无机材料学报

• 研究论文 • 上一篇    下一篇

非晶金刚石薄膜的拉曼光谱研究

陈弟虎1; 魏爱香1,2; 周友国2; 范家海2; 杨增红2; 彭少麒1   

  1. 中山大学物理系,广州 510275; 2. 海军广州舰艇学院, 广州 510431
  • 收稿日期:1999-03-02 修回日期:1999-05-04 出版日期:2000-02-20 网络出版日期:2000-02-20

Raman Spectroscopy of Amorphous Diamond Films

CHEN Di-Hu1; WEI Ai-Xiang1,2; ZHOU You-Guo2; FAN Jia-Hai2; YANG Zeng-Hong2; PENG Shao-Qi1   

  1. 1.Department of Physics; Zhongshan University; Guangzhou 510275; China; 2. Department of Physics; Guangzhou Naval Academy; Guangzhou 510431; China
  • Received:1999-03-02 Revised:1999-05-04 Published:2000-02-20 Online:2000-02-20

摘要: 碳离子的能量是影响非晶金刚石薄膜结构和性质最关键的工艺参数.采用磁过滤真空溅射离子技术,研究不同衬底偏压(即不同碳离子能量)下制备的非晶金刚石薄膜的拉曼光谱和表面形貌.结果表明:-50V≤≤-10V时,样品表面均匀、光滑,拉曼谱是对称且很宽的散射带;>-10V或<-50V时,已有晶团出现,表面粗糙度明显增加,拉曼谱明显地分裂为1580cm-1的G带和1350cm-1带.

关键词: 非晶金刚石薄膜, 拉曼光谱, 表面形貌

Abstract: The ion energy is a crucial parameter for amorphous diamond films deposition. Amorphous diamond
films (a-D) were prepared by magnetic field filtered plasma stream system. The Raman spectroscopy and surface morphology of a-D films deposited at various substrate bias voltages Vb were studied. The
results show that a-D films, deposited at Vb in the range from --10V to --50V, have a single and nearly symmetric very broad Raman
peak range from 1200cm-1 to 1800cm-1. The surface morphology of these films is very smooth and uniform. However, for samples deposited
at Vb>-10V or Vb<-50V, the Raman spectra exhibit two broad peaks centered approximately at 1350cm-1(D peak) and 1580cm-1(G peak), and the surface roughness will be increases.

Key words: amorphous diamond films, Raman spectra, surface morphology

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