γ-Bi2O3/TiO2复合纤维的制备及光催化性能

doi:10.3724/SP.J.1077.2012.11490

无机材料学报 ›› 2012, Vol. 27 ›› Issue (7): 687-692.DOI: 10.3724/SP.J.1077.2012.11490

γ-Bi₂O₃/TiO₂复合纤维的制备及光催化性能

李跃军^1,2, 曹铁平², 邵长路¹, 王长华¹

(1. 东北师范大学先进光电子功能材料研究中心, 长春130024; 2. 白城师范学院化学系, 白城 137000)

收稿日期:2011-08-05 修回日期:2011-10-28 出版日期:2012-07-20 网络出版日期:2012-06-06
作者简介:李跃军(1964-), 男, 副教授. E-mail: bclyj@yahoo.com.cn
基金资助:
国家自然科学基金(50572014, 50972027); 教育部新世纪优秀人才支持计划(NCET-05-0322); 吉林省科技发展计划(201205034)

Preparation and Photocatalytic Properties of γ-Bi₂O₃/TiO₂ Composite Fibers

LI Yue-Jun^1,2, CAO Tie-Ping², SHAO Chang-Lu¹, WANG Chang-Hua¹

(1. Centre for Advanced Optoelectronic Functional Material Research, Northeast Normal University, Changchun 130024, China; 2. Department of Chemistry, Baicheng Normal College, Baicheng 137000, China)

Received:2011-08-05 Revised:2011-10-28 Published:2012-07-20 Online:2012-06-06
About author:LI Yue-Jun. E-mail: bclyj@yahoo.com.cn
Supported by:
National Natural Science Foundation of China (50572014, 50972027); New Century Excellent Talents in University (05-0322); Development Project of Science and Technology of Jilin Province (201205034)

摘要/Abstract

摘要： 采用静电纺丝技术与溶剂热法相结合制备了γ-Bi₂O₃/TiO₂复合纤维光催化材料. 利用X射线衍射(XRD)、扫描电镜(SEM)、电子能谱(EDS)、透射电镜(TEM)、高分辨透射电镜(HRTEM)和紫外–可见吸收光谱(UV-Vis)等分析测试手段对材料进行了表征, 并以罗丹明Ｂ(RB)的脱色降解为模式反应, 考察了材料的可见光催化性能. 结果表明: γ-Bi₂O₃纳米片均匀地生长在TiO₂纤维上, 形成了具有异质结构的γ-Bi₂O₃/TiO₂复合纤维光催化材料, 其光谱响应范围拓宽至可见光区, 有利于TiO₂光生电子和空穴的分离, 增强了体系的量子效率. 与纯TiO₂纤维相比可见光催化活性明显提高, 对RB的脱色率达87.8%.

关键词: 静电纺丝, 溶剂热法, γ-Bi₂O₃ /TiO₂复合纤维, 光催化

Abstract: Heterostructured γ-Bi₂O₃/TiO₂ composite fibers were prepared via combination of solvothermal method and electrospinning technique. X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscope (EDS), transmission electron microscope (TEM), high-resolution transmission electron microscope (HRTEM) and UV-Vis absorption spectra were used to characterize heterostructured γ-Bi₂O₃/TiO₂composite fibers. The photocatalytic properties of the heterostructured samples were evaluated by degrading rhodamine B (RB) under visible light irradiation. The results showed that γ-Bi₂O₃ nanosheets could evenly grow on the TiO₂ fibers surface and thus heterostructured γ-Bi₂O₃/TiO₂ composite fibers were successfully obtained. The absorption range of the as-obtained heterostructured samples were extended to the visible light region. Moreover, the presence of γ-Bi₂O₃ nanostructures/TiO₂ fibers heterostructures was beneficial to separation of photo-generated electrons and holes which enhanced the system’s quantum efficiency. In comparison with that of pure TiO₂ nanofibers, the γ-Bi₂O₃/TiO₂ heterostructures have enhanced photocatalytic efficiency under visible light irradiation, and the decolorizing efficiency of RB solution can reach 87.8%.

Key words: electrospinning, solvothermal method, γ-Bi₂O₃/TiO₂ composite fibers, photocatalytic degradation

中图分类号:

O643

李跃军, 曹铁平, 邵长路, 王长华. γ-Bi₂O₃/TiO₂复合纤维的制备及光催化性能[J]. 无机材料学报, 2012, 27(7): 687-692.

LI Yue-Jun, CAO Tie-Ping, SHAO Chang-Lu, WANG Chang-Hua. Preparation and Photocatalytic Properties of γ-Bi₂O₃/TiO₂ Composite Fibers[J]. Journal of Inorganic Materials, 2012, 27(7): 687-692.

参考文献

[1] Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode. Nature, 1972, 238(5358): 37-38.

[2] Fujishima A, Zhang X T, Tryk D A. TiO2 photocatalysis and related surface phenomena. Surf. Sci. Rep., 2008, 63(12): 515-582.

