ZnO纳米棒阵列的水热生长条件对柔性染料敏化太阳能电池的影响

doi:10.3724/SP.J.1077.2012.12089

无机材料学报 ›› 2012, Vol. 27 ›› Issue (7): 775-779.DOI: 10.3724/SP.J.1077.2012.12089

ZnO纳米棒阵列的水热生长条件对柔性染料敏化太阳能电池的影响

朱新波¹, 方晓东^1,2,3, 邓赞红^1,2, 董伟伟^1,2, 王时茂¹, 邵景珍¹, 胡林华², 朱俊²

(1. 中国科学院安徽光学精密机械研究所, 合肥230031; 2. 中国科学院新型薄膜太阳电池重点实验室, 合肥230031; 3. 中国科学技术大学物理学院, 合肥 230029)

收稿日期:2012-02-14 修回日期:2012-03-14 出版日期:2012-07-20 网络出版日期:2012-06-06
作者简介:ZHU Xin-Bo(1987-), male, candidate of master degree. E-mail: zxb26j@126.com
基金资助:
National Natural Science Foundation of China (51172237); National Basic Research Program of China (2011CBA00700); National High Technology Research and Development Program of China (2011AA050527); Anhui Provincial International Science and Technology Cooperation Program (10080703021); Knowledge Innovation Program of the Chinese Academy of Sciences

Effects of Hydrothermal Growth Conditions of ZnO Nanorods Arrays on Flexible Dye-sensitized Solar Cells

ZHU Xin-Bo¹, FANG Xiao-Dong^1,2,3, DENG Zan-Hong^1,2, DONG Wei-Wei^1,2, WANG Shi-Mao¹, SHAO Jing-Zhen¹, HU Lin-Hua², ZHU Jun²

(1. Anhui Provincial Key Laboratory of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China; 2. Key Lab of New Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, China; 3. School of Physical Sciences, University of Science and Technology of China, Hefei 230029, China)

Received:2012-02-14 Revised:2012-03-14 Published:2012-07-20 Online:2012-06-06
About author:ZHU Xin-Bo(1987-), male, candidate of master degree. E-mail: zxb26j@126.com
Supported by:
National Natural Science Foundation of China (51172237); National Basic Research Program of China (2011CBA00700); National High Technology Research and Development Program of China (2011AA050527); Anhui Provincial International Science and Technology Cooperation Program (10080703021); Knowledge Innovation Program of the Chinese Academy of Sciences

摘要/Abstract

摘要： 利用水热法在不同条件下在ITO-PET(tin-doped indium oxide polyethylene terephthalate)上制备氧化锌纳米棒阵列, 通过一些定量的参数, 如纳米棒的直径、长度和棒密度来表征纳米棒的形貌. 通过改变反应条件可以调节上述参数. 分别讨论了两个重要条件: 反应时间和前驱体浓度. 研究表明前驱体浓度对长径比有重要影响. 柔性基底上的氧化锌纳米棒作为染料敏化电池的新型光阳极, 长径比的改变对柔性电池有重要的影响. 可通过调节反应条件来提高柔性染料敏化电池的性能.

关键词: 氧化锌纳米棒阵列, 水热, 柔性, 染料敏化太阳能电池

Abstract: ZnO nanorod arrays (ZNRs) were prepared on the tin-doped indium oxide polyethylene terephthalate (ITO-PET) by hydrothermal method under different conditions. Morphology of ZNRs was characterized by some quantitative parameters such as the diameter and length of nanorod and the density of rods. All these parameters were adjusted by changing the reaction conditions. Two important reaction conditions including reaction time and precursor concentration are discussed separately. It is demonstrated that the precursor concentration has great influence on the aspect ratio of nanorod. Flexible substrates with ZNRs are used as the novel photoanode of flexible dye-sensitized solar cells (DSCs). The aspect ratio of nanorod has major influence on the performance of flexible DSCs. The performance of flexible DSCs is improved by controlling the reaction conditions.

Key words: ZnO nanorod arrays, hydrothermal, flexible, dye-sensitized solar cells

中图分类号:

O647

朱新波, 方晓东, 邓赞红, 董伟伟, 王时茂, 邵景珍, 胡林华, 朱俊. ZnO纳米棒阵列的水热生长条件对柔性染料敏化太阳能电池的影响[J]. 无机材料学报, 2012, 27(7): 775-779.

ZHU Xin-Bo, FANG Xiao-Dong, DENG Zan-Hong, DONG Wei-Wei, WANG Shi-Mao, SHAO Jing-Zhen, HU Lin-Hua, ZHU Jun. Effects of Hydrothermal Growth Conditions of ZnO Nanorods Arrays on Flexible Dye-sensitized Solar Cells[J]. Journal of Inorganic Materials, 2012, 27(7): 775-779.

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ZnO纳米棒阵列的水热生长条件对柔性染料敏化太阳能电池的影响

Effects of Hydrothermal Growth Conditions of ZnO Nanorods Arrays on Flexible Dye-sensitized Solar Cells

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