合成具有高效光催化活性的片状β-Bi2O3的一种新方法

doi:10.15541/jim20170601

无机材料学报 ›› 2018, Vol. 33 ›› Issue (8): 919-922.DOI: 10.15541/jim20170601

所属专题：光催化材料与技术

• • 上一篇

合成具有高效光催化活性的片状β-Bi₂O₃的一种新方法

陈军¹, 湛菁¹, 丁风华¹, 李启厚¹, 汤依伟²

1. 中南大学冶金与环境学院, 长沙 410083;
2. 广东佳纳能源科技有限公司, 清远 513056

收稿日期:2017-12-18 出版日期:2018-08-28 网络出版日期:2018-07-17
作者简介:陈军. E-mail: 43994071@qq.com

Novel Synthesis Method of Sheet-like Agglomerateβ-Bi₂O₃ with High Photocatalytic Activity

CHEN Jun¹, ZHAN Jing¹, DING Feng-Hua¹, LI Qi-Hou¹, TANG Yi-Wei²

1. School of Metallurgy and Environment, Central South University, Changsha 410083, China;
2. Guangdong Jiana Energy Technology Co. Ltd., Qingyuan 513056, China

Received:2017-12-18 Published:2018-08-28 Online:2018-07-17
About author:CHEN Jun (1993?), male, candidate of Master degree. E-mail: 43994071@qq.com
Supported by:
Foundation item: Jiana Foundation of Central South University (JNJJ201613);Nonferrous Foundation of the Hunan Province (2010SK2010)

摘要/Abstract

摘要：

采用萃取-反萃-热分解法以辉铋矿的盐酸浸出液为原料制备了层片状的β-Bi₂O₃。所制备的样品分别用X衍射仪及透射电镜对其物相及形貌进行表征, 以罗丹明B为污染物研究了其光催化活性。结果表明: 所制备的β-Bi₂O₃是一种层状的纳米片, 具有较低的禁带宽度。在实验条件下, 对罗丹明B进行4 h的降解, 降解率达到99.23%, 样品的重复降解实验还表现出良好的循环稳定性。

关键词: β-Bi₂O₃;, 辉铋矿浸出液, 萃取, 反萃, 降解

Abstract:

Sheet-like agglomerates β-Bi₂O₃ were synthesized via an extraction-precipitation stripping-decomposition method using a leaching solution of bismuthinite as raw materials in acidic chloride media. Phase form of as-prepared Bi₂O₃ was confirmed by X-ray diffraction (XRD) and its morphology was observed by scanning electron microscope (SEM) and transmission electron microscope (TEM). Moreover, photocatalytic activity of the β-Bi₂O₃ was evaluated by measuring the degradation of Rhodamine B (RhB) under visible light irradiation. The results showed that the powders consisted of nanoflakes. The β-Bi₂O₃ exhibited a smaller band gap energy and larger absorbance edge than α-Bi₂O₃ and reported β-Bi₂O₃. In addition, 99.23% of the RhB was degraded under 4 h visible light irradiation and β-Bi₂O₃ was a fairly stable photocatalyst under the experimental conditions.

Key words: β-Bi₂O₃;, leaching solution from bismuthinite, extraction, stripping precipitation, degradation

中图分类号:

TF125

陈军, 湛菁, 丁风华, 李启厚, 汤依伟. 合成具有高效光催化活性的片状β-Bi₂O₃的一种新方法[J]. 无机材料学报, 2018, 33(8): 919-922.

CHEN Jun, ZHAN Jing, DING Feng-Hua, LI Qi-Hou, TANG Yi-Wei. Novel Synthesis Method of Sheet-like Agglomerateβ-Bi₂O₃ with High Photocatalytic Activity[J]. Journal of Inorganic Materials, 2018, 33(8): 919-922.

图/表 8

Fig. 1 XRD pattern of the precursor

Fig. 2 SEM images of the precursor

Fig. 3 XRD patterns of β-Bi2O3

Fig. 4 (a) SEM, (b) TEM and (c) HRTEM images of β-Bi2O3

Fig. 5 (a) RhB concentration changes with irradiation and (b) RhB degradation in the first four cycle runs for β-Bi2O3

Fig. 6 Possible reaction mechanism of β-Bi2O3 photocatalysts for RhB photodegradation

Fig. S1 UV-Vis diffuse reflectance spectra of as-prepared β-Bi2O3 (inset: plots of (αhν)2 vs. photon energy)

