无机材料学报

• 研究论文 • 上一篇    下一篇

气-液界面非担载SiO2无机膜的仿生制备

王一平; 朱丽; 李韡; 郭翠梨   

  1. 天津大学化工学院 天津 300072
  • 收稿日期:2000-12-28 修回日期:2001-03-19 出版日期:2002-01-20 网络出版日期:2002-01-20

Biomimetic Synthesis of Free-standing Silica Membranes at the Air-Water Interface

WANG Yi-Ping; ZHU Li; LI Wei; QUO Cui-Li   

  1. School of Chemical Engineering; Tianjin University; Tianjin 300072; China
  • Received:2000-12-28 Revised:2001-03-19 Published:2002-01-20 Online:2002-01-20

摘要: 利用有机大分子CTAB的自组装体为模板来调制正硅酸乙酯(TEOS)的水解缩聚,于气-液界面上制备出非担载的SiO无机膜.对取膜时间进行了选择,考察了仿生制备SiO膜过程中物料配比对成膜质量的影响,对其进行了优化。由CTAB极性头基排列而成的六边形区域聚集于溶液表面,TEOS在其内部的水解缩聚及随后的层层复制过程形成了仿生合成膜的空间网络结构.

关键词: 仿生合成, SiO2膜, 无机膜, 复制

Abstract: Free-standing silica membranes were prepared at the air-water interface by biomimetic synthesis technology
from the hydrolysis of tetraethyoxysilane (TEOS) under the templating of assemblies of cetyltrimethylammonium bromide (CTAB). Time was chosen, the
material ratio used in the membrane-growing process that determined the qualities of membranes was optimized. Membrane formation can be considered to
involve polymerization of silicates in surfactant head group regions of a hexagonal mesophase that is concentrated at the liquid surface overstructure.

Key words: biomimetic synthesis, silica membrane, inorganic membrane, replicate

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