Journal of Inorganic Materials ›› 2012, Vol. 27 ›› Issue (2): 122-128.DOI: 10.3724/SP.J.1077.2012.00122
• Orginal Article • Previous Articles Next Articles
LI Lei1, ZHU Kai1, ZHANG Li1, CHEN Da-Zhou2
Received:
2011-01-18
Revised:
2011-04-17
Published:
2012-02-10
Online:
2012-01-05
CLC Number:
LI Lei, ZHU Kai, ZHANG Li, CHEN Da-Zhou. Preparation and Photophysical Properties of Materials Obtained by Co-intercalation of 4-MAA and 2-NSA into Mg-Al-LDH[J]. Journal of Inorganic Materials, 2012, 27(2): 122-128.
Add to citation manager EndNote|Ris|BibTeX
Sample (n4-MAA/n2-NSA in mixture of solution) | Composition |
---|---|
3:1 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.22 (2-NSA)0.10·0.67H2O |
2:1 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.17 (2-NSA)0.15·0.66H2O |
1:1 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.11 (2-NSA)0.21·0.67H2O |
1:2 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.08 (2-NSA)0.24·0.64H2O |
1:3 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.05 (2-NSA)0.27·0.63H2O |
Table 1 Chemical compositions of co-intercalation compounds
Sample (n4-MAA/n2-NSA in mixture of solution) | Composition |
---|---|
3:1 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.22 (2-NSA)0.10·0.67H2O |
2:1 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.17 (2-NSA)0.15·0.66H2O |
1:1 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.11 (2-NSA)0.21·0.67H2O |
1:2 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.08 (2-NSA)0.24·0.64H2O |
1:3 | [Mg 0.66 Al 0.34 (OH) 2] (4-MAA)0.05 (2-NSA)0.27·0.63H2O |
Anion | Calculated charges | ||
---|---|---|---|
O1 | O2 | O3 | |
4-MAA | -0.7533 | -0.7503 | -0.6669 |
2-NSA | -0.6939 | -0.7812 | -0.6903 |
Table 2 Calculated charges for O of 4-MAA and 2-NSA anions
Anion | Calculated charges | ||
---|---|---|---|
O1 | O2 | O3 | |
4-MAA | -0.7533 | -0.7503 | -0.6669 |
2-NSA | -0.6939 | -0.7812 | -0.6903 |
[1] | Khan A I, O’Hare D. Intercalation chemistry of layered double hydroxides: recent developments and applications. Journal of Materials Chemistry, 2002, 12: 3191-3198. |
[2] | Cavani F, Trifiro F, Vaccari A. Hydrotalcite-type anionic clays: preparation, properties and applications. Catalysis Today, 1991, 11(2): 173-301. |
[3] | 段 雪,张法智. 插层组装与功能材料. 北京: 化学工业出版社, 2007. |
[4] | Ogawa M, Kuroda K. Photofunctions of intercalation compounds. Chemical Reviews, 1995, 95(2): 399-438. |
[5] | Li L, Liu S J, Li B S, et al. Preparation and photochemical characterization of compounds by intercalation of organic UV absorbents into Zn-Al hydrotalcite-like compounds. Chinese Journal of Inorganic Chemistry, 2007, 23(3): 407-414. |
[6] | Tanaka T, Nishimoto S, Kameshima Y, et al. A novel nanocomposite material prepared by intercalating photoresponsive dendrimers into a layered double hydroxide. Journal of Solid State Chemistry, 2010, 183(3): 479-484. |
[7] | Wang Z L, Kang Z H, Wang E B, et al. Intercalation and photophysical properties of the tetra-(8-hydroxyquinolinato) boron complex and 3,3’,4,4’-benzophenone tetracarboxylic anion into Mg-Al layered double hydroxides. Inorganic Chemistry, 2006, 45(11): 4364-4371. |
[8] | Malherbe F, Besse J P. Investigating the effects of guest-host interactions on the properties of anion-exchanged Mg-Al hydrotalcites. Journal of Solid State Chemistry, 2000, 155(2): 332-341. |
[9] | Aloisi G G, Costantino U, Elisei F, et al. Preparation and photo-physical characterisation of nanocomposites obtained by intercalation and co-intercalation of organic chromophores into hydrotalcite-like compounds. Journal of Materials Chemistry, 2002, 12: 3316-3323. |
[10] | Latterini L, Nocchetti M, Aloisi G G, et al. Organized chromophores in layered inorganic matrices. Inorganica Chimica Acta, 2007, 360(3): 728-740. |