Fig. S2 XRD patterns of as-prepared β-Bi2O3 after degradation of RhB

参考文献 18

[1]	LIU J, LIU Y, LIU N,et al.Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Science, 2015, 347(6225): 970-974.
[2]	WAKERLEY D W, KUEHNEL M F, ORCHARD K L,et al. Solar- driven reforming of lignocellulose to H2 with a CdS/CdOx photocatalyst. Nat. Energy, 2017, 2(4): 17021-17029.
[3]	MENG X, ZHANG Z.Bismuth-based photocatalytic semiconductors: introduction, challenges and possible approaches.J. Mol. Catal. A-Chem., 2016, 423: 533-549.
[4]	BARRERA-MOTA K, BIZARRO M, CASTELLINO M,et al.Spray deposited β-Bi2O3 nanostructured films with visible photocatalytic activity for solar water treatment. Photoch. Photobio. Sci., 2015, 14(6): 1110-1119.
[5]	BAO Y, LIM T T, ZHONG Z,et al.Acetic acid-assisted fabrication of hierarchical flower-like Bi2O3 for photocatalytic degradation of sulfamethoxazole and rhodamine B under solar irradiation. J.. Colloid Interf. Sci., 2017, 505(1): 489-499.
[6]	SÁNCHEX-MARTÍNEZ D, JUÁREZ-RAMÍREZ I, TORRES- MARTÍNEZ L M,et al. Photocatalytic properties of Bi2O3 powders obtained by an ultrasound-assisted precipitation method.Ceram. Int., 2016, 42(1): 2013-2020.
[7]	QIN F, ZHAO H, LI G,et al. Size-tunable fabrication of multifunctional Bi2O3 porous nanospheres for photocatalysis, bacteria inactivation and template-synthesis.Nanoscale, 2014, 6(10): 5402-5409.
[8]	LI J Z, ZHONG J B, ZENG J,et al. Improved photocatalytic activity of dysprosium-doped Bi2O3 prepared by Sol-Gel method.Mat. Sci. Semicon. Proc., 2013, 16(2): 379-384.
[9]	LIANG Z, CAO Y, LI Y,et al.Solid-state chemical synthesis of rod-like fluorine-doped β-Bi2O3 and their enhanced photocatalytic property under visible light. Appl. Surf. Sci., 2016, 390: 78-85.
[10]	ZHANG D X, XU H, LIAO Y Z,et al. Synthesis and characterization of nano-composite copper oxalate powders by a surfactant- free stripping-precipitation process.Powder Technol., 2009, 189(3): 404-408.
[11]	CHEN J, HUANG B, HUANG C,et al. Preparation of nanoscaled yttrium oxide by citrate preparation method.J. Rare Earth, 2017, 35(1): 79-84.
[12]	INNOCENZI V, MICHELIS I D, FERELLA F,et al. Secondary yttrium from spent fluorescent lamps: recovery by leaching and solvent extraction.Int. J. Miner. Process, 2017, 168(10): 87-94.
[13]	DING F, ZHAN J, WANG Z,et al.Simultaneous leaching of low grade bismuthinite and pyrolusite ores in hydrochloric acid medium. Hydrometallurgy, 2016, 166: 279-284.
[14]	WANG Z, DING F, ZHAN J,et al.Solvent extraction mechanism and precipitation stripping of bismuth (Ⅲ) in hydrochloric acid medium by tributyl phosphate J. Cent. South Univ., 2016, 23: 3085-3091.
[15]	XIAO X, HU R, LIU C, ,et al. Facile large-scale synthesis of β-Bi2O3 nanospheres as a highly efficient photocatalyst for the degradation of acetaminophen under visible light irradiation. Appl. Catal. B Environ., 2013,140-141: 433-443.
[16]	JALALAH M, FAISAL M, BOUZID H,et al.Comparative study on photocatalytic performances of crystalline α- and β-Bi2O3 nanoparticles under visible light. J. Ind. Eng. Chem., 2015, 30: 183-189.
[17]	CHEN X, DAI J, SHI G,et al.Visible light photocatalytic degradation of dyes by β-Bi2O3/graphene nanocomposites. J. Alloys. Compd., 2015, 649: 872-877.
[18]	WANG Y, WEN Y, DING H,et al.Improved structural stability of titanium-doped β-Bi2O3 during visible-light-activated photocatalytic processes. J. Mater. Sci., 2010, 45(5): 1385-1392.

合成具有高效光催化活性的片状β-Bi₂O₃的一种新方法

Novel Synthesis Method of Sheet-like Agglomerateβ-Bi₂O₃ with High Photocatalytic Activity

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