation and strength of Al2O3/YAG single crystal composites above 1500℃. Journal of the European Ceramic Society, 2000, 20(10): 1453-1458.

[6] LLorca J, Orera V M. Directionally solidi-ed eutectic ceramic oxides. Progress in Materials Science, 2006, 51(6): 711-809.

[7] Pastor J Y, LLorca J, Salaar A, et al. Mechanical properties of melt grown alumina-yttrium aluminum garnet eutectics up to 1900 K. Journal of the American Ceramic Society, 2005, 88(6):1488-1495.

[8] Triantafyllidis D, Li L, Stott F H. Surface treatment of alumina based ceramic using combined laser sources. Applied Surface Science, 2002, 186(1-4): 140-144.

[9] 苏海军. 超高温氧化铝基共晶自生复合陶瓷的凝固组织与性能. 西安: 西北工业大学博士论文, 2009.

[10] 张军, 苏海军, 刘林, 等. Al2O3/YAG共晶自生复合陶瓷的激光熔凝实验研究. 航空材料学报, 2003, 23(Suppl.): 171-174.

[11] Su Haijun, Zhang Jun, Deng Yangfang, et al. A modified preparation technique and characterization of directionally solidified Al2O3/Y3Al5O12 eutectic in situ composites. Scripta Materialia, 2009, 60(6): 362-365.

[12] Mizuno M, Noguchi T. Formation of compounds in Y2O3 -Al2O3 system. Rep. Govt. Industr. Inst. Nagoya, 1967, 16: 171-175.

[13] Warshaw I, Roy R. Stable and metastable equilibria in the systems Y2O3-Al2O3 and Gd2O3-Fe2O3. Journal of the American Ceramic Society, 1959, 42(9): 434-438.

[14] 陆学善著. 激光基质钇铝石榴石的进展. 北京: 科学出版社, 1972: 13-21.

[15] Su Haijun, Zhang Jun, Cui Chunjuan, et al. Rapid solidification behavior of Al2O3/Y3Al5O12 (YAG) binary eutectic ceramic in Situ composites. Materials Science and Engineering A, 2008, 479(1/2): 380-388.

[16] 裴军, 李江涛, 梁睿, 等(PEI Jun, et al). 以超重力熔铸新技术快速制备Al2O3/YAG/YSZ三元共陶瓷. 稀有金属材料与工程(Rare Metal Mat. Eng.), 2010, 39(5): 906-910.

[17] Zhang Duanming, Li Zhihua, Yu Boming, et al. Dynamic simulation on the preparation process of thin trims by pulsed laser. Science in China(Series A), 2001, 44(11): 1485-1496.

[18] 何永. 脉冲激光沉积ZnO薄膜的工艺及其性能的研究. 武汉: 武汉理工大学硕士论文, 2007.

[19] Pe-a J I, Larsson M, Merino R I, et al. Processing, microstructure and mechanical properties of directionally solidified Al2O3-Y3Al5O12-ZrO2 ternary eutectics. Journal of the European Society, 2006, 26(15): 3113-3121.

[20] Oliete P B, Pe-a J I. Study of the gas inclusions in Al2O3/Y3Al5O12 and Al2O3/Y3Al5O12/ZrO2 eutectic fibers grown by laser floating zone. Journal of Crystal Growth, 2007, 304(2): 514-519.

[21] DENG Yang-Fang, ZHANG Jun, SU Hai-Jun, et al. Microstructure and fracture toughness of Al2O3/Er3Al5O12 eutectic ceramic prepared by laser zone remelting. Journal of Inorganic Materials, 2011, 26(8): 841-846.

[22] Hunt J D, Jackson K A. Lamellar and rod eutectic growth. Trans. Metal. Soc. AIME, 1966, 236: 843-852.

[23] Elbaumu B M, Yoshikawa K, Shimamura K, et al. Microstructure of Al2O3/Y3Al5O12 eutectic fibers grown by μ-PD method. Journal of Crystal Growth, 1999, 198-199: 471-475.

[24] 苏海军, 张军, 刘林, 等. 定向凝固Al2O3/Y3Al5O12共晶自生复合材料的组织形态及非规则共晶生长. 金属学报, 2008, 44(4): 457-462.