[3] Chen X B, Shen S H, Guo L J, et al. Semiconductor-based photocatalytic hydrogen generation. Chem. Rev., 2010, 110(11): 6503-6570.

[4] ZHOU Wen-Qian, LU Yu-Ming, CHEN Chang-Zhao, et al．Effect of Li-doped TiO2 compact layers for dye sensitized solar cell. Journal of Inorganic Materials, 2011, 26(8): 819-822．

[5] Cao T P, Li Y J, Shao C L, et al. Fabrication, structure, and enhanced photocatalytic properties of hierarchical CeO2 nanostructures/TiO2 nano-bers heterostructures. Materials Research Bulletin, 2010, 45(10): 1406-1412.

[6] Chen X B, Mao S S. Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev, 2007, 107(7): 2891-2959.

[7] Subramanian V, Wolf E E, Kamat P V. Catalysis with TiO2/gold nanocomposites. effect of metal particle size on the fermi level equilibration. J. Am. Chem. Soc., 2004, 126(15): 4943-4950.

[8] Cabot A, Marsal A, Arbiol J, et al. Bi2O3 as a selective sensing material for NO detection. Sensors and Actuators B, 2004, 99(1): 74-89.

[9] Drache M, Roussel P, Wignacourt J P. Structures and oxide mobility in Bi-Ln-O materials: heritage of Bi2O3. Chem. Rev., 2007, 107(1): 80-96.

[10] Harwig H A, Gerards A G. Electrical properties of the α , β, γ and δ phases of bismuth sesquoxide. Journal of Solid State Chemistry, 1978, 26: 265-274.

[11] Harwig H A. On the structure of bismuthsesquioixide: the alpha,beta, gamma and delta-phase. Zeitschrift fur Anorganische und Allgemeine Chemie, 1978, 444: 151-166.

[12] Wang C H, Shao C L, Wang L J, et al. Electrospinning preparation, characterization and photocatalytic properties of Bi2O3 nanofibers. J. Colloid Interf. Sci., 2009, 333(1): 242-248.

[13] Bessekhouad Y, Robert D, Weber J V. Photocatalytic activity of Cu2O/TiO2, Bi2O3/TiO2 and ZnMn2O4/TiO2 heterojunctions. Catal. Today, 2005, 101(3/4): 315-321.

[14] 邹文, 郝维昌, 信心, 等. 不同晶型Bi2O3可见光光催化降解罗丹明B的研究. 无机化学学报(Chinese J. Inorg. Chem.), 2009, 25(11): 1971-1976.

[15] Zhang L S, Wang W Z, Yang J, et al. Sonochemical synthesis of nanocrystallite Bi2O3 as a visible-light-driven photocatalyst. Applied Catalysis A: General, 2006, 308(7): 105-110.

[16] He W D, Qin W, Wu X H, et al. The photocatalytic properties of bismuth oxide films prepared through the Sol-Gel method. Thin Solid Films, 2007, 515(13): 5362-5365.

[17] Gurunathan K. Photocatalytic hydrogen production using transition metal ions-doped γ-Bi2O3 semiconductor particles. International Journal of Hydrogen Energy, 2004, 29(9): 933-940.

[18] Cloutt B A, Sagatys D S, Smith G, et al. The preparation and crystal structure of a unique bismuth complex with ethylene glycol:the tris [ethane1,2-diolato(2-)] dibismuth(III) polymer hydrate. Aust. J. Chem., 1997, 50: 947-950.

[19] Bian Z F, Ren J, Zhu J, et al. Self-assembly of BixTi1-xO2 visible photocatalyst with core–shell structure and enhanced activity. Appl. Catal. B: Environ., 2009, 89(3): 577-582.

[20] Cao X B, Lan X M, Guo Y, et al. Preparation and characterization of bifunctional ZnO/ZnS nanoribbons decorated by gamma-Fe2O3 clusters. J. Phys. Chem. C, 2007, 111(51): 18958-18964.

[21] Masuda Y, Ieda S, Koumoto K. Site-selective deposition of anatase TiO2 in an aqueous solution using a seed layer. Langmuir, 2003, 19(10): 4415-4419.

[22] Yu H G, Lee S C, Yu J G, et al. Photocatalytic activity of dispersed TiO2 particles deposited on glass fibers. J. Mol. Catal. A, 2006, 246(1/2): 206-211.

[23] Kabalnov J, Disper. Ostwald ripening and related phenomena. J. Disper. Sci. Technol., 2001, 22(1): 1-12.

[24] Yu J G, Guo H G, Davis S A, et al. Fabrication of hollow inorganic microspheres by chemically induced self-transformation. Adv. Funct. Mater., 2006, 16(15): 2035-2041.

[25] Yu J G., Zhao X F, Liu S W, et al. Poly(methacrylic acid)-mediated morphosynthesis of PbWO4 micro-crystals. Appl. Phys. A-Mater. Sci. Proc., 2007, 87(1): 113-120.

γ-Bi₂O₃/TiO₂复合纤维的制备及光催化性能

Preparation and Photocatalytic Properties of γ-Bi₂O₃/TiO₂ Composite Fibers

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