Degradation Effect of Super Acid Modified Fe2O3-TiO2-N on Acrylic Acid under Visible Light

doi:10.15541/jim20140234

Abstract

Abstract:

Super acid modified Fe₂O₃-TiO₂-N was prepared by hydrolysis precipitation method and sulfuric acid impregnation method. X-ray diffraction (XRD) showed that the catalysts were anatase, Fe₂O₃ were highly decentralized in the catalysts with amorphous form, and modification of SO₄^2- inhibited grain growth. Ultraviolet-visible spectra (UV-Vis) showed that Fe and N co-doping made the visible light absorption to the red shift, and sulfuric acid impregnation treatment made the light absorption to the blue shift. Diffuse reflectance Fourier transform infrared (DRIFT-IR) spectra showed that sulfuric acid impregnation can improve the surface acidity of catalysts. X-ray photoelectron spectra (XPS) showed that the valence of S was +6 in the catalysts. Its photocatalytic activity on the degradation of acrylic acid under visible light was studied. The one hour degradation rate of super acid modified Fe₂O₃-TiO₂-N catalyst under visible light was improved 57% than that of the N-doping sample under the same condition.

Key words: co-doping, degradation, visible light, photocatalytic

CLC Number:

TQ174

HAN Zhi-Yue, DU Zhi-Ming, ZHANG Ying-Hao, ZHAO Lin-Shuang, CONG Xiao-Min. Degradation Effect of Super Acid Modified Fe₂O₃-TiO₂-N on Acrylic Acid under Visible Light[J]. Journal of Inorganic Materials, 2014, 29(10): 1110-1114.

Figures/Tables 11

Fig. 1 Catalytic reactor system for degradation of acrylic acid with visible lamp irradiation

Fig. 2 XRD patterns of the TiO2-N, Fe2O3-TiO2-N and Fe2O3- TiO2-N-SO42- powders

Fig. 3 XRD patterns of samples treated by sulfuric acid and calcined at different temperatures

Fig. 4 DRIFT spectroscopy associated with NH3 adsorption on catalysis with different concentrations of H2SO4

Fig. 5 S XPS patterns of Fe2O3-TiO2-N-SO42-

Fig. 6 N XPS patterns of Fe2O3-TiO2-N-SO42-

Fig. 7 Ti XPS patterns of Fe2O3-TiO2-N-SO42-

Fig. 8 UV-Vis absorption of different samples

Fig. 9 Degradation rate of acrylic acid with different catalysts

Fig. 10 Degradation rate of acrylic acid with different concentrations of sulfuric acid

Fig. 11 Degradation rate of acrylic acid with different calcination temperatures

References 11

[1]	FUJISHIMA A, HONDA K. Electrochemical photolysis of water at a semiconductor electrode. Nature, 1972, 238(5358): 37-38.
[2]	FUJISHIMA A, RAO T, TRYK D. Titanium dioxide photocatalysis. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2000, 1(1): 1-21.
[3]	ASAHI R, MORIKAWA T, OHWAKI T, et al. Visible-light photocatalysis in nitrogen-doped titanium oxides. Science, 2001, 293(5528): 269-271.
[4]	UMEBAYASHI T, YAMAKI T, ITOH H, et al. Band gap narrowing of titanium dioxide by sulfur doping. Applied Physics Letters, 2002, 81(3): 454-456.
[5]	YU J C, YU J G, HO W K, et al. Effects of F- doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chemistry of Materials, 2002, 14: 3808-3816.
[6]	SAKTHIVEL S, KISCH H. Daylight photocatalysis by carbon modified titanium dioxide. Angew. Chem. Int. Ed., 2003, 42(40): 4908-4911.
[7]	Mwangi I W, Ngila J C, Ndungu P, et al. Immobilized Fe (III)-doped titanium dioxide for photodegradation of dissolved organic compounds in water. Environmental Science and Pollution Research, 2013, 20(9): 6028-6038.
[8]	YALCIN Y, KILIC M, CINAR Z. Fe+3-doped TiO2: A combined experimental and computational approach to the evaluation of visible light activity. Applied Catalysis B: Environmental, 2010, 99(3/4): 469-477.
[9]	LEE SEUNG JOON, HAN SANG WOO, YOON MINJOONG, et al. Adsorption characteristics of 4-dimethylaminobenzoic acid on silver and titania: diffuse reflectance infrared Fourier transform spectro-scopy study. Vibrational Spectroscopy, 2000, 24(2): 265-275.
[10]	GOLE J L, STOUT J D, BURDA C, et al. Highly efficient formation of visible light tunable TiO2-xNx photocatalysts and their transformation at the nanoscale. The Journal of Physical Chemistry B, 2004, 108(4): 1230-1240.
[11]	IHARA T, MIYOSHI M, IRIYAMA Y, et al. Visible-light-active titanium oxide photocatalyst realized by an oxygen-deficient structure and by nitrogen doping. Applied Catalysis B: Environmental, 2003, 42: 403-409.

