无机材料学报

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退火处理对铅基弛豫型铁电体介电、压电性能的影响

夏峰; 姚熹   

  1. 西安交通大学电子材料与器件研究所; 西安 710049
  • 收稿日期:1998-03-16 修回日期:1998-04-21 出版日期:1999-02-20 网络出版日期:1999-02-20

退火处理对铅基弛豫型铁电体介电、压电性能的影响

XIA Feng; YAO Xi   

  1. Electronic Materials Research Laboratory; Xi an Jiaotong University Xi an 710049 China
  • Received:1998-03-16 Revised:1998-04-21 Published:1999-02-20 Online:1999-02-20

摘要: 铅基弛豫型铁电体的峰值介电常数和压电性能在退火后有较大提高.在PMN-PT陶瓷中,kp由58%提高到66%,峰值介电常数由30900提高到37200,d33达到530pC/N.在PZN-PT-BT陶瓷中,kp由35%提高到51%,峰值介电常数km由11400提高到29000,d33由347PC/N提高到624pC/N.这种改善可能与晶界玻璃相的消除以及畴壁运动等因素有关

关键词: 退火处理, 弛豫型铁电体, 介电、压电性能

Abstract: After thermal annealing, dielectric and piezoelectric properties of lead-based ferroelectric ceramics increase apparently. In PMN-PT system, E=37200, kp=66% d33=530pC/N were obtained;in PZN-PT-BT system, m=29000, kp=51% d33 =624pC/N were obtained. Thermal annealing isa good way to improve the dielectric and piezoelectric properties of lead-based ferroelectric ceramics, and this effect can be attributed to the grain boundary layer and domain wall motion in thesematerials.

Key words: thermal annealing, relaxor ferroelectrics, dielectric and piezoelectric properties

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