Synthesis and Evaluation of Ca-doped Sr2Fe1.5Mo0.5O6-δ as Symmetrical Electrodes for High Performance Solid Oxide Fuel Cells

doi:10.15541/jim20190067

Abstract

Abstract:

A series of Ca-substituted Sr₂Fe_1.5Mo_0.5O_6-_δ oxides, Sr_2-_xCa_xFe_1.5Mo_0.5O_6-_δ (SCFMO, x=0, 0.2, 0.4 and 0.6), were synthesized and evaluated as potential electrodes for symmetrical solid oxide fuel cells. X-ray diffraction examination showed that all samples maintained cubic perovskite structure in both air and wet hydrogen atmospheres. Temperature programmed reduction measurements indicated that the Ca ²⁺ substitution promoted the catalytic activity of SCFMO toward oxygen evolution reactions. Symmetrical anode fuel cell measurements showed the lowest polarization resistance in humidified hydrogen emerged at x=0.6. Single cells-SC_0.6FMO|La_0.9Sr_0.1Ga_0.8Mg_0.2O₃(LSGM)|SC_0.6FMO, fabricated via tape-casting and impregnation methods, produced peak power densities of 1.05 W·cm ^-2 at 800 ℃ and 0.41 W·cm ^-2 at 650 ℃ when operating on hydrogen fuels and air oxidants. These results demonstrate SC_0.6FMO is a potential electrode material for symmetrical solid oxide fuel cells.

Key words: Symmetrical Solid Oxide Fuel Cells, perovskite, electrode materials

CLC Number:

TQ174

XIA Tian, MENG Xie, LUO Ting, ZHAN Zhong-Liang. Synthesis and Evaluation of Ca-doped Sr₂Fe_1.5Mo_0.5O_6-_δ as Symmetrical Electrodes for High Performance Solid Oxide Fuel Cells[J]. Journal of Inorganic Materials, 2019, 34(10): 1109-1114.

Figures/Tables 6

Fig. 1 XRD patterns of Sr2-xCaxFe1.5Mo0.5O6-δ powders synthetized in air (a) and reduced in humidified hydrogen (b) at 800 ℃ for 4 h; (c) Magnified view of the diffraction peak at 67.5°

Fig. 2 Measured H2-TPR profiles for Sr2-xCaxFe1.5Mo0.5O6-δ powders with a ramp rate of 10 ℃·min-1

Fig. 3 Cross-sectional SEM micrographs showing impregnated fuel cells (a) Low magnification; (b) High magnification

Fig. 4 (a) EIS plots of the Sr2-xCaxFe1.5Mo0.5O6-δ symmetrical cells measured in humidified hydrogen at 800 ℃, and (b) Arrhenius plots of the anode polarization resistances over the temperature range of 650-800 ℃

Fig. 5 (a) EIS plots of the Sr2-xCaxFe1.5Mo0.5O6-δ symmetrical cells measured in air at 800 ℃, and (b) Arrhenius plots of the cathode polarization resistances over the temperature range of 650-800 ℃

Fig. 6 (a) Voltage and power density versus current density for a symmetrical fuel cell with Sr2-xCaxFe1.5Mo0.5O6-δ(x=0.6) electrode measured in humidified hydrogen fuel and dry air over the temperature range of 650-800 ℃; (b) Nyquist plots of impedance data measured at open circuits; (c) Maximum power densities of the symmetrical SCFMO electrode cells at different Ca2+ substitutions over the temperature range of 650-800 ℃

