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氯化镁介质中PAA在Al2O3表面吸附作用的研究

孙静; 高濂   

  1. 中国科学院上海硅酸盐研究所高性能陶瓷与超微结构国家重点实验室 上海 200050
  • 收稿日期:2001-02-22 修回日期:2001-05-10 出版日期:2002-01-20 网络出版日期:2002-01-20

Adsorption Study of PAA onto Alumina Powder in Magnesium Chloride Solutions

SUN Jing; GAO Lian   

  1. State Key Lab of High Performance Ceramics and Superfine Microstructure; Shanghai Institute of Ce- ramics; Chinese Academy of Sciences; Shanghai 200050; China
  • Received:2001-02-22 Revised:2001-05-10 Published:2002-01-20 Online:2002-01-20

摘要: 研究了氯化镁介质中分散剂聚丙烯酸在氧化铝表面的吸附情况.发现盐浓度和PH对吸附曲线均有显著影响.与氯化钠介质中的吸附情况相比,镁离子的存在使PAA的吸附量明显提高,当PAA加入浓度为1570mg/L时,对应吸附曲线的最大值.镁离子与聚丙烯酸形成络合聚合物吸附在氧化铝表面.

关键词: MgCl2介质, PAA, Al2O3粉体, 吸附作用

Abstract: The paper presents the results on the adsorption behaviour of polyacrylic acid onto alumina with the presence of magnesium ions. Both the salt concentration and pH have great influence on the adsorption isotherms. Comparing with the adsorption behaviour in sodium chlo- ride solution, magnesium ions can enhance the adsorption amount obviously. Magnesium ions are co-adsorbed onto alumina powders as a complex with PAA.

Key words: magnesium chloride solution, alumina, PAA, adsorption behaviour

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