孔结构可控的网眼多孔陶瓷的制备

无机材料学报

孔结构可控的网眼多孔陶瓷的制备

朱新文; 江东亮; 谭寿洪; 张兆泉

中国科学院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室上海 200050

收稿日期:2001-02-16 修回日期:2001-03-15 出版日期:2002-01-20 网络出版日期:2002-01-20

Preparation of Reticulated Porous Ceramics with a Controlled Pore Structure

ZHU Xin-Wen; JIANG Dong-Liang; TAN Shou-Hong; ZHANG Zhao-Quan

State Key Lab of High Performance Ceramics and Superfine Microstructure; Shanghai Institute of Ce-ramics; Chinese Academy of Sciences; Shanghai 200050; China

Received:2001-02-16 Revised:2001-03-15 Published:2002-01-20 Online:2002-01-20

摘要/Abstract

摘要： 采用一种具有三维网状结构和贯通气孔的有机泡沫体作为载体，首先利用有机泡沫浸渍工艺制备出高气孔率且几乎没有堵孔的网眼素坯，经过排塑、预烧处理获得具有一定强度的预制体．由于未经烧结，预制体的孔筋呈疏松多孔结构．利用粘度较低、流动性很好的浆料对预制体进行涂覆处理．结果表明：通过这种处理，孔筋上的裂纹被消除，非常细的孔筋被避免，孔筋厚度比较均匀，从而获得了结构非常均匀的网眼陶瓷．相对密度、孔筋厚度、孔径大小可以根据徐覆次数来调节．随着涂覆次数的增加，孔径减小，孔筋厚度增加，相对密度也增加．本工作为网眼陶瓷孔结构的精确设计提供了一种新工艺，对于优化其力学性能、渗透率等性能具有重要意义．

关键词: 多孔陶瓷, 结构, 浆料, 涂覆

Abstract: A polymeric sponge with interconnected pores in all three dimensions was chosen to prepare firstly the reticulated preform by the replication process. After the
polymeric sponge was burned out, the reticulated preform was presintered to obtain enough operating strength. The struts of the reticulated preform exhibit porous
microstructure, which is beneficial to coating of the slurry on them. The coating treatment was conducted by the thinner slurry on the reticulated preform. The
typical flaws such as longitudinal strut cracks were eliminated by recoating process; additionally, very thin struts were avoided by coating. The reticulated
ceramics with a very uniform macrostructure was produced by recoating process and few filled cells were invisible. The effects of coating numbers on the pore
size, strut thickness and relative density were investigated in detail. This work has developed successfully an innovative approach to precisely control the macrostructure
for the reticulated ceramics, which is valuable to predict and optimize their properties such as mechanical properties and permeability.

Key words: porous ceramics, macrostructure, slurry, coating

中图分类号:

TM285

朱新文,江东亮,谭寿洪,张兆泉. 孔结构可控的网眼多孔陶瓷的制备[J]. 无机材料学报.

ZHU Xin-Wen,JIANG Dong-Liang,TAN Shou-Hong,ZHANG Zhao-Quan. Preparation of Reticulated Porous Ceramics with a Controlled Pore Structure[J]. Journal of Inorganic Materials.

[1]	孙强强, 陈子璇, 杨子玥, 王毅梦, 曹宝月. 金属镍铜负载钒氧化物的高效电解产氢性能[J]. 无机材料学报, 2023, 38(6): 647-655.
[2]	吴锐, 张敏慧, 金成韵, 林健, 王德平. 光热核壳TiN@硼硅酸盐生物玻璃纳米颗粒的降解和矿化性能[J]. 无机材料学报, 2023, 38(6): 708-716.
[3]	贺丹琪, 魏明旭, 刘蕤之, 汤志鑫, 翟鹏程, 赵文俞. 一步法制备重费米子YbAl₃热电材料及其性能提升[J]. 无机材料学报, 2023, 38(5): 577-582.
[4]	马晓森, 张丽晨, 刘砚超, 汪全华, 郑家军, 李瑞丰. 13X@SiO₂合成及其甲苯吸附性能[J]. 无机材料学报, 2023, 38(5): 537-543.
[5]	吴爽, 苟燕子, 王永寿, 宋曲之, 张庆雨, 王应德. 高温热处理对国产KD-SA型SiC纤维组成结构与力学性能的影响[J]. 无机材料学报, 2023, 38(5): 569-576.
[6]	张万文, 罗建强, 刘淑娟, 马建国, 张小平, 杨松旺. 氧化锆间隔层的低温喷涂制备及其三层结构钙钛矿太阳能电池应用性能[J]. 无机材料学报, 2023, 38(2): 213-218.
[7]	王士维. 基于疏水作用的陶瓷浆料自发凝固成型研究进展[J]. 无机材料学报, 2022, 37(8): 809-820.
[8]	柳琪, 朱璨, 谢贵震, 王俊, 张东明, 邵刚勤. Ce掺杂SrMgF₄超结构多晶体的吸收/光致发光光谱[J]. 无机材料学报, 2022, 37(8): 897-902.
[9]	欧阳琴, 王艳菲, 徐剑, 李寅生, 裴学良, 莫高明, 李勉, 李朋, 周小兵, 葛芳芳, 张崇宏, 何流, 杨磊, 黄政仁, 柴之芳, 詹文龙, 黄庆. 核用碳化硅纤维增强碳化硅复合材料研究进展[J]. 无机材料学报, 2022, 37(8): 821-840.
[10]	程玮杰, 王明磊, 林国强. 电弧离子镀CrAlN-DLC硬质复合薄膜的成分、结构与性能[J]. 无机材料学报, 2022, 37(7): 764-772.
[11]	文志勤, 黄彬荣, 卢涛仪, 邹正光. 压力对PbTiO₃结构和热物性质影响的第一性原理研究[J]. 无机材料学报, 2022, 37(7): 787-794.
[12]	迟聪聪, 屈盼盼, 任超男, 许馨, 白飞飞, 张丹洁. SiO₂@Ag@SiO₂@TiO₂核壳结构的制备及其光催化降解性能[J]. 无机材料学报, 2022, 37(7): 750-756.
[13]	徐谱昊, 张相召, 刘桂武, 张明芬, 桂新易, 乔冠军. Al-Ti合金钎焊SiC陶瓷接头界面微观结构与力学性能[J]. 无机材料学报, 2022, 37(6): 683-690.
[14]	洪督, 牛亚然, 李红, 钟鑫, 郑学斌. 等离子喷涂TiC-Graphite复合涂层摩擦磨损性能[J]. 无机材料学报, 2022, 37(6): 643-650.
[15]	关旭峰, 李桂芳, 卫云鸽. Na_1-_xM_xCaEu(WO₄)₃ (M=Li, K)红色荧光粉的微观结构与热猝灭特性研究[J]. 无机材料学报, 2022, 37(6): 676-682.