无机材料学报 ›› 2012, Vol. 27 ›› Issue (1): 1-10.DOI: 10.3724/SP.J.1077.2012.00001
• • 下一篇
张青红
收稿日期:
2011-09-22
修回日期:
2011-09-27
出版日期:
2012-01-09
网络出版日期:
2011-12-19
作者简介:
张青红, 男, 博士, 东华大学教授, 博士生导师. 主要从事光催化、染料敏化太阳能电池、自组装、有机/无机杂化材料的研究, 在二氧化钛纳米结构的晶相控制、形貌调控、构效关系、锐钛矿水性溶胶、可见光催化等方面成果突出, 已在Chem. Commun., Appl. Catal. B: Environ., Langmuir, J. Mater. Chem., J. Am. Ceram. Soc. 等国内外核心刊物发表学术论文80余篇, 论文他引超过1100余篇次, 单篇论文他引超过200余篇次, 获20余项中国发明专利授权, 合著《纳米氧化钛光催化材料及应用》一部. 先后主持科技部十一五支撑计划子课题1项、国家自然科学基金项目3项, 参与上海市纳米科技专项3项, 作为主要研究人员分别于2002年、2006年获得上海市自然科学奖二等奖各1项.
基金资助:
ZHANG Qing-Hong
Received:
2011-09-22
Revised:
2011-09-27
Published:
2012-01-09
Online:
2011-12-19
Supported by:
摘要:
二氧化钛纳米材料是当前纳米科技的研究热点, 其在太阳能光催化分解水制氢、二氧化碳的光催化还原、染料敏化太阳能电池等清洁能源技术方面均显示了重大的应用前景. 本文主要综述了近年来二氧化钛基纳米材料的研究趋势、存在的主要问题, 以及这些材料在上述清洁能源利用中的最新进展. 对备受关注的非金属掺杂、高能面暴露的二氧化钛、染料敏化太阳能电池阳极致密层等热点问题进行了评述和展望.
中图分类号:
张青红. 二氧化钛基纳米材料及其在清洁能源技术中的研究进展[J]. 无机材料学报, 2012, 27(1): 1-10.
ZHANG Qing-Hong. Progress on TiO2-based Nanomaterials and Its Utilization in the Clean Energy Technology[J]. Journal of Inorganic Materials, 2012, 27(1): 1-10.
图1 氮掺杂TiO2[9](A)与TiO2/Ta3N5(B)纳米复合光催化材料的紫外-可见漫反射光谱
Fig. 1 UV-Vis diffuse reflectance spectra of nitrogen doping TiO2[9] and TiO2/Ta3N5 nanocomposite photocatalyst
图3 (a) 单晶锐钛矿相二氧化钛的XRD图谱; (b) 单晶锐钛矿相二氧化钛的FE-SEM照片; (c) {001}面与{101}面的夹角, 白色虚线分别代表(001)面与(101)面; (d)单晶锐钛矿相二氧化钛暴露的{110}面(以圈表示); (e)单晶锐钛矿相二氧化钛的结构示意图; (f)单晶锐钛矿相二氧化钛与不规整二氧化钛光催化降解亚甲基蓝, 不同反应时间内亚甲基蓝溶液浓度的变化[30]
Fig. 3 (a) XRD pattern of the anatase single crystals; (b) FE-SEM image of the anatase single crystals; (c) Interfacial angle between {001} and {101} facets (68.3°±0.3° on average). The white dashed lines indicate the (001) and (101) crystal planes of anatase TiO2, respectively; (d) Small rhombus {110} facets (indicated by red circle) of the anatase single crystals; (e) Schematic diagram of the anatase single crystal; (f) The variation of MB concentration by photochemical reaction with the anatase TiO2 single crystals and the irregular TiO2 product[30]
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[98] | 作者学术成就介绍: |
[99] | 张青红, 男, 博士, 东华大学教授, 博士生导师. 主要从事光催化、染料敏化太阳能电池、自组装、有机/无机杂化材料的研究, 在二氧化钛纳米结构的晶相控制、形貌调控、构效关系、锐钛矿水性溶胶、可见光催化等方面成果突出, 已在Chem. Commun., Appl. Catal. B: Environ., Langmuir, J. Mater. Chem., J. Am. Ceram. Soc. 等国内外核心刊物发表学术论文80余篇, 论文他引超过1100余篇次, 单篇论文他引超过200余篇次, 获20余项中国发明专利授权, 合著《纳米氧化钛光催化材料及应用》一部. 先后主持科技部十一五支撑计划子课题1项、国家自然科学基金项目3项, 参与上海市纳米科技专项3项, 作为主要研究人员分别于2002年、2006年获得上海市自然科学奖二等奖各1项. |
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