[11] | LI Lei, WEN Zheng, CHEN Da-Zhou, et al. Preparation and characterization of chromophores pillared Zn-Al-LDH. Journal of Inorganic Materials, 2009, 24(5): 1019-1024. |
[12] | LI Lei, ZHANG Li, CHEN Da-Zhou, et al. Preparation and photophysical properties of chromophores pillared Mg-Al-LDH. Journal of Inorganic Materials., 2010, 25(11): 1133-1138. |
[13] | 王宗明,何欣翔,孙殿卿. 实用红外光谱学, 2版. 北京: 石油工业出版社, 1990. |
[1] | ZHOU Xiong, FANG Lizhi, HUANG Shuangwu, XIA Haiping, HU Jianxu, ZHANG Jianli, CHEN Baojiu. Ultraviolet and Near-infrared Luminescence of Ce 3+/Yb 3+ Co-doping LiLuF4 Single Crystal [J]. Journal of Inorganic Materials, 2020, 35(5): 556-560. |
[2] | LI Sheng-Song, ZHENG Yong-Chao, MENG Shu-Lin, WU Li-Zhu, ZHONG Jin- Yi, ZHAO Chong-Lin. Core/Shell Quantum Dots and Au Nanoparticles Assembly for Effective Detection of Nerve Agent Mimic [J]. Journal of Inorganic Materials, 2019, 34(8): 893-898. |
[3] | SHI Zhong-Xiang, WANG Jing, GUAN Xin. Multicolor Upconversion Emission Tuning of NaY(WO4)2: Dy3+ via Er3+ Doping [J]. Journal of Inorganic Materials, 2018, 33(5): 521-527. |
[4] | YANG Guang-Wu, YANG Rui-Xia, ZHANG Shou-Chao, ZHU Fei. Ce Doping Concentration on Luminescence Property of YVO4:Ce3+ Crystals [J]. Journal of Inorganic Materials, 2016, 31(10): 1073-1080. |
[5] |
PENG Xia, LI Shu-Xing, LIU Xue-Jian, HUANG Yi-Hua, HUANG Zheng-Ren, LI Hui-Li.
Syntheses and Photoluminescence Properties of Eu2+/Tb3+ Doped Sr2Si5N8 Phosphors [J]. Journal of Inorganic Materials, 2015, 30(4): 397-400. |
[6] | LUO Jia-Liang, WU Yun-Tao, REN Guo-Hao. Luminescence Property and Energy Transfer of Ce3+, Eu3+ Co-doped Lu3Al5O12 Polycrystals [J]. Journal of Inorganic Materials, 2014, 29(11): 1211-1217. |
[7] | ZHANG Shou-Chao, RUAN Yong-Feng, JIA Guo-Zhi, FENG Zhi-Hui, LIU Zhi-Peng, PEI Li-Bin. Blue-emitting Properties of Ce3+ Doped YVO4 under Ultraviolet Excitation [J]. Journal of Inorganic Materials, 2014, 29(10): 1067-1072. |
[8] | WANG Sen, ZHOU Ya-Xun, DAI Shi-Xun, WANG Xun-Si, SHEN Xiang, CHEN Fei-Fei. Influence of High Phonon Energy Oxide on Spectroscopic Properties of Er3+/Ce3+ Co-doped Tellurite Glasses [J]. Journal of Inorganic Materials, 2012, 27(8): 865-870. |
[9] | WEI Shu-Lin, XU Yin-Sheng, ZHANG Pei-Qing, CHEN Fei-Fei, NIE Qiu-Hua, XU Tie-Feng, DAI Shi-Xun. 2.00 μm Emission Properties of Tm3+/Ho3+ Co-doped Chalcohalide Glasses [J]. Journal of Inorganic Materials, 2012, 27(7): 711-715. |
[10] | HU Yue-Bo1,2,3, QIU Jian-Bei2, ZHOU Da-Li1, YANG Zhen-Wen2, SONG Zhi-Guo2. Characteristics and Mechanism of Up-conversion Luminescence in Er3+/Yb3+/Tb3+ Co-doped Oxyfluorogermanate Glasses [J]. Journal of Inorganic Materials, 2010, 25(5): 551-556. |
[11] | LI Lei, ZHANG Li, CHEN Da-Zhou, TANG Hua. Preparation and Photophysical Properties?of Chromophores Pillared Mg-Al-LDH [J]. Journal of Inorganic Materials, 2010, 25(11): 1133-1138. |
[12] | LI Lei,WEN Zheng,CHEN Da-Zhou,TANG Hua. Preparation and Characterization of Chromophores Pillared Zn-Al-LDH [J]. Journal of Inorganic Materials, 2009, 24(5): 1019-1024. |
[13] | WANG Sheng,QIAN Qi,ZHANG Qin-Yuan,YANG Zhong-Min,JIANG Zhong-Hong. Gd3+-sensitized Tb3+-doped Scintillating Silicate Glasses [J]. Journal of Inorganic Materials, 2009, 24(4): 773-777. |
[14] | LI Wei-Nan,ZOU Kuai-Sheng,LU Min,XIANG Li-Bin. Properties of Up-conversion Emission of Er3+-doped Silicate Glasses [J]. Journal of Inorganic Materials, 2007, 22(1): 30-34. |
[15] | HONG Zhang-Lian,ZHANG Peng-Yue,HUANG Qiu-Ping,FAN Xian-Ping,WANG Min-Quan. Afterglow and Energy Transfer from Ti to Eu3+ in Y2O2S:0.03Eu,0.03Ti Phosphor [J]. Journal of Inorganic Materials, 2006, 21(2): 329-334. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||