钒电解液的绿色制备及其热力学分析

doi:10.3724/SP.J.1077.2011.00535

无机材料学报 ›› 2011, Vol. 26 ›› Issue (5): 535-539.DOI: 10.3724/SP.J.1077.2011.00535

钒电解液的绿色制备及其热力学分析

吴雄伟¹, 彭穗¹, 冯必钧¹, 山村朝雄², 矢野贵², 佐藤伊佐務², 刘素琴¹, 黄可龙¹

(1. 中南大学化学化工学院, 长沙 410083; 2. 日本东北大学, 日本仙台 9808577）

收稿日期:2010-07-02 修回日期:2010-11-01 出版日期:2011-05-20 网络出版日期:2011-06-07
作者简介:吴雄伟(1980-), 男, 博士研究生. E-mail: wxwcsu@yahoo.cn
基金资助:
国家重点基础研究发展计划(2010CB227201); 国家自然科学基金(50972165)

Preparation, Thermodynamic and Electrochemical Properties of Vanadium Solution

WU Xiong-Wei¹, PENG Sui¹, FENG Bi-Jun¹, Yamamura Tomoo², Takashi Yano², Satoh Isamu², LIU Su-Qin¹, HUANG Ke-Long¹

(1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China; 2. Institute for Materials Research, Tohoku University, Sendai, Miyagi 980-8577, Japan)

Received:2010-07-02 Revised:2010-11-01 Published:2011-05-20 Online:2011-06-07
Supported by:
The National Basic Research Program of China (2010CB227201); National Natural Science Foundation of China (50972165)

摘要/Abstract

摘要： 以分析纯V₂O₅为原料, 利用双氧水还原的方法制备钒电解液, 并对五氧化二钒的溶解机理进行了研究. 通过UV-Vis光谱分析和ICP, 对钒电解液在电解过程中钒离子的价态变化和浓度变化进行表征. 通过计算, 得到了钒电解液制备的反应焓变和吉布斯自由能变化, 结果表明: 生成硫酸氧钒的反应为放热反应, 并且该反应促进了五价钒离子的溶解. 将所制备的电解液组装成动态电池, 在电流密度为2.4 mA/cm²时, 电池的电流效率、电压效率、能量效率分别为93.6%、98.1%和91.9%, 充放电结果表明: 所制备的电解液具有很好的活性, 可以应用于钒电池.

关键词: 钒液流电池, 电解液, 热力学

Abstract: The vanadium solution was prepared by the mixture of hydrogen peroxide and vanadium pentoxide in sulphuric acid solution. The solubility mechanism of vanadium pentoxide was investigated. The valence and concentration change of vanadium solution were characterized by UV-Vis and ICP measurement in the following electrolysis procedure. △H and △G of the reaction were calculated. The results showed that the reaction was exothermic. The electrochemical activity was characterized by the charging and discharging experiment. And the results showed that the high current efficiency, voltage efficiency and energy efficiency of 93.6%, 98.1% and 91.9% were obtained at the current density of 2.4 mA/cm², respectively. This indicated that the prepared vanadium solution was suitable for vanadium redox-flow battery.

Key words: redox-flow battery, vanadium solution, thermodynamic

中图分类号:

O642

吴雄伟, 彭穗, 冯必钧, 山村朝雄, 矢野贵, 佐藤伊佐務, 刘素琴, 黄可龙. 钒电解液的绿色制备及其热力学分析[J]. 无机材料学报, 2011, 26(5): 535-539.

WU Xiong-Wei, PENG Sui, FENG Bi-Jun, Yamamura Tomoo, Takashi Yano, Satoh Isamu, LIU Su-Qin, HUANG Ke-Long. Preparation, Thermodynamic and Electrochemical Properties of Vanadium Solution[J]. Journal of Inorganic Materials, 2011, 26(5): 535-539.

参考文献

[1] Sum E, Skyllas-Kazacos M. A study of the V(II)/V(III) redox couple for redox flow cell application. Journal of Power Source, 1985, 15(5): 179-190.

[2] Sum E, Rychcik M, Skyllas-Kozacos M. Investigation of the V(V)/V(IV) system for use in the positive half-cell of a redox batery. Journal of Power Source, 1985, 16(8): 85-95.

[3] Zhao P, Zhang H M, Zhou H T, et al. Characteristics and performance of 10 kW class all-vanadium redox-flow battery stack. Journal of Power Source, 2006, 162(2): 1416-1420.

[4] Xi J Y, Wu Z H, Qiu X P, et al. Nafion/SiO2 hybid membrane for vanadium redox flow battery. Journal of Power Source, 2007, 166(2): 531-536.

[5] Kazacos M, Cheng M, Skyllas-Kazacos M. Vanadium redox cell electrolyte optimization studies. Journal of Applied Electrochemistry, 1990, 20(3): 463-467.

[6] Oriji G, Katayama Y, Miura T. Investigation on V(IV)/V(V) species in a vanadium redox flow battery. Journal of Electrochimica Acta, 2004, 49(19): 3091-3095.

[7] Lu X Q. Spectroscopic study of vanadium(V) precipitation in the vanadium redox cell electrolyte. Journal of Electrochemica Acta, 2001, 46(28): 4281-4287.

[8] Oriji G, Katayama Y, Miura T. Investigations on V(IV)/V(V) and V(II)/V(III) redox reactions by various electrochemical methods. Journal of Power Sourses, 2005, 139(1/2): 321-324.

