整体抗氧化C/C-ZrC-SiC复合材料的超高温烧蚀性能研究

doi:10.3724/SP.J.1077.2011.00852

无机材料学报 ›› 2011, Vol. 26 ›› Issue (8): 852-856.DOI: 10.3724/SP.J.1077.2011.00852

整体抗氧化C/C-ZrC-SiC复合材料的超高温烧蚀性能研究

武海棠^1,2, 魏玺¹, 于守泉¹, 张伟刚¹

(1. 中国科学院过程工程研究所, 多相复杂系统国家重点实验室, 北京 100190; 2. 中国科学院研究生院, 北京 100049)

收稿日期:2010-10-12 修回日期:2010-11-26 出版日期:2011-08-20 网络出版日期:2011-07-14
作者简介:武海棠(1982-), 男, 博士研究生. E-mail: haitang345@yahoo.cn
基金资助:
中国科学院知识创新工程重要方向项目(YYYJ-0808-2)

Ablation Performances of Multi-phased C/C-ZrC-SiC Ultra-high Temperature Composites

WU Hai-Tang^1,2, WEI Xi¹, YU Shou-Quan¹, ZHANG Wei-Gang¹

(1. State Key Lab of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China; 2. Graduate University of the Chinese Academy of Sciences, Beijing 100049, China)

Received:2010-10-12 Revised:2010-11-26 Published:2011-08-20 Online:2011-07-14
Supported by:
CAS Knowledge Innovation Program(YYYJ-0808-2)

摘要/Abstract

摘要： 以聚合有机锆与聚碳硅烷组成的共溶前驱体为原料, 采用溶液浸渍-裂解(PIP)工艺制得了2D C/C-ZrC-SiC复合材料, 对复合材料的超高温烧蚀性能进行了研究. 利用SEM和XRD对烧蚀后材料的微观结构和物相组成进行分析, 探讨了复合材料的抗烧蚀机理. 结果表明, 复合材料的质量烧蚀率和线烧蚀率随着ZrC含量的增加先减小后增大. 其中ZrC含量为17.45vol%的复合材料具有最优的抗烧蚀性能, 即在表面温度为2200℃, 等离子焰烧蚀300s后, 其质量烧蚀率仅为1.77mg/s, 线烧蚀率为0.55μm/s. 研究发现, 材料表层的ZrC氧化生成的ZrO₂溶于SiC氧化生成的SiO₂中, 形成粘稠的二元玻璃态混合物, 有效阻止氧化性气氛进入基体内部, 对抗超高温烧蚀起到协同作用.

关键词: 前驱体浸渍-裂解, C/C-ZrC-SiC复合材料, 烧蚀性能

Abstract: The 2D C/C-ZrC-SiC composites were prepared through precursor infiltration and pyrolysis (PIP) process using a hybrid precursor contained polycarbosilane and organic zirconium-contained polymeric precursor. The microstructures and ablation behaviors of the prepared composites were studied. The composition and microstructure of the ablated samples were characterized by XRD and SEM, respectively. The results show that the mass ablation rate and linear ablation rate of the composites generally firstly decrease and then increase with the increasing of ZrC contents. The sample with 17.45vol% ZrC has optimum anti-ablation property. After ablation at 2200℃ for 300s via the plasma torch heating technique, the mass loss and linear recession rate is as low as 1.77mg/s and 0.55μm/s, respectively. It is found that during ultra-high temperature stage, the matrix of ZrC and SiC are oxidized into ZrO₂ and SiO₂, which form a kind of viscous binary glassy mixture. The mixture could effectively cover the ablation surface and therefore promote its anti-ablation property.

Key words: precursor infiltration and pyrolysis, C/C-ZrC-SiC composite, anti-ablation property

中图分类号:

TB332

武海棠, 魏玺, 于守泉, 张伟刚. 整体抗氧化C/C-ZrC-SiC复合材料的超高温烧蚀性能研究[J]. 无机材料学报, 2011, 26(8): 852-856.

WU Hai-Tang, WEI Xi , YU Shou-Quan, ZHANG Wei-Gang. Ablation Performances of Multi-phased C/C-ZrC-SiC Ultra-high Temperature Composites[J]. Journal of Inorganic Materials, 2011, 26(8): 852-856.

