高密度预制体制备炭/炭复合材料致密化研究

doi:10.3724/SP.J.1077.2011.00711

无机材料学报 ›› 2011, Vol. 26 ›› Issue (7): 711-714.DOI: 10.3724/SP.J.1077.2011.00711

高密度预制体制备炭/炭复合材料致密化研究

李建立, 苏哲安, 张明瑜, 杨鑫, 黄启忠

(中南大学粉末冶金国家重点实验室, 长沙 410083)

收稿日期:2010-09-06 修回日期:2010-11-14 出版日期:2011-07-20 网络出版日期:2011-06-20
作者简介:李建立(1986-), 男, 硕士研究生. E-mail: leejunney@hotmail.com
基金资助:
国家自然科学基金(50802115); 国家973计划(2011CB605801)

Mechanism of Densification of C/C Composites Fabricated with High Density Preform

LI Jian-Li, SU Zhe-An, ZHANG Ming-Yu, YANG Xin, HUANG Qi-Zhong

(State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China)

Received:2010-09-06 Revised:2010-11-14 Published:2011-07-20 Online:2011-06-20
Supported by:
National Natural Science Foundation of China (50802115); 973 Program (2011CB605801)

摘要/Abstract

摘要： 采用高密度3D炭纤维预制体, 以丙烯作为碳源, 氮气作为载气, 利用自制的快速CVI炉制备了板形C/C复合材料. 详细分析了压差等工艺参数在CVI制备C/C复合材料过程中对“封孔”现象的影响, 采用扫描电镜(SEM)和正交偏光显微镜(PLM)对各阶段C/C材料的微观形貌特征作了详细研究, 分析了预制体在増密过程中密度的变化, 初步探讨了“封孔”形成的机理. 实验证明: 采用多阶段CVI工艺可明显改善板形C/C材料封孔现象, 初始密度为0.94g/cm³的高密度预制体经过250h的增密, C/C复合材料密度达到了1.82g/cm³.

关键词: 炭/炭复合材料, 多阶段CVI, 封孔, 增密, 高温热处理

Abstract: With C₃H₆as the precursor, N₂ as the carrier gas and high density 3D carbon fiber braided preform, the plate of C/C composites was fabricated by the fast CVI process. Influence of gradient pressure and other factors of process on the sealed pores in C/C composites were analyzed, and the morphologies were characterized by scanning electron microscope (SEM) and polarized light microscope (PLM) in detail. The formation mechanism of sealed pores and the transformation of density in high density preform in the densification process are simply analysized. The experimental results show that the sealed pores can be reduced by multi-stage CVI process and the density of the C/C composite are improved from 0.94g/cm3 to 1.82g/cm³after 250 h CVI process.

Key words: C/C composites, multi-stage CVI, sealed pores, densification, high temperature treatment

中图分类号:

TB332

李建立, 苏哲安, 张明瑜, 杨鑫, 黄启忠. 高密度预制体制备炭/炭复合材料致密化研究[J]. 无机材料学报, 2011, 26(7): 711-714.

LI Jian-Li, SU Zhe-An, ZHANG Ming-Yu, YANG Xin, HUANG Qi-Zhong. Mechanism of Densification of C/C Composites Fabricated with High Density Preform[J]. Journal of Inorganic Materials, 2011, 26(7): 711-714.

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高密度预制体制备炭/炭复合材料致密化研究

Mechanism of Densification of C/C Composites Fabricated with High Density Preform

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