Syntheses and Photoluminescence Properties of Eu2+/Tb3+ Doped Sr2Si5N8 Phosphors

doi:10.15541/jim20140374

Abstract

Abstract:

Eu²⁺/Tb³⁺ doped Sr₂Si₅N₈ phosphors were prepared by carbothermal reduction and nitridation method. The luminescence of Tb³⁺/Eu²⁺ co-doped Sr₂Si₅N₈ were investigated. The experimental results indicated that owing to spin-allowed f → d transition rule the four emission lines located at 490, 543, 585, and 623 nm which ascribed to the ⁵D₄→⁷F_j (j = 6, 5, 4, 3) transitions were observed under 330 nm excitation. No obvious changes in spectral line shape were observed for Sr₂Si₅N₈:Eu²⁺ co-doped with Tb³⁺. However, the emission intensity was improved by about 20% with Tb³⁺ doping concentration of x = 0.01 mainly because of the electric multipole energy transfer from Tb³⁺ to Eu²⁺.

Key words: alkaline-earth-silicon-nitrides, carbothermal reduction and nitridation method, luminescence, energy transfer

CLC Number:

O614

PENG Xia, LI Shu-Xing, LIU Xue-Jian, HUANG Yi-Hua, HUANG Zheng-Ren, LI Hui-Li. Syntheses and Photoluminescence Properties of Eu²⁺/Tb³⁺ Doped
Sr₂Si₅N₈ Phosphors[J]. Journal of Inorganic Materials, 2015, 30(4): 397-400.

Figures/Tables 3

References 23

[1]	TAKAHASHI K, HIROSAKI N, XIE R J, et al.Luminescence properties of blue LaxCe1-xAl(Si6-zAlz)(N10-zOz)(z~1) oxynitride phosphors and their application in white light-emitting diode.Appl. Phys. Lett., 2007, 91: 091923.
[2]	XIE R J, HIROSAKI N, YAMAMOTO Y, et al.Fluorescence of Eu2+ in strontium oxonitridoaluminosilicates (SiAlONS).J. Ceram. Soc. Jpn., 2005, 11(7): 462-465.
[3]	SUEHIRO T, HIROSAKI N, XIE R J, et al.Blue-emitting LaSi3N5:Ce3+ fine powder phosphor for UV-converting white light-emitting diodes.Appl. Phys. Lett., 2009, 95: 051903.
[4]	HIROSAKI N, XIE R J, INOUE K, et al.Blue-emitting AlN:Eu2+ nitride phosphor for field emission displays.Appl. Phys. Lett., 2007, 91: 061101.
[5]	INOUE K, HIROSAKI N, XIE R J, et al.Highly efficient and thermally stable blue-emitting AlN:Eu2+ phosphor for ultraviolet white light-emitting diodes. J. Phys. Chem. C, 2009, 113: 9392-9397.
[6]	HIROSAKI N, XIE R J, KIMOTO K, et al.Characterization and properties of green-emitting β-SiAlON:Eu2+ powder phosphors for white light-emitting diodes.Appl. Phys. Lett., 2005, 86: 211905.
[7]	YAMADA S, EMOTO H, IBUKIYAMA M, et al.Properties of SiAlON powder phosphors for white LEDs.J. Eur. Ceram. Soc., 2012, 32: 1355-1358.
[8]	LI Y Q, DELSING A C A, WITH G DE, et al. Luminescence properties of Eu2+-activated alkaline-earth silicon-oxynitride MSi2O2-δN2+2/3δ(M=Ca, Sr, Ba): a promising class of novel LED conversion phosphors.Chem. Mater., 2005, 17: 3242-3248.
[9]	XIE R J, HIROSAKI N, SAKUMA K, et al.Eu2+ doped Ca-α-SiAlON: A yellow phosphor for white light-emitting diodes. Appl. Phys. Lett., 2004, 84(26): 5404-5406.
[10]	SUEHIRO T, ONUMA H, HIROSAKI N, et al.Powder synthesis of Y-α-SiAlON and its potential as a phosphor host.J. Phys. Chem. C, 2010, 114: 1337-1342.
[11]	LI Y Q, STEEN J E J VAN, KREVEL J W H VAN, et al. Luminescence properties of red-emitting Sr2Si5N8:Eu2+ (M=Ca, Sr, Ba) LED conversion phosphors.J. Alloys Compd., 2006, 417: 273-279.
[12]	LI Y Q, WITH G DE, HINTZEN H T, et al.The effect of replacement of Sr by Ca on the structural and luminescence properties of the red-emitting Sr2Si5N8:Eu2+ LED conversion phosphor.J. Solid State Chem., 2008, 181: 515-524.
[13]	UHEDA K, HIROSAKI N, YAMAMOTO Y, et al.Luminescence properties of a red phosphor, CaAlSiN3:Eu2+, for white light emitting diodes.Solid State Lett., 2006, 9(4): H22-H25.
[14]	DUAN C J, OTTEN W M, DELSING A C A, et al. Preparation and photoluminescence properties of Mn2+-activated M2Si5N8 (M = Ca, Sr, Ba) phosphors.J. Solid State Chem., 2008, 181(4): 751-757.
[15]	TENG X M, LIU Y H, LIU Y Z, et al.Luminescence properties of Tm3+ co-doped of srzs: Eu2+ red phosphor.J. Lumin., 2010, 130(5): 851-854.
[16]	LI J, LEI B, QIN J, et al.Temperature-dependent emission spectra of Ca2Si5N8:Eu2+, Tm3+ phosphor and its afterglow properties. J. Am. Ceram. Soc., 2013, 96(3): 873-878.
[17]	TEN KATE O M, ZHANG Z, DORENBOS, et al. 4f and 5d energy levels of the divalent and trivalent lanthanide ions in M2Si5N8 (M = Ca, Sr, Ba).J. Solid State Chem., 2013, 197: 209-217.
[18]	XU L L, CHEN Y B, ZENG R J.Spectroscopic properties and energy transfer of Eu2+-Tb3+ co-doped Li2SrSiO4.J. Ceram., 2011, 32(3): 419-424.
[19]	HIRAMATSU R, ISHIDA K, AIGA F, et al.Tb3+ luminescence by energy transfer from Eu2+ in (Sr, Ba)2SiO4 phosphor.J. Appl. Phys., 2009, 106(9): 093513.
[20]	PENG XIA, LI SHU-XING, LIU XUE-JIAN, et al.Syntheses and photoluminescence properties of Sr2Si5N8: Eu2+ phosphors.Journal of Inorganic Materials, 2014, 29(12):1281-1286.
[21]	Shannon R D, Prewitt C T.Effective ionic radii in oxides and fluorides. Acta Cryst., 1969, B25: 925-946.
[22]	孙家跃, 杜海燕, 胡文祥. 固体发光材料. 北京: 化学工业出版社, 2003:152-178.
[23]	BLASSE G.Energy transfer between inequivalent Eu2+ ions.J. Solid State Chem., 1986, 62(2): 207-211.

Syntheses and Photoluminescence Properties of Eu²⁺/Tb³⁺ Doped
Sr₂Si₅N₈ Phosphors

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