Journal of Inorganic Materials ›› 2015, Vol. 30 ›› Issue (11): 1189-1194.DOI: 10.15541/jim20150191
• Orginal Article • Previous Articles Next Articles
QIAO Bei-Jing, CHEN Fei-Fei, NIE Qiu-Hua, DAI Shi-Xun, HUANG Yi-Cong
Received:
2015-04-24
Revised:
2015-05-28
Published:
2015-11-20
Online:
2015-10-20
About author:
QIAO Bei-Jing. E-mail: optic315211@163.com
Supported by:
CLC Number:
QIAO Bei-Jing, CHEN Fei-Fei, NIE Qiu-Hua, DAI Shi-Xun, HUANG Yi-Cong. Structure and Third-order Optical Nonlinearity Performance of Ge-Sn-Se Doped TiO2 Glass-ceramics at 1550 nm[J]. Journal of Inorganic Materials, 2015, 30(11): 1189-1194.
Fig. 2 Raman spectra of TiO2 doped Ge-Sn-Se samples heat- treated for different time Inset is the variation of integrated area from 170 to 210 cm-1 with heat- treatment time
Fig. 4 Tauc curves and optical band gap Eopg of TiO2 doped Ge-Sn-Se samples affer heat-treatment for different time Inset is variety tendency of Eopgwith heat treatment time
NO. | Density/(g·cm-3) (±0.001) | Eopg/ eV(±0.001) | Ee/ eV(±0.001) | n2/ (10-17m2·W-1)(±10%) | β/ (10-12 m·W-1)(±10%) | FOM (±20%) |
---|---|---|---|---|---|---|
GSS-Ti-0 | 4.492 | 1.667 | 0.082 | 5.59 | 2.22 | 16.25 |
GSS-Ti-3 | 4.479 | 1.659 | 0.087 | 23.36 | 4.01 | 37.58 |
GSS-Ti-6 | 4.475 | 1.652 | 0.099 | 57.50 | 93.73 | 3.96 |
GSS-Ti-12 | 4.451 | 1.634 | 0.100 | 49.24 | 110.27 | 2.88 |
GSS-Ti-18 | 4.367 | -- | -- | -- | -- | -- |
GSS-Ti-30 | 4.360 | -- | -- | -- | -- | -- |
As2Se3 | -- | -- | -- | 1.22 | 1.20 | 13.12 |
Table 1 Physical properties and nonlinearity parameters of TiO2 doped Ge-Sn-Se glass-ceramic samples
NO. | Density/(g·cm-3) (±0.001) | Eopg/ eV(±0.001) | Ee/ eV(±0.001) | n2/ (10-17m2·W-1)(±10%) | β/ (10-12 m·W-1)(±10%) | FOM (±20%) |
---|---|---|---|---|---|---|
GSS-Ti-0 | 4.492 | 1.667 | 0.082 | 5.59 | 2.22 | 16.25 |
GSS-Ti-3 | 4.479 | 1.659 | 0.087 | 23.36 | 4.01 | 37.58 |
GSS-Ti-6 | 4.475 | 1.652 | 0.099 | 57.50 | 93.73 | 3.96 |
GSS-Ti-12 | 4.451 | 1.634 | 0.100 | 49.24 | 110.27 | 2.88 |
GSS-Ti-18 | 4.367 | -- | -- | -- | -- | -- |
GSS-Ti-30 | 4.360 | -- | -- | -- | -- | -- |
As2Se3 | -- | -- | -- | 1.22 | 1.20 | 13.12 |
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