无机材料学报

• 研究论文 • 上一篇    下一篇

一种低烧、低介、高频多层片式电感用的介质材料

罗凌虹1,2; 周和平1; 彭榕1; 乔梁1   

  1. 1. 清华大学材料科学与工程系新型陶瓷与精细工艺国家重点实验室, 北京 100084; 2. 景德镇陶瓷学院材料工程系, 景德镇 333001
  • 收稿日期:2001-05-11 修回日期:2001-06-11 出版日期:2002-05-20 网络出版日期:2002-05-20

Low-T Sintering, Low-Dielectric Materials for High Frequency Multilayer Chip Inductors

LUO Ling-Hong1,2, ZHOU He-Ping1, PENG Rong1, QIAO Liang1   

  1. 1. State Key Lab of New Ceramic and Fine Processing, Department of Materials Science and Engineering Tsinghua University, Beijing 100084, China; 2. Dempartment of Materials Engineering, Jing-De-Zhen Ceramics Institure, Jingdezhen 333001, China
  • Received:2001-05-11 Revised:2001-06-11 Published:2002-05-20 Online:2002-05-20

摘要: 利用复合结构原理,研制出“硼硅玻璃+α-石英+硅酸锌”系低烧低介陶瓷材料,利用XRD、HP4194频谱仪、SEM分析了该材料的晶相组成、介电性能及显微结构.结果表明:在高频下,该材料具有很低的介电常数(=4~5,1MHz)和很低的介电损耗(tanδ<0.001,1MHz);同时能在低于900℃温度下烧结.该材料是一种理想的适用于高频(1GHz以上)多层片式电感(MLCIs)元件用的介质材料.同时得出:在该组成中,硼硅玻璃重烧结的过程中有方石英析出;少量硅酸锌由于锌离子进入玻璃中而转变为亚硅酸锌;硅酸锌在该组成中有助烧结的作用,该材料介电性能随频率的变化与德拜方程的描述基本吻合.

关键词: “硼硅玻璃+α-石英+硅酸锌”, 介质材料, 高频MLCIs

Abstract: The low temperature sintering and low dielectric properties ceramic materials of “borosilicate glass+
alpha-quartz+zinc silicate” system were prepared by applying the principle of the componund structure. The crystal phases, dielectric properties and
microstructure of the all sintering samples were analyzed by X-ray diffraction (XRD), HP4194ALCR analyzer and scanning electron microscopy
(SEM) respectively. The results show these materials possess very low dielectric constant (K=4~5, 1MHz)and very low dissipation factor
(tanδ<0. 001, 1MHz)in high frequencies. And they can be sintered below 900℃. These materials are promising dielectric materials
for high frequencies(≥1GHz) mulitlayer chip inductors (MLCIs). In the mean while, new crystalline phase of cristobalite is formed during
re-sintering the borosilicate glass and ZnSiO_3 phase is formed from zinc silicate visa zinc ions melting into the glass net. Zinc silicate
phase is of an aid-sintering function. The changes of dielectric properties of the samples with frequencies are fit with Debye equation.

Key words: borosilicate glass+alpha quartz+zinc silicate ", dielectric materials, high frequency MLCIs

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