[1]	TUERHONG Munire, ZHAO Honggang, MA Yuhua, QI Xianhui, LI Yuchen, YAN Chenxiang, LI Jiawen, CHEN Ping. Construction and Photocatalytic Activity of Monoclinic Tungsten Oxide/Red Phosphorus Step-scheme Heterojunction [J]. Journal of Inorganic Materials, 2023, 38(6): 701-707.
[2]	WANG Lei, LI Jianjun, NING Jun, HU Tianyu, WANG Hongyang, ZHANG Zhanqun, WU Linxin. Enhanced Degradation of Methyl Orange with CoFe₂O₄@Zeolite Catalyst as Peroxymonosulfate Activator: Performance and Mechanism [J]. Journal of Inorganic Materials, 2023, 38(4): 469-476.
[3]	CHEN Ying, LUAN Weiling, CHEN Haofeng, ZHU Xuanchen. Multi-scale Failure Behavior of Cathode in Lithium-ion Batteries Based on Stress Field [J]. Journal of Inorganic Materials, 2022, 37(8): 918-924.
[4]	HONG Jiahui, MA Ran, WU Yunchao, WEN Tao, AI Yuejie. CoN_x/g-C₃N₄ Nanomaterials Preparation by MOFs Self-sacrificing Template Method for Efficient Photocatalytic Reduction of U(VI) [J]. Journal of Inorganic Materials, 2022, 37(7): 741-749.
[5]	AN Lin, WU Hao, HAN Xin, LI Yaogang, WANG Hongzhi, ZHANG Qinghong. Non-precious Metals Co_5.47N/Nitrogen-doped rGO Co-catalyst Enhanced Photocatalytic Hydrogen Evolution Performance of TiO₂ [J]. Journal of Inorganic Materials, 2022, 37(5): 534-540.
[6]	MA Hui, TAO Jianghui, WANG Yanni, HAN Yu, WANG Yabin, DING Xiuping. Gold Nanoparticles Supported on Silica & Titania Hybrid Mesoporous Spheres and Their Catalytic Performance Regulation [J]. Journal of Inorganic Materials, 2022, 37(4): 404-412.
[7]	CHEN Shikun, WANG Chuchu, CHEN Ye, LI Li, PAN Lu, WEN Guilin. Magnetic Ag₂S/Ag/CoFe_1.95Sm_0.05O₄ Z-scheme Heterojunction: Preparation and Its Photocatalytic Degradation Property [J]. Journal of Inorganic Materials, 2022, 37(12): 1329-1336.
[8]	GAO Wa, XIONG Yujie, WU Congping, ZHOU Yong, ZOU Zhigang. Recent Progress on Photocatalytic CO₂ Reduction with Ultrathin Nanostructures [J]. Journal of Inorganic Materials, 2022, 37(1): 3-14.
[9]	LI Tie, LI Yue, WANG Yingyi, ZHANG Ting. Preparation and Catalytic Properties of Graphene-Bismuth Ferrite Nanocrystal Nanocomposite [J]. Journal of Inorganic Materials, 2021, 36(7): 725-732.
[10]	LIU Fangfang, CHUAN Xiuyun, YANG Yang, LI Aijun. Influence of N/S Co-doping on Electrochemical Property of Brucite Template Carbon Nanotubes [J]. Journal of Inorganic Materials, 2021, 36(7): 711-717.
[11]	AN Weijia, LI Jing, WANG Shuyao, HU Jinshan, LIN Zaiyuan, CUI Wenquan, LIU Li, XIE Jun, LIANG Yinghua. Fe(III)/rGO/Bi₂MoO₆ Composite Photocatalyst Preparation and Phenol Degradation by Photocatalytic Fenton Synergy [J]. Journal of Inorganic Materials, 2021, 36(6): 615-622.
[12]	CAI Miao, CHEN Zihang, ZENG Shi, DU Jianghui, XIONG Juan. CuS Nanosheet Decorated Bi₅O₇I Composite for the Enhanced Photocatalytic Reduction Activity of Aqueous Cr(VI) [J]. Journal of Inorganic Materials, 2021, 36(6): 665-672.
[13]	XIONG Jinyan, LUO Qiang, ZHAO Kai, ZHANG Mengmeng, HAN Chao, CHENG Gang. Facilely Anchoring Cu nanoparticles on WO₃ Nanocubes for Enhanced Photocatalysis through Efficient Interface Charge Transfer [J]. Journal of Inorganic Materials, 2021, 36(3): 325-331.
[14]	XIA Zhaoyang, WANG Hui, FANG Jinghong, ZHANG Yang, WANG Chaoyue, HE Huan, NI Jinqi, SHI Yun, LI Qin, YU Jianding. Co Incorporation on Structure, Conductivity and Magnetism of GaFeO₃ [J]. Journal of Inorganic Materials, 2021, 36(3): 319-324.
[15]	DONG Zhengming, LI Xiu, CHEN Chen, CAO Minghe, YI Zhiguo. Photostriction of NBT-BNT Ceramics [J]. Journal of Inorganic Materials, 2021, 36(3): 277-282.

Degradation Effect of Super Acid Modified Fe₂O₃-TiO₂-N on Acrylic Acid under Visible Light

RichHTML

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

Figures/Tables 11

References 11

Related Articles 15

Recommended Articles

Metrics

Comments