无机材料学报 ›› 2018, Vol. 33 ›› Issue (2): 153-161.DOI: 10.15541/jim20170414
聂恒昌1, 王永龄1, 贺红亮2, 王根水1, 董显林1
收稿日期:
2017-08-25
修回日期:
2017-11-13
出版日期:
2018-02-26
网络出版日期:
2018-01-26
作者简介:
聂恒昌(1983),男,副研究员.E-mail:sestonenhc@mail.sic.ac.cn
基金资助:
NIE Heng-Chang1, WANG Yong-Ling1, HE Hong-Liang2, WANG Gen-Shui1, DONG Xian-Lin1
Received:
2017-08-25
Revised:
2017-11-13
Published:
2018-02-26
Online:
2018-01-26
摘要:
基于铁电材料冲击波去极化效应的高功率脉冲电源在国防和高新技术领域具有重要应用。PZT95/5铁电陶瓷是目前铁电体高功率脉冲电源应用的理想材料。近年来, 多孔PZT95/5铁电陶瓷被发现具有更优异的综合性能而引起广泛关注。本文概述了多孔PZT95/5铁电陶瓷在微结构与性能调控、冲击波加载下的响应行为以及抗冲击损伤机制等方面的最新进展。研究发现, 具有合适气孔率和气孔分布的多孔PZT95/5铁电陶瓷具有优异的抗冲击损伤和耐电击穿性能; 多孔脆性材料中破碎介质的“滑移与转动”变形机制增强了材料的塑性变形, 从而提高了多孔材料的抗冲击损伤性能。最后, 简要介绍了BNT基无铅铁电陶瓷以及PIN-PMN铁电单晶在高功率脉冲电源方面应用的研究进展, 并对未来研究工作提出展望。
中图分类号:
聂恒昌, 王永龄, 贺红亮, 王根水, 董显林. 多孔PZT95/5铁电陶瓷材料研究进展[J]. 无机材料学报, 2018, 33(2): 153-161.
NIE Heng-Chang, WANG Yong-Ling, HE Hong-Liang, WANG Gen-Shui, DONG Xian-Lin. Recent Progress of Porous PZT95/5 Ferroelectric Ceramics[J]. Journal of Inorganic Materials, 2018, 33(2): 153-161.
图3 (a)糊精(Dextrin)和(b)聚甲基丙烯酸甲酯(PMMA)及其作为造孔剂及制备的PZT95/5铁电陶瓷(c~d)的SEM照片[28-29]
Fig. 3 SEM images of (a) Dextrin, (b) PMMA, (c) PZT 95/5 ceramics with Dextrin as pore formers and (d) PZT 95/5 ceramics with PMMA as pore formers[28-29]
图4 不同微结构孔的多孔PZT95/5铁电陶瓷SEM照片[37]
Fig. 4 SEM images of the porous PZT95/5 ceramics with different pore sizes[37] (a) 1.8 mm PMMA spheres; (b) 5 μm PMMA spheres; (c) 15 μm PMMA spheres; (d) 60 μm PMMA spheres
Property | Dense PZT95/5 ferroelectric ceramics | Porous PZT95/5 ferroelectric ceramics |
---|---|---|
Bulk density/(g•cm-3) | ~7.6 | ~7.3 |
Effective permittivity | 280-300 | 250-260 |
Piezoelectric constant/(pC•N-1) | 66-70 | 66-70 |
Bulk resistivity/(Ω•cm) | 1011-12 | 1011-12 |
Tangent loss/% | 1.7-2.0 | 1.5-1.8 |
Remnant polarization/(μC•cm-2) | ~35 | ~30 |
表1 气孔均匀分布的多孔PZT95/5铁电陶瓷与致密陶瓷性能比较[39-40]
Table 1 Physical property comparison between dense and porous PZT95/5 ferroelectric ceramics with disperse distribution[39-40]
Property | Dense PZT95/5 ferroelectric ceramics | Porous PZT95/5 ferroelectric ceramics |
---|---|---|
Bulk density/(g•cm-3) | ~7.6 | ~7.3 |
Effective permittivity | 280-300 | 250-260 |
Piezoelectric constant/(pC•N-1) | 66-70 | 66-70 |
Bulk resistivity/(Ω•cm) | 1011-12 | 1011-12 |
Tangent loss/% | 1.7-2.0 | 1.5-1.8 |
Remnant polarization/(μC•cm-2) | ~35 | ~30 |
图7 (a)三明治结构的PZT95/5铁电陶瓷的断面结构示意图以及(b)断面、(c) 致密层和(d)多孔层的SEM照片[42]
Fig. 7 Schematic diagram (a) and SEM images of polished fracture cross section of sandwich structure PZT95/5 ferroelectric ceramic: (b) full cross section; (c) dense layer; (d) porous layer[42]
图9 不同冲击压力下均匀分布气孔多孔PZT95/5铁电陶瓷动态响应行为[40]
Fig. 9 Dynamic response behaviors of porous PZT95/5 ferroelectric ceramics with disperse pores under different shock pressures[40]
Catalogue | Property |
---|---|
Type I (not dependent on porosity) | Curie temperature, Spontaneous polarization |
Type II (depend only on the amount of porosity) | Remnant polarization, bulk density, effective permittivity, piezoelectric constant, tangent loss, Young’s modulus, Dynamic yielding threshold |
Type III (depend on both the amount and one or more characteristics of porosity) | Shock plasticity, Dielectric strength |
表2 多孔PZT95/5铁电陶瓷的性质与气孔的关系
Table 2 Relationship catalogue between physical property and pore of PZT95/5 ferroelectric ceramics
Catalogue | Property |
---|---|
Type I (not dependent on porosity) | Curie temperature, Spontaneous polarization |
Type II (depend only on the amount of porosity) | Remnant polarization, bulk density, effective permittivity, piezoelectric constant, tangent loss, Young’s modulus, Dynamic yielding threshold |
Type III (depend on both the amount and one or more characteristics of porosity) | Shock plasticity, Dielectric strength |
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