Effect of Rare Earth Dopant on Thermal Stability and Structure of ZnO-B2O3-SiO2 Glass

doi:10.15541/jim20160509

Abstract

Abstract:

To investigate the effect of the lanthanides and non-lanthanides elements on the thermal stability and structure of ZnO-B₂O₃-SiO₂ glass, the crystallization behavior, thermal stability and structural changes of ZnO-B₂O₃-SiO₂ glass doped with La₂O₃and Y₂O₃ were characterized by the differential scanning calorimetry (DSC) and Fourier Transform Infrared spectroscope (FTIR). The results showed that when the La₂O₃ and Y₂O₃additions are more than 8mol% and 6mol%, respectively, the 60ZnO-30B₂O₃-10SiO₂ glass system begins to crystallize. When La₂O₃and Y₂O₃ additions are 4mol% and 2mol%, respectively, this glass is of the best thermal stability. According to the structure research, the network linking performance of this kind of glass can be improved by a small amount addition of rare earth oxide. In contrast, the network linking performance of this kind of glass can be decreased by rare earth oxide’s addition exceeding a certain threshold value.

Key words: ZnO-B₂O₃-SiO₂ glass, La₂O₃, Y₂O₃, thermal stability, structure

CLC Number:

TQ174

WANG Mi-Tang, FANG Long, LI Mei, LIU Zhao-Gang, HU Yan-Hong, ZHANG Xiao-Wei. Effect of Rare Earth Dopant on Thermal Stability and Structure of ZnO-B₂O₃-SiO₂ Glass[J]. Journal of Inorganic Materials, 2017, 32(6): 643-648.

Figures/Tables 10

Fig. 1 Pictures of different content of rare earth oxide doped glass samples

Fig. 2 DSC curve of glasses doped with REO

Table 1 Characteristic temperature of glasses doped with REO

Glass	T_g /℃	T_c /℃	T_p /℃	S
B0	570	699	727	6.3
L1	568	701	734	7.7
L2	565	692	728	8.1
L3	565	689	724	7.7
L4	565	695	728	7.6
Y1	573	708	739	7.3
Y2	575	715	744	7.1
Y3	576	724	750	6.7

Fig. 3 Thermal stability of glass vs. content of REO

Fig. 4 FT-IR spectra of glasses dopedwith REO

Fig. 5 Deconvoluted FT-IR spectra of B0

Fig. 6 Effect of REO on the peak position of Zn-O P1 in [ZnO4] tetrahedron

Table 2 Deconvoluted parameters of the FT-IR spectra of the glasses (the band centers C and the relative area A)

Glass	P1	P2		P3		P4		P7		P8
Glass	C	C	A	C	A	C	A	C	A	C	A
B0	580.4	693.2	21.9	837.3	6.1	914.6	30.4	1328.4	89.6	1464.8	25.0
L1	581.4	692.4	14.3	886.3	21.1	997.1	39.4	1343.3	36.6	1445.2	43.2
L2	581.8	695.8	15.0	870.0	13.8	965.5	41.3	1337.4	16.4	1431.7	56.1
L3	587.8	702.8	19.8	862.2	14.2	956.8	54.3	1331.2	33.8	1429.8	58.9
L4	584.9	704.3	18.9	851.4	10.0	943.2	50.1	1332.7	32.3	1430.2	49.5
Y1	585.3	692.3	9.9	883.3	17.2	988.3	33.1	1370.8	27.2	1473	43.1
Y2	585.9	696.7	18.5	871.9	15.4	965.4	41.2	1351.7	30.3	1450.2	43.0
Y3	588.3	700.4	15.2	867.7	12.4	958.7	37.2	1337.6	15.7	1433.4	59.1

Fig. 7 (a) Peak position of bending vibration of [BO3] P2 and stretching vibration of [BO4] P3 vs content of La2O3; (b) Peakposition of bending vibration of [BO3] P2 and stretching vibration of [BO4] P3 vs content of Y2O3.

Fig. 8 (a) N3 and N4 vs content of La2O3; (b) N3 and N4 vs content of Y2O3

References 32

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Effect of Rare Earth Dopant on Thermal Stability and Structure of ZnO-B₂O₃-SiO₂ Glass

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Glass	T_g /℃	T_c /℃	T_p /℃	S
B0	570	699	727	6.3
L1	568	701	734	7.7
L2	565	692	728	8.1
L3	565	689	724	7.7
L4	565	695	728	7.6
Y1	573	708	739	7.3
Y2	575	715	744	7.1
Y3	576	724	750	6.7

Glass	T_g /℃	T_c /℃	T_p /℃	S
B0	570	699	727	6.3
L1	568	701	734	7.7
L2	565	692	728	8.1
L3	565	689	724	7.7
L4	565	695	728	7.6
Y1	573	708	739	7.3
Y2	575	715	744	7.1
Y3	576	724	750	6.7

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Glass	T_g /℃	T_c /℃	T_p /℃	S
B0	570	699	727	6.3
L1	568	701	734	7.7
L2	565	692	728	8.1
L3	565	689	724	7.7
L4	565	695	728	7.6
Y1	573	708	739	7.3
Y2	575	715	744	7.1
Y3	576	724	750	6.7

Glass	T_g /℃	T_c /℃	T_p /℃	S
B0	570	699	727	6.3
L1	568	701	734	7.7
L2	565	692	728	8.1
L3	565	689	724	7.7
L4	565	695	728	7.6
Y1	573	708	739	7.3
Y2	575	715	744	7.1
Y3	576	724	750	6.7

Glass	T_g /℃	T_c /℃	T_p /℃	S
B0	570	699	727	6.3
L1	568	701	734	7.7
L2	565	692	728	8.1
L3	565	689	724	7.7
L4	565	695	728	7.6
Y1	573	708	739	7.3
Y2	575	715	744	7.1
Y3	576	724	750	6.7

Glass	T_g /℃	T_c /℃	T_p /℃	S
B0	570	699	727	6.3
L1	568	701	734	7.7
L2	565	692	728	8.1
L3	565	689	724	7.7
L4	565	695	728	7.6
Y1	573	708	739	7.3
Y2	575	715	744	7.1
Y3	576	724	750	6.7