Journal of Inorganic Materials

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Photoluminescence Properties and Preparation of Nanosized Carbon Particles Embedded Gel-Glass

YANG He-Qing; LIN Yin-Yin; WANG Min-Qiang; ZHANG Liang-Ying; YAO Xi   

  1. Electronic Materials Research Laboratory; Xian Jiaotong university; Xian 710049; China
  • Received:1999-04-12 Revised:1999-06-10 Published:2000-04-20 Online:2000-04-20

Abstract: C-nanoparticles embedded xAl2O3· xP2O5·100SiO2 (x=0.25 or 0.5) gel-glasses were prepared by a sol-gel process. The gels synthesized through hydrolysis of PO(OC2H5)3, Al(NO3)3· 9H2O and Si(OC2H5)4, were heated at 600℃ for 10h, in which -- OC2H5 were carbonized to precipitate nanosized C particles. Glasses doped with C nanoparticles showed a strong roomtemperature photoluminescence with a peak at 630nm under 532nm Nd:YAG laser excitation. The photoluminescence spectra were caused by C nanoparticles embedded gel-glasses.

Key words: sol-gel process, C/xAl2O3·xP2O3·100SiO2 (, C-nanoparticles, photoluminescence properties

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