[9] Zhong Z, Skyllas-Kazacos M. Electrochemical behaviour of V(V)/V(IV) redox couple at graphite electrodes. Journal of Power Sources, 1992, 39(1): 1-9.

[10] Rychcik M, Skyllas-Kazacos M. Characteristics of new all-vanadium redox flow battery. Journal of Power Sources, 1988, 22(1): 59-67.

[11] Abdus-Samad M, Skyllas-Kazacos M. Studies of Chemical Regeneration of Vanadium (V) for Vanadium Redox Battery. Proceedings 9th Australasian Electrochemical Conference, Wollongong, 1994, 4: 651-654.

[12] 彭声谦, 许国镇, 杨华栓, 等. 用从石煤中提取的V2O5制备钒电池用VOSO4的研究. 无机盐工业, 1997, 1: 3-6.

[13] 崔艳华, 孟凡明. 全钒离子液流电池的应用研究. 电源技术2000, 24(6): 356-358.

[14] Cheng M, Skyllas-Kazacos M. Evaluation of NH4VO3 derived electrolyte for vanadium redox flow battery. Journal of Power Sources, 1993, 45(1): 43-54.

[15] Kazacos M, Chen M, Skyllas-Kazacos M .Vanadium rdox flow cell electrolyte optimization studies. Journal of Applied electrochemistry, 1990, 20(3): 463-467.

[16] 廖世明. 柏谈论国外钒冶金. 北京: 冶金工艺出版社, 1985.

[17] 李晓刚. 10 kW 全钒氧化还原液流储能系统若干关键技术研究.长沙: 中南大学博士论文, 2006.

[18] 化学学会编. 化学便览. 日本仙台: 丸善株式会社, 1975.

钒电解液的绿色制备及其热力学分析

Preparation, Thermodynamic and Electrochemical Properties of Vanadium Solution

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	江依义, 沈旻, 宋半夏, 李南, 丁祥欢, 郭乐毅, 马国强. 双功能电解液添加剂对锂离子电池高温高电压性能的影响[J]. 无机材料学报, 2022, 37(7): 710-716.
[2]	蔚海浪, 曹学强, 邓龙辉, 蒋佳宁. LaMeAl₁₁O₁₉/YSZ热障涂层热力学性能和热循环寿命[J]. 无机材料学报, 2022, 37(12): 1259-1266.
[3]	吴静, 余立兵, 刘帅帅, 黄秋艳, 姜姗姗, ANTON Matveev, 王连莉, 宋二红, 肖蓓蓓. NiN₄/Cr修饰的石墨烯电化学固氮电极[J]. 无机材料学报, 2022, 37(10): 1141-1148.
[4]	陈雷雷, 邓子旋, 李勉, 李朋, 常可可, 黄峰, 都时禹, 黄庆. 新型MAX相的相图热力学研究[J]. 无机材料学报, 2020, 35(1): 35-40.
[5]	马国强, 蒋志敏, 陈慧闯, 王莉, 董经博, 张建君, 徐卫国, 何向明. 基于锂盐的新型锂电池电解质研究进展[J]. 无机材料学报, 2018, 33(7): 699-710.
[6]	孙青, 祁琪, 张俭, 潘方珍, 盛嘉伟. 磁性ZnFe₂O₄/埃洛石复合材料的结构及吸附性能研究[J]. 无机材料学报, 2018, 33(4): 390-396.
[7]	王舒玮, 胡和丰, 王德宇, 沈彩. 钠离子电池HOPG负极固体电解质界面膜的AFM研究[J]. 无机材料学报, 2017, 32(6): 596-602.
[8]	罗军明, 吴小红, 徐吉林. 电解液组分对TiC_P/Ti6Al4V复合材料微弧氧化膜耐蚀性及耐磨性影响[J]. 无机材料学报, 2017, 32(4): 418-424.
[9]	李玲, 肖俊莹, 崔米豆, 太优一, 庞永文, 韩松, 李晓苇. 高效CdS量子点敏化B/S共掺杂纳米TiO₂太阳能电池的制备及光电性能研究[J]. 无机材料学报, 2016, 31(6): 627-633.
[10]	何章兴, 刘剑蕾, 何震, 刘素琴. 全钒液流电池用碳纸电极掺氮改性的研究[J]. 无机材料学报, 2015, 30(7): 779-784.
[11]	彭犇, 邱桂博, 岳昌盛, 张梅, 郭敏. 一维β-SiAlON材料可控合成[J]. 无机材料学报, 2014, 29(7): 706-710.
[12]	邱锐浩, 李永祥, 张文清. 铋层状化合物相竞争关系的第一性原理热力学研究[J]. 无机材料学报, 2014, 29(11): 1156-1160.
[13]	王欢, 张华, 靳宏建, 赵文文. 燃料对甘氨酸-硝酸盐法合成Gd_0.8Sr_0.2CoO_3-δ阴极材料的影响[J]. 无机材料学报, 2013, 28(8): 818-824.
[14]	胡锋, 张羊换, 张胤, 侯忠辉1, 董忠平, 邓磊波. 球磨CeMg₁₂+100wt%Ni+Ywt%TiF₃(Y=0、3、5)合金微观结构及电化学储氢性能[J]. 无机材料学报, 2013, 28(2): 217-223.
[15]	胡菁菁, 李国然, 高学平. 锂/硫电池的研究现状、问题及挑战[J]. 无机材料学报, 2013, 28(11): 1181-1186.