References 25

[1]	ORMEROD R M . Solid oxide fuel cells. Chemical Society Reviews, 2003,32(1):17-28.
[2]	MINH N Q . Solid oxide fuel cell technology—features and applications. Solid State Ionics, 2004,174(1):271-277.
[3]	IRVINE J T S, CONNOR P . SOFC Facts and Figures: Past Present and Future Perspectives for SOFC Technologies. London: Springer London, 2013.
[4]	STEELE B C H, HEINZEL A . Materials for fuel-cell technologies. Nature, 2001,414:345-352.
[5]	CARLOS RUIZ-MORALES J, MARRERO-LOPEZ D, CANALES-VAZQUEZ J , et al. Symmetric and reversible solid oxide fuel cells.RSC Adv., 2011,1(8):1403-1414.
[6]	SU C, WANG W, LIU M , et al. Progress and prospects in symmetrical solid oxide fuel cells with two identical electrodes.Advanced Energy Materials, 2015,5(14):1500188.
[7]	DOS SANTOS-GÓMEZ L, PORRAS-VÁZQUEZ J M, LOSILLA E R , et al. Ti-doped SrFeO₃ nanostructured electrodes for symmetric solid oxide fuel cells.RSC Adv., 2015,5(130):107889-107895.
[8]	BIAN L, DUAN C, WANG L , et al. Ce-doped La_0.7Sr_0.3Fe_0.9Ni_0.1O₃-_δ as symmetrical electrodes for high performance direct hydrocarbon solid oxide fuel cells.Journal of Materials Chemistry A, 2017,5(29):15253-15259.
[9]	LIN B, WANG S, LIU X , et al. Simple solid oxide fuel cells.Journal of Alloys and Compounds, 2010,490(1):214-222.
[10]	BASTIDAS D M, TAO S ,IRVINE J T S. A symmetrical solid oxide fuel cell demonstrating redox stable perovskite electrodes. J. Mater. Chem., 2006,16(17):1603-1605.
[11]	CHEN M, PAULSON S, THANGADURAI V , et al. Sr-rich chromium ferrites as symmetrical solid oxide fuel cell electrodes.Journal of Power Sources, 2013,236:68-79.
[12]	CANALES-VÁZQUEZ J, RUIZ-MORALES J C, MARRERO-LÓPEZ D , et al. Fe-substituted (La,Sr)TiO₃ as potential electrodes for symmetrical fuel cells (SFCs).Journal of Power Sources, 2007,171(2):552-557.
[13]	MARTíNEZ-CORONADO R, AGUADERO A, PÉREZ-COLL D , et al. Characterization of La_0.5Sr_0.5Co_0.5Ti_0.5O₃-_δ as symmetrical electrode material for intermediate-temperature solid-oxide fuel cells.International Journal of Hydrogen Energy, 2012,37(23):18310-18318.
[14]	FERNANDEZ-ROPERO A J, PORRAS-VAZQUEZ J M, CABEZA A , et al. High valence transition metal doped strontium ferrites for electrode materials in symmetrical SOFCs.J. Power Sources, 2014,249:405-413.
[15]	LIU Q, DONG X, XIAO G , et al. A novel electrode material for symmetrical SOFCs.Advanced Materials, 2010,22(48):5478-5482.
[16]	MENG X, LIU X J, DA H , et al. Symmetrical solid oxide fuel cells with impregnated SrFe_0.75Mo_0.25O₃-_δ electrodes.J. Power Sources, 2014,252:58-63.
[17]	GAO J, MENG X, LUO T , et al. Symmetrical solid oxide fuel cells fabricated by phase inversion tape casting with impregnated SrFe_0.75Mo_0.25O₃-_δ(SFMO) electrodes.International Journal of Hydrogen Energy, 2017,42(29):18499-18503.
[18]	LIU F, ZHANG L, HUANG G , et al. High performance ferrite-based anode La_0.5Sr_0.5Fe_0.9Mo_0.1O₃-_δ for intermediate-temperature solid oxide fuel cell.Electrochimica Acta, 2017,255:118-126.
[19]	QIAO J, CHEN W, WANG W , et al. The Ca element effect on the enhancement performance of Sr₂Fe_1.5Mo_0.5O₆-_δ perovskite as cathode for intermediate-temperature solid oxide fuel cells.J. Power Sources, 2016. 331:400-407.
[20]	MENG X, HAN D, WU H , et al. Characterization of SrFe_0.75Mo_0.25O₃-_δ-La_0.9Sr_0.1Ga_0.8Mg_0.2O₃-_δ composite cathodes prepared by infiltration.Journal of Power Sources, 2014,246(Supplement C):906-911.
[21]	MUÑOZ-GARCÍA A B, BUGARIS D E, PAVONE M , et al. Unveiling structure-property relationships in Sr₂Fe_1.5Mo_0.5O₆-_δ, an electrode material for symmetric solid oxide fuel cells.Journal of the American Chemical Society, 2012,134(15):6826-6833.
[22]	XIAO G L, CHAO J, QING L , et al.. Ni modified ceramic anodes for solid oxide fuel cells.Journal of Power Sources, 2012,201:43-48.
[23]	WANG Y, LIU T, LI M , et al. Exsolved Fe-Ni nano-particles from Sr₂Fe_1.3Ni_0.2Mo_0.5O₆ perovskite oxide as a cathode for solid oxide steam electrolysis cells.Journal of Materials Chemistry A, 2016,4(37):14163-14169.
[24]	KUBO J, UEDA W . Catalytic behavior of AMoO _x(A=Ba, Sr) in oxidation of 2-propanol.Materials Research Bulletin, 2009,44(4):906-912.
[25]	HE B, ZHAO L, SONG S , et al. Sr₂Fe_1.5Mo_0.5O₆-_δ-Sm_0.2Ce_0.8O_1.9 composite anodes for intermediate-temperature solid oxide fuel cells.Journal of The Electrochemical Society, 2012,159(5):B619-B626.

Synthesis and Evaluation of Ca-doped Sr₂Fe_1.5Mo_0.5O_6-_δ as Symmetrical Electrodes for High Performance Solid Oxide Fuel Cells

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