Journal of Inorganic Materials ›› 2022, Vol. 37 ›› Issue (5): 547-553.DOI: 10.15541/jim20210311
• RESEARCH ARTICLE • Previous Articles Next Articles
WANG Hongli1(), WANG Nan1, WANG Liying1, SONG Erhong2(
), ZHAO Zhankui1(
)
Received:
2021-05-17
Revised:
2021-07-12
Published:
2022-05-20
Online:
2021-07-12
Contact:
SONG Erhong, associate professor. E-mail: ehsong@mail.sic.ac.cn;ZHAO Zhankui, professor. E-mail: zhaozk@ccut.edu.cn
About author:
WANG Hongli (1989-), female, associate professor. E-mail:wanghongli@ccut.edu.cn
Supported by:
CLC Number:
WANG Hongli, WANG Nan, WANG Liying, SONG Erhong, ZHAO Zhankui. Hydrogen Generation from Formic Acid Boosted by Functionalized Graphene Supported AuPd Nanocatalysts[J]. Journal of Inorganic Materials, 2022, 37(5): 547-553.
Fig. 2 TEM images, XRD pattern and EDX spectrum of Au0.3Pd0.7/PEI-rGO (a-b) TEM images and (c)HRTEM image for Au0.3Pd0.7/PEI-rGO with inset in (b) showing corresponding histogram of particle size distribution, (d) XRD pattern and (e) EDX pattern for Au0.3Pd0.7/PEI-rGO
Fig. 3 XPS spectra of Au0.3Pd0.7/PEI-rGO and Au0.3Pd0.7/rGO (a) XPS total spectra for (1) Au0.3Pd0.7/rGO and (2) Au0.3Pd0.7/PEI-rGO; (b) High resolution XPS spectra of N1s for Au0.3Pd0.7/PEI-rGO; (c) Au4f, (d) Pd3d XPS spectra for (1) Au0.3Pd0.7/PEI-rGO and (2) Au0.3Pd0.7/rGO
Fig. 4 Comparison of the catalytic performances for hydrogen evolution from FA dehydrogenation reaction of Au0.3Pd0.7/PEI-rGO, Au0.3Pd0.7/rGO and Au0.3Pd0.7 catalysts (a) Volume of gas versus time for the dehydrogenation of FA (1 mol/L, 5 mL) catalyzed by (1) Au0.3Pd0.7/PEI-rGO, (2) Au0.3Pd0.7/rGO and (3) Au0.3Pd0.7; (b) Corresponding TOF values
Catalyst | Temperature/K | ncatalyst/nFA | TOF/(molH2∙ molcatalyst-1∙h-1) |
---|---|---|---|
Pd-NPs@TA-CoP[ | 328 | 0.013 | 233.0a |
Pd@ED/Cr-MIL-101[ | 328 | 0.003 | 583.0b |
Ni0.4Pd0.6/NH2-N-rGO[ | 298 | 0.020 | 954.3a |
Pd0.7Ag0.3/CeOx-NPC[ | 323 | 0.008 | 1101.9a |
Pd@TB-POP[ | 323 | 0.100 | 1344.0b |
Pd/ImIP-2[ | 323 | 0.008 | 1593.0b |
AuPd/n-CNS[ | 333 | 0.020 | 1896.0a |
PdAg-CeO2[ | 303 | 0.033 | 2272.8a |
Au0.3Pd0.7/PEI-rGO | 323 | 0.020 | 2357.5a |
Pd/MSC-30[ | 323 | 0.013 | 2623.0a |
Pd-Co2P/NPC[ | 323 | 0.026 | 2980.0b |
Table 1 TOF of different catalysts for FA dehydrogenation
Catalyst | Temperature/K | ncatalyst/nFA | TOF/(molH2∙ molcatalyst-1∙h-1) |
---|---|---|---|
Pd-NPs@TA-CoP[ | 328 | 0.013 | 233.0a |
Pd@ED/Cr-MIL-101[ | 328 | 0.003 | 583.0b |
Ni0.4Pd0.6/NH2-N-rGO[ | 298 | 0.020 | 954.3a |
Pd0.7Ag0.3/CeOx-NPC[ | 323 | 0.008 | 1101.9a |
Pd@TB-POP[ | 323 | 0.100 | 1344.0b |
Pd/ImIP-2[ | 323 | 0.008 | 1593.0b |
AuPd/n-CNS[ | 333 | 0.020 | 1896.0a |
PdAg-CeO2[ | 303 | 0.033 | 2272.8a |
Au0.3Pd0.7/PEI-rGO | 323 | 0.020 | 2357.5a |
Pd/MSC-30[ | 323 | 0.013 | 2623.0a |
Pd-Co2P/NPC[ | 323 | 0.026 | 2980.0b |
Fig.5 (a) Volume of gas versus time for the dehydrogenation of FA at different temperatures over Au0.3Pd0.7/PEI-rGO catalyst; (b) Arrhenius plot (lnTOF versus 1/T) for Au0.3Pd0.7/PEI-rGO; (c) Volume of gas versus time for the dehydrogenation of FA at different ratios of AuxPd1-x/PEI-rGO (x=0, 0.1, 0.3, 0.7, 0.9, 1.0) at 323 K; (d) Durability tests of Au0.3Pd0.7/PEI-rGO towards the decomposition of FA (1.0 mol/L, 5.0 mL)
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