[25] CUI Chun-Juan, ZHANG Jun, SU Hai-Jun, et al. Microstructures of directionally solidified Si-TaSi2 eutectic in situ composite for field emission. Journal of Inorganic Materials, 2007, 22(5): 1019-1023.

[26] Kingery W D, Bowen H K, Uhlmann D R. 清华大学新型陶瓷与精细工艺国家重点实验室译. 陶瓷导论, 2版. 北京: 高等教育出版社, 2010: 516-543.

激光双面区熔Al₂O₃/Y₃Al₅O₁₂共晶自生复合陶瓷的制备与表征

Fabrication and Characterization of Al₂O₃/Y₃Al₅O₁₂ Eutectic in situ Composite Ceramics by Double Side Laser Zone Remelting Method

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	韦婷婷, 徐华蕊, 朱归胜, 龙神峰, 张秀云, 赵昀云, 江旭鹏, 宋金杰, 郭宁杰, 龚祎鹏. BaTiO₃陶瓷的低温冷烧结制备及性能研究[J]. 无机材料学报, 2022, 37(8): 903-910.
[2]	白志强, 赵璐, 白云峰, 冯锋. MXenes的制备、性质及其在肿瘤诊疗中的研究进展[J]. 无机材料学报, 2022, 37(4): 361-375.
[3]	刘海方, 苏海军, 申仲琳, 姜浩, 赵迪, 刘园, 张军, 刘林, 傅恒志. 激光增材制造超高温氧化物共晶陶瓷研究进展[J]. 无机材料学报, 2022, 37(3): 255-266.
[4]	刘云鹏, 盛伟繁, 吴忠华. 同步辐射及其在无机材料中的应用进展[J]. 无机材料学报, 2021, 36(9): 901-918.
[5]	李江, 丁继扬, 黄新友. 稀土离子掺杂Gd₂O₂S闪烁陶瓷的研究进展[J]. 无机材料学报, 2021, 36(8): 789-806.
[6]	孙鲁超, 周翠, 杜铁锋, 吴贞, 雷一明, 李家麟, 苏海军, 王京阳. 光悬浮区熔定向凝固Al₂O₃/Er₃Al₅O₁₂和Al₂O₃/Yb₃Al₅O₁₂共晶陶瓷的制备与性能研究[J]. 无机材料学报, 2021, 36(6): 652-658.
[7]	李子宜, 章佳佳, 邹小勤, 左家玉, 李俊, 刘应书, 裴有康. 菱沸石分子筛膜的合成调控与气体分离研究进展[J]. 无机材料学报, 2021, 36(6): 579-591.
[8]	方华靖, 赵泽天, 武文婷, 汪宏. 柔性电致变色器件研究进展[J]. 无机材料学报, 2021, 36(2): 140-151.
[9]	夏芳芳, 王发坤, 胡海龙, 许翔, 李阳, 翟天佑. 二次谐波在二维材料结构表征中的应用[J]. 无机材料学报, 2021, 36(10): 1022-1030.
[10]	冯明星, 王斌, 徐鹏宇, 涂兵田, 王皓. 基于键价模型的MgAl₂O₄透明陶瓷热机械性能预测[J]. 无机材料学报, 2021, 36(10): 1067-1073.
[11]	陈磊,王恺,苏文韬,张文,徐晨光,王玉金,周玉. 过渡金属非氧化物高熵陶瓷的研究进展[J]. 无机材料学报, 2020, 35(7): 748-758.
[12]	马亚楠, 刘宇飞, 余晨旭, 张传坤, 罗时军, 高义华. 不同横向尺寸单层Ti₃C₂T_x纳米片的制备及其电化学性能研究[J]. 无机材料学报, 2020, 35(1): 93-98.
[13]	张天宇, 崔聪, 程仁飞, 胡敏敏, 王晓辉. 同步氨化/碳化法制备MXene/C平面多孔复合电极[J]. 无机材料学报, 2020, 35(1): 112-118.
[14]	陈仁德, 郭鹏, 左潇, 许世鹏, 柯培玲, 汪爱英. Ag掺杂非晶碳膜结构、力学与电学行为研究[J]. 无机材料学报, 2019, 34(4): 387-393.
[15]	万宇驰,湛菁,陈军. 不同形貌纳米NiCo₂O₄的研究进展[J]. 无机材料学报, 2019, 34(2): 121-129.