参考文献

[1] 张伟刚. 化学气相沉积-从烃类气体到固体碳. 北京:科学出版社, 2007: 266-273.

[2] Windhorst T, Blount G. Carbon-carbon composites: a summary of recent developments and application. Materials and Design, 1997, 18(1): 11-15.

[3] Fitzer E. The future of carbon-carbon composites. Carbon, 1987, 25(2): 163-190.

[4] 韩杰才, 胡平, 张幸红, 等. 超高温材料的研究进展. 固体火箭技术, 2005, 28(4) : 289-294.

[5] 徐永东, 成来飞, 张立同, 等(XU Yong-Dong, et al). 连续纤维增韧碳化硅陶瓷基复合材料研究. 硅酸盐学报(Journal of the Chinese Ceramic Society), 2002, 30(2): 184-188.

[6] Lee Y J, Joo H J. Ablation characteristics of carbon fiber reinforced carbon (CFRC) composites in the presence of silicon carbide (SiC) coating. Surface and Coatings Technology, 2004, 180/181(1): 286-289.

[7] Lespade P, Richet N, Goursat P. Oxidation resistance of HfB2–SiC composites for protection of carbon-based materials. Acta Astronautica, 2007, 60(10/11): 858-864.

[8] 李翠艳, 李克智, 欧阳海波, 等(LI Cui-Yan, et al). HfC改性炭/炭复合材料的烧蚀性能. 稀有金属材料与工程(Rare Metal Mat. Eng.), 2006, 35(S2): 365-368.

[9] 李淑萍, 李克智, 郭领军, 等. HfC改性C/C复合材料整体喉衬的烧蚀性能研究. 无机材料学报(Journal of Inorganic Materials), 2008, 23(6): 1155-1158.

[10] Li H B, Zhang L T, Cheng L F, et al. Fabrication of 2DC/ZrC–SiC composite and its structural evolution under high-temperature treatment up to 1800℃. Ceramics International, 2009, 35(7): 2831-2836.

[11] 王俊山, 李仲平, 敖明, 等. 掺杂难熔金属碳化物对炭/炭复合材料烧蚀微观结构的影响. 新型炭材料, 2005, 20(2): 97-102.

[12] Li X T, Shi J L, Zhang G B, et al. Effect of ZrB2 on the ablation properties of carbon composites. Materials Letters, 2006, 60(7): 892-896.

[13] Tang S F, Deng J Y, Wang S J, et al. Ablation behaviors of ultra- high temperature ceramic composites. Materials Science & Engineering A, 2007, 465(1/2): 1-7.

[14] Tong Q F, Shi J L, Song Y Z, et al. Resistance to ablation of pitch- derived ZrC/C composites. Carbon, 2004, 42(12/13): 2495-2500.

[15] Sun W, Xiong X, Huang B Y, et al. ZrC ablation protective coating for carbon/carbon composites. Carbon, 2009, 47(14): 3368-3371.

[16] 沈学涛, 李克智, 李贺军, 等(SHEN Xue-Tao, et al). 烧蚀产物ZrO2对ZrC改性C/C复合材料烧蚀的影响. 无机材料学报(Journal of Inorganic Materials), 2009, 24(5): 943-947.

[17] 王其坤, 胡海峰, 陈朝辉. 先驱体转化法制备2D C/SiC-ZrC复合材料中ZrC含量对材料结构性能影响研究. 航空材料学报, 2009, 29(4): 72-76.

[18] 刘建军, 苏君明, 陈长乐. 炭/炭复合材料烧蚀性能影响因素分析. 炭素, 2003(2): 15-19.

整体抗氧化C/C-ZrC-SiC复合材料的超高温烧蚀性能研究

Ablation Performances of Multi-phased C/C-ZrC-SiC Ultra-high Temperature Composites

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

本文评价

[1]	樊乾国, 崔红, 闫联生, 张强, 孟祥利, 杨星. 浆料浸渍法制备C/C-SiC-ZrB₂超高温复合材料及其烧蚀性能研究[J]. 无机材料学报, 2013, 28(9): 1014-1018.
[2]	周海军, 张翔宇, 高乐, 胡建宝, 吴斌, 董绍明. ZrB₂-SiC超高温陶瓷涂层的抗烧蚀性能研究[J]. 无机材料学报, 2013, 28(3): 256-260.