Journal of Inorganic Materials ›› 2013, Vol. 28 ›› Issue (12): 1364-1368.DOI: 10.3724/SP.J.1077.2013.13210

• Research Paper • Previous Articles     Next Articles

Study on Etching Process and Mechanism of New Phase Change Material Ti0.5Sb2Te3

ZHANG Xu1,2, LIU Bo1, SONG San-Nian1, YAO Dong-Ning1, ZHU Min1,2, RAO Feng1, WU Liang-Cai1, SONG Zhi-Tang1, FENG Song-Lin1   

  1. (1. State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro- system and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China; 2. University of the Chinese Academy of Sciences, Beijing 100083, China)
  • Received:2013-04-15 Revised:2013-06-07 Published:2013-12-20 Online:2013-11-15
  • About author:ZHANG Xu. E-mail:zhangxu08@mail.sim.ac.cn
  • Supported by:

    National Key Basic Research Program of China (2010CB934300, 2011CBA00607); National Natural Science Foundation of China (61006087, 61076121,61076122,61106001); Science and Technology Council of Shanghai (12nm0503701)

Abstract: The dry etching characteristic of new Ti0.5Sb2Te3 (TST) phase change material was investigated by using the CF4 and Ar gas mixture. The research mainly focuses on how to optimize the experimental parameters such as gas flow rate within the chamber, CF4/Ar flow ratio, the chamber background pressure and the incident RF power applied to the lower electrode. The results show that CF4 mainly plays a role of chemical etching and Ar plays a role of physical bombardment. The etching rate of TST films increases with the increasing concentration of CF4 in the gas mixture. The etching chamber pressure has less effect on the TST film etching speed, while the etching power has larger effect. The etch rate is up to 126 nm/min with the smooth etched surface (RMS=0.82 nm) and TST film profile is almost vertical (approaching 90°) using optimized etching parameters, including the total flow rate of 50 sccm, CF4 concentration of 26%, power of 400 W and pressure of 13.3 Pa.

Key words: new phase change material, dry etching, CF4/Ar gas mixture, etch rate

CLC Number: