Journal of Inorganic Materials ›› 2014, Vol. 29 ›› Issue (6): 667-672.DOI: 10.3724/SP.J.1077.2014.14039
• Orginal Article • Previous Articles
ZHANG Qing-Hua, HUI Hao-Hao, YANG Wei, WEI Yao-Wei, WANG Jian, XU Qiao
Received:
2014-01-17
Published:
2014-06-20
Online:
2014-05-27
CLC Number:
ZHANG Qing-Hua, HUI Hao-Hao, YANG Wei, WEI Yao-Wei, WANG Jian, XU Qiao. Sol-Gel Preparation of PHFBMA/PFG/Silica Coatings with Durable
Shortwave-band Antireflective Performance[J]. Journal of Inorganic Materials, 2014, 29(6): 667-672.
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Weight ratio of PFG to silica/% | Silica coatings | Viscosity of silica sols<br/>/ (×10-3, Pa•s) | Weight ratio of PHFBMA to silica/% | Silica coatings | Viscosity of silica sols<br/>/(×10-3, Pa•s) | ||
---|---|---|---|---|---|---|---|
Refractive index (n) | Thickness /nm | Refractive index (n) | Thickness /nm | ||||
0 | 1.226 | 64.2 | 1.52 | 6.8 | 1.245 | 65.6 | 1.53 |
13.2 | 1.263 | 67.6 | 1.53 | ||||
26.4 | 1.271 | 69.0 | 1.54 | ||||
1 | 1.212 | 75.4 | 1.56 | ||||
2 | 1.204 | 86.1 | 1.66 | ||||
4 | 1.195 | 98.7 | 1.75 | 6.8 | 1.203 | 59.1 | 1.37 |
13.2 | 1.210 | 61.4 | 1.44 | ||||
26.4 | 1.230 | 63.5 | 1.50 | ||||
6 | 1.177 | 106.9 | 2.05 |
Table 1 Refractive indices (at 365 nm) and thickness of the silica coatings and viscosity of the sols
Weight ratio of PFG to silica/% | Silica coatings | Viscosity of silica sols<br/>/ (×10-3, Pa•s) | Weight ratio of PHFBMA to silica/% | Silica coatings | Viscosity of silica sols<br/>/(×10-3, Pa•s) | ||
---|---|---|---|---|---|---|---|
Refractive index (n) | Thickness /nm | Refractive index (n) | Thickness /nm | ||||
0 | 1.226 | 64.2 | 1.52 | 6.8 | 1.245 | 65.6 | 1.53 |
13.2 | 1.263 | 67.6 | 1.53 | ||||
26.4 | 1.271 | 69.0 | 1.54 | ||||
1 | 1.212 | 75.4 | 1.56 | ||||
2 | 1.204 | 86.1 | 1.66 | ||||
4 | 1.195 | 98.7 | 1.75 | 6.8 | 1.203 | 59.1 | 1.37 |
13.2 | 1.210 | 61.4 | 1.44 | ||||
26.4 | 1.230 | 63.5 | 1.50 | ||||
6 | 1.177 | 106.9 | 2.05 |
Fig. 2 FIB-SEM images of the coatings (a) Pure silica coating with a magnification of 150,000; (b) 4wt% PFG-containing silica with a magnification of 150,000
Fig. 3 Surface morphologies of coatings (a) Pure silica coating; (b) 4wt% PFG containing silica coating; (c) 4wt% PFG containing silica coating modified by 26.4wt% of PHFBMA
Fig. 4 Transmittance spectra of AR coatings (a) Pure silica (1.65wt%) and silica with different content of PFG; (b) Pure silica (1.65wt%) with different content of PHFBMA; (c) 4wt% PFG containing silica with different content of PHFBMA
Fig. 7 Changes in maximum transmittance as function of test time (a) In a closed container with 75% relative humidity at 25℃; (b) In a vacuum chamber of 0.15